Overcoming the shortcomings of the Nernst–Planck model (Englisch)

Nationallizenz
In: Physical Chemistry Chemical Physics   ;  15 ,  19  ;  7075-7086  ;  2013

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This is a study on electrolytes that takes a thermodynamically consistent coupling between mechanics and diffusion into account. It removes some inherent deficiencies of the popular Nernst–Planck model. A boundary problem for equilibrium processes is used to illustrate the features of the new model.

Inhaltsverzeichnis – Band 15, Ausgabe 19

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Front cover
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Contents list
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7017
The limitations of models of surfactant mixing at interfaces as revealed by neutron scattering
Penfold, Jeffrey / Thomas, Robert K. | 2013
7028
Accurate quantum chemical energies for tetrapeptide conformations: why MP2 data with an insufficient basis set should be handled with caution
Goerigk, Lar / Karton, Amir / Martin, Jan M. L. / Radom, Leo | 2013
7032
Influence of deuteration in the glassing matrix on 13C dynamic nuclear polarization
Lumata, Lloyd / Merritt, Matthew E. / Kovacs, Zoltan | 2013
7036
Using waste Li ion batteries as cathodes in rechargeable Li–liquid batteries
Chun, Jinyoung / Chung, Moonsik / Lee, Jinwoo / Kim, Youngsik | 2013
7041
Mesoporous chromium nitride as a high performance non-carbon support for the oxygen reduction reaction
Yang, Minghui / Cui, Zhiming / DiSalvo, Francis J. | 2013
7045
Surface engineering of sponge-like silicon particles for high-performance lithium-ion battery anodes
Lee, Jung-In / Park, Jang-Hoon / Lee, Sang-Young / Park, Soojin | 2013
7050
Integrated microfluidic test-bed for energy conversion devices
Modestino, Miguel A. / Diaz-Botia, Camilo A. / Haussener, Sophia / Gomez-Sjoberg, Rafael / Ager, Joel W. / Segalman, Rachel A. | 2013
7055
Attenuated total reflectance infrared spectroelectrochemistry at a carbon particle electrode; unmediated redox control of a [NiFe]-hydrogenase solution
Healy, Adam J. / Ash, Philip A. / Lenz, Oliver / Vincent, Kylie A. | 2013
7060
Simultaneous two and three photon resonant enhancement of third-order NLO susceptibility in an azo-dye functionalized polymer film
Jerca, Florica Adriana / Jerca, Valentin Victor / Kajzar, Francoi / Manea, Ana Maria / Rau, Ileana / Vuluga, Dumitru Mircea | 2013
7064
The lifetime and efficiency of triplet–triplet fluorescence from the excited state of a TMM biradical determined using transient emission spectroscopy by two-color two-laser flash photolysis
Matsui, Yasunori / Kawahara, Daisuke / Ohta, Eisuke / Ikeda, Hiroshi | 2013
7070
Experimental validation of the novel theory explaining self-organization in porous anodic alumina films
Pashchanka, Mikhail / Schneider, Jörg J. | 2013
7075
Overcoming the shortcomings of the Nernst–Planck model
Dreyer, Wolfgang / Guhlke, Clemen / Müller, Rüdiger | 2013
7087
Regeneration and recombination kinetics in cobalt polypyridine based dye-sensitized solar cells, explained using Marcus theory
Feldt, Sandra M. / Lohse, Peter W. / Kessler, Florian / Nazeeruddin, Mohammed K. / Grätzel, Michael / Boschloo, Gerrit / Hagfeldt, Ander | 2013
7098
Tunable electronic and dielectric behavior of GaS and GaSe monolayers
Ma, Yandong / Dai, Ying / Guo, Meng / Yu, Lin / Huang, Baibiao | 2013
7106
Effects of convergent diffusion and charge transfer kinetics on the diffusion layer thickness of spherical micro- and nanoelectrodes
Molina, A. / Laborda, E. / González, J. / Compton, R. G. | 2013
7114
Modeling CO2 reduction on Pt(111)
Shi, Chuan / O'Grady, Christopher P. / Peterson, Andrew A. / Hansen, Heine A. / Nørskov, Jens K. | 2013
7123
Long-range Li+ dynamics in the lithium argyrodite Li7PSe6 as probed by rotating-frame spin–lattice relaxation NMR
Epp, V. / Gün, Ö. / Deiseroth, H.-J. / Wilkening, M. | 2013
7133
Mesoscopic modelling of frustration in microemulsions
Duvail, Magali / Dufrêche, Jean-Françoi / Arleth, Lise / Zemb, Thoma | 2013
7142
Stability and physical properties of a tri-ring based porous g-C4N3 sheet
Li, Xiaowei / Zhang, Shunhong / Wang, Qian | 2013
7147
Interpretation of experimental hydrogen-bond enthalpies and entropies from COSMO polarisation charge densities
Klamt, Andrea / Reinisch, Jen / Eckert, Frank / Graton, Jérôme / Le Questel, Jean-Yve | 2013
7155
Hydrogen and carbon monoxide generation from laser-induced graphitized nanodiamonds in water
Jang, Dong Myung / Im, Hyung Soon / Myung, Yoon / Cho, Yong Jae / Kim, Han Sung / Back, Seung Hyuk / Park, Jeunghee / Cha, Eun Hee / Lee, Minyung | 2013
7161
Low-lying excited-states of 5-benzyluracil
Micciarelli, Marco / Altucci, Carlo / Ventura, Bartolomeo Della / Velotta, Raffaele / Toşa, Valer / Pérez, Adán B. Gónzalez / Rodríguez, Martin Pérez / de Lera, Ángel R. / Bende, Attila | 2013
7174
Thermal evaporation-induced anhydrous synthesis of Fe3O4–graphene composite with enhanced rate performance and cyclic stability for lithium ion batteries
Dong, Yucheng / Ma, Ruguang / Hu, Mingjun / Cheng, Hua / Yang, Qingdan / Li, Yang Yang / Zapien, Juan Antonio | 2013
7182
Effects of intramolecular hydrogen bonding on the excited state dynamics of phenol chromophores
Yang, Yi Lin / Ho, Yu-Chieh / Dyakov, Yuri A. / Hsu, Wen-Hsin / Ni, Chi-Kung / Sun, Yi-Lun / Tsai, Wan-Chen / Hu, Wei-Ping | 2013
7191
Chelating ionic liquids for reversible zinc electrochemistry
Kar, Mega / Winther-Jensen, Bjorn / Forsyth, Maria / MacFarlane, Douglas R. | 2013
7198
Combined experimental and theoretical investigation of the hemi-squaraine/TiO2 interface for dye sensitized solar cells
Cicero, Giancarlo / Musso, Giorgia / Lamberti, Andrea / Camino, Bruno / Bianco, Stefano / Pugliese, Diego / Risplendi, Francesca / Sacco, Adriano / Shahzad, Nadia / Ferrari, Anna Maria et al. | 2013
7204
Measurement of the interface tension of smectic membranes in water
Harth, Kirsten / Stannarius, Ralf | 2013
7210
Protonation equilibrium of the poly(allylammonium) cation in an aqueous solution of binary 1 : 1 electrolytes
Bohinc, Klemen / Kovačević, Davor / Požar, Josip | 2013
7220
Selective terminal function modification of SAMs driven by low-energy electrons (0–15 eV)
Houplin, J. / Amiaud, L. / Humblot, V. / Martin, I. / Matar, E. / Azria, R. / Pradier, C.-M. / Lafosse, A. | 2013
7228
Structure and membrane interactions of the b-amyloid fragment 25-35 as viewed using spectroscopic approaches
Labbe, J. F. / Lefevre, T. / Guay-Begin, A. A. / Auger, M. | 2013
7228
Structure and membrane interactions of the β-amyloid fragment 25–35 as viewed using spectroscopic approaches
Labbé, Jean-Françoi / Lefèvre, Thierry / Guay-Bégin, Andrée-Anne / Auger, Michèle | 2013
7240
Direct methanol steam reforming to hydrogen over CuZnGaOx catalysts without CO post-treatment: mechanistic considerations
Tong, Weiyi / Cheung, Kevin / West, Adam / Yu, Kai-Man / Tsang, Shik Chi Edman | 2013
7249
Hydrogen and halogen bonds are ruled by the same mechanisms
Grabowski, Sławomir J. | 2013
7260
First principles calculations of the structure and V L-edge X-ray absorption spectra of V2O5 using local pair natural orbital coupled cluster theory and spin–orbit coupled configuration interaction approaches
Maganas, Dimitrio / Roemelt, Michael / Hävecker, Michael / Trunschke, Annette / Knop-Gericke, Axel / Schlögl, Robert / Neese, Frank | 2013
7277
Vortex domain structures of an epitaxial ferroelectric nanodot and its temperature-misfit strain phase diagram
Chen, W. J. / Zheng, Yue / Wang, B. / Ma, D. C. / Ling, F. R. | 2013
7286
Composition-dependent electrocatalytic activity of AuPd alloy nanoparticles prepared via simultaneous sputter deposition into an ionic liquid
Hirano, Masanori / Enokida, Kazuki / Okazaki, Ken-ichi / Kuwabata, Susumu / Yoshida, Hisao / Torimoto, Tsukasa | 2013
7295
Benchmark quantum-chemical calculations on a complete set of rotameric families of the DNA sugar–phosphate backbone and their comparison with modern density functional theory
Mládek, Arnošt / Krepl, Miroslav / Svozil, Daniel / Čech, Petr / Otyepka, Michal / Banáš, Pavel / Zgarbová, Marie / Jurečka, Petr / Šponer, Jiří | 2013
7311
The reaction force constant as an indicator of synchronicity/nonsynchronicity in [4+2] cycloaddition processes
Yepes, Diana / Donoso-Tauda, Oscar / Pérez, Patricia / Murray, Jane S. / Politzer, Peter / Jaque, Pablo | 2013
7321
Effective bulk and surface temperatures of the catalyst bed of FT-IR cells used for in situ and operando studies
Li, Haoguang / Rivallan, Mickael / Thibault-Starzyk, Frederic / Travert, Arnaud / Meunier, Frederic C. | 2013
7328
The effect of axial ligand on the oxidation of syringyl alcohol by Co(salen) adducts
Elder, Thoma / Bozell, Joseph J. / Cedeno, Diana | 2013
7338
Characterization of strain recovery and “self-healing” in a self-assembled metallo-gel
Terech, Pierre / Yan, Minhao / Maréchal, Manuel / Royal, Guy / Galvez, Jose / Velu, Sabareesh K. P. | 2013
7345
Synthesis of low-cost, rubbery amphiphilic comb-like copolymers and their use in the templated synthesis of mesoporous TiO2 films for solid-state dye-sensitized solar cells
Kim, Dong Jun / Kim, Sang Jin / Roh, Dong Kyu / Kim, Jong Hak | 2013
7354
Probing micro-solvation in “numbers”: the case of neutral dipeptides in water
Takis, Panteleimon G. / Papavasileiou, Konstantinos D. / Peristeras, Loukas D. / Melissas, Vasilios S. / Troganis, Anastassios N. | 2013
7363
Co–Ni layered double hydroxides for water oxidation in neutral electrolyte
Zhang, Ye / Cui, Bai / Zhao, Chunsong / Lin, Hong / Li, Jianbao | 2013
7370
Examination of the chemical behavior of the quercetin radical cation towards some bases
Marković, Zoran / Amić, Dragan / Milenković, Dejan / Dimitrić-Marković, Jasmina M. / Marković, Svetlana | 2013
7379
Density-induced molecular arrangements of water inside carbon nanotubes
Sadeghi, M. / Parsafar, G. A. | 2013
7389
On the signature of the hydrophobic effect at a single molecule level
Graziano, Giuseppe | 2013
7396
The effect of size on the optical properties of guanine nanostructures: a femtosecond to nanosecond study
Hua, Ying / Changenet-Barret, Pascale / Gustavsson, Thoma / Markovitsi, Dimitra | 2013
7403
A statistical approach for analyzing the development of 1H multiple-quantum coherence in solids
Mogami, Yuuki / Noda, Yasuto / Ishikawa, Hiroto / Takegoshi, K. | 2013
7411
Ligand strain and conformations in a family of Fe(ii) spin crossover hexadentate complexes involving the 2-pyridylmethyl-amino moiety: DFT modelling
Matouzenko, Galina S. / Borshch, Serguei A. / Schünemann, Volker / Wolny, Juliusz A. | 2013
7421
Back matter
| 2013