Initial performance metrics of a new custom-designed ArF excimer LA-ICPMS system coupled to a two-volume laser-ablation cell (Englisch)

Nationallizenz
In: Journal of Analytical Atomic Spectrometry   ;  24 ,  2  ;  209-214  ;  2008

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A new custom-built excimer (193 nm) laser-ablation system with two-volume laser-ablation cell coupled to a quadrupole ICPMS is described, which combines rapid (<1.5 s for 99%) signal washout with full flexibility in sample size (50 × 50 × 25 mm) and high sensitivity (>10000 cps/ppm for mid-high m/z, 55 μm, 5 Hz). An application of reconstructing medieval Pb exposure highlights the need for rapid signal washout in unravelling strongly varying Pb peaks in well-preserved archaeological tooth enamel.

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117
Front cover
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119
Contents and Chemical Technology
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127
Metallomics issue 1 contents pages
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131
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Todorov, Todor I. / Xu, Hanna / Ejnik, John W. / Mullick, Florabel G. / Squibb, Katherine / McDiarmid, Melissa A. / Centeno, Jose A. | 2008
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Technique for sensitive carbon depth profiling in thin samples using C–C elastic scattering
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On-line separation and identification of inorganic and organic arsenic species in ethanolic kelp and bladderwrack extracts through liquid chromatography/particle beam-electron ionization mass spectrometry (LC/PB-EIMS)
Balarama Krishna, M. V. / Castro, Joaudimir / Brewer, Tim M. / Marcus, R. Kenneth | 2008
209
Initial performance metrics of a new custom-designed ArF excimer LA-ICPMS system coupled to a two-volume laser-ablation cell
Müller, Wolfgang / Shelley, Michael / Miller, Pascal / Broude, Sergey | 2008
215
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Semi-quantitative analysis of geological samples using laser plasma time-of-flight mass spectrometry
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Validation of a reference measurement procedure for the assessment of selenomethionine in nutritional supplements
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242
Back matter
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247
Back cover
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