Ionische Flüssigkeiten und Mikrowellen: Synthese von Zeolithen für kommende Anwendungen (Deutsch)

Titelbild: Mesostructured Prussian Blue Analogues (Angew. Chem. 3/2008)

Innentitelbild: Ionothermal Synthesis of Oriented Zeolite AEL Films and Their Application as Corrosion‐Resistant Coatings (Angew. Chem. 3/2008)

Graphisches Inhaltsverzeichnis: Angew. Chem. 3/2008

Top‐Beiträge aus unseren Schwesterzeitschiften: Angew. Chem. 3/2008

Top-Beitrage aus unseren Schwesterzeitschiften: Angew. Chem. 3/2008

Integrated Approach to Coordination Chemistry. An Inorganic Laboratory Guide. Von Rosemary A. Marusak, Kate Doan und Scott D. Cummings.

Ionische Flüssigkeiten und Mikrowellen: Synthese von Zeolithen für kommende AnwendungenFNR HREF="nss"> FN ID="nss"> R.E.M. dankt dem EPSRC und der Leverhulme-Stiftung für finanzielle Unterstützung.

Ionische Flussigkeiten und Mikrowellen: Synthese von Zeolithen fur kommende Anwendungen

Ionische Flüssigkeiten und Mikrowellen: Synthese von Zeolithen für kommende Anwendungen

Die nächste Generation formstabiler Zeolith‐Analoga: kovalent gebundene organische Netzwerkverbindungen

Die nachste Generation formstabiler Zeolith-Analoga: kovalent gebundene organische Netzwerkverbindungen

Die nächste Generation formstabiler Zeolith-Analoga: kovalent gebundene organische NetzwerkverbindungenFNR HREF="nss"> FN ID="nss"> Mein Dank gilt der Deutschen Forschungsgemeinschaft (DFG) für die finanzielle Unterstützung.

Mikroporöse Polymere mit einstellbarer PorengrößeFNR HREF="nss"> FN ID="nss"> Der Autor dankt der National Science Foundation für Förderung unter Projektnummer DMR-0215342.

Mikroporose Polymere mit einstellbarer Porengroe

Mikroporöse Polymere mit einstellbarer Porengröße

Höhere Acene: vielseitige organische Halbleiter

Hohere Acene: vielseitige organische Halbleiter

From Storable Sources of Atomic Nb- and Ta- Ions to Isolable Anionic Tris(1,3-butadiene)metal Complexes: [M(η4-C4H6)3]-, M=Nb, TaFNR HREF="nss"> FN ID="nss"> Highly Reduced Organometallics, Part 63. This work was supported by the U.S. National Science Foundation and the donors of the Petroleum Research Fund administered by the American Chemical Society, a predoctoral fellowship from the National Science Foundation (V.J.S.), and a University of Minnesota Doctoral Dissertation Fellowship (V.J.S.). We thank Christine Lundby for expert assistance in the preparation of this manuscript. Part 62: see Ref. [30].

From Storable Sources of Atomic Nb⁻ and Ta⁻ Ions to Isolable Anionic Tris(1,3‐butadiene)metal Complexes: [M(η⁴‐C₄H₆)₃]⁻, M=Nb, Ta

Single‐Molecule Magnets with Mesomorphic Lamellar Ordering

Single-Molecule Magnets with Mesomorphic Lamellar OrderingFNR HREF="nss"> FN ID="nss"> We are grateful to the Swiss National Science Foundation, the CNRS-ULP, and the National Agency for Research (ANR DENDRIMAT) for financial support. We thank N. Beyer for the artwork, D. Burger for TGA measurements, and Dr. B. Heinrich for discussions.

Achiral Nucleobase Cytosine Acts as an Origin of Homochirality of Biomolecules in Conjunction with Asymmetric AutocatalysisFNR HREF="nss"> FN ID="nss"> This work was supported by a Grant-in-Aid for Scientific Research from the Ministry of Education, Culture, Sports, Science, and Technology and by Merck Research Laboratories.

Achiral Nucleobase Cytosine Acts as an Origin of Homochirality of Biomolecules in Conjunction with Asymmetric Autocatalysis

A Tunable FRET Circuit for Engineering Fluorescent Biosensors

A Tunable FRET Circuit for Engineering Fluorescent BiosensorsFNR HREF="nss"> FN ID="nss"> This work was supported by the NIH (DK073368), the American Heart Association, W.M. Keck Center, the Young Clinical Scientist Award Program of the Flight Attendant Medical Research Institute, and 3M (to J.Z.).

Observation of Three Intervalence‐Transfer Bands for a Class II–III Mixed‐Valence Complex of Ruthenium

Observation of Three Intervalence-Transfer Bands for a Class II-III Mixed-Valence Complex of RutheniumFNR HREF="nss"> FN ID="nss"> This work was supported by the UCDRD program (at LANL) and the NSF (at UNC; grant CHE554561). The assistance of Dr. S. Iyer (mass spectrometry) is gratefully acknowledged.

Experimental Evidence That a DNA Polymerase Can Incorporate N7-Platinated Guanines To Give Platinated DNAFNR HREF="nss"> FN ID="nss"> The Università del Salento (Italy) is acknowledged for financial support.

Experimental Evidence That a DNA Polymerase Can Incorporate N7‐Platinated Guanines To Give Platinated DNA

Mesostructured Prussian Blue Analogues

Mesostructured Prussian Blue AnaloguesFNR HREF="nss"> FN ID="nss"> We thank the Natural Sciences and Engineering Research Council of Canada and UBC for funding. X.R. thanks the FQRNT and NSERC for postgraduate scholarships. We thank Dev Sharma and Danny Leznoff (Simon Fraser University) for obtaining the Mössbauer data, Robert Thompson (UBC) for helpful discussions, and Erin MacLachlan for assistance with the text.

Encapsulation of Fullerenes in a Helical PMMA Cavity Leading to a Robust Processable Complex with a Macromolecular Helicity Memory

Encapsulation of Fullerenes in a Helical PMMA Cavity Leading to a Robust Processable Complex with a Macromolecular Helicity MemoryFNR HREF="nss"> FN ID="nss"> We are deeply grateful to Prof. N. Tanaka, Prof. M. M. Green, and Prof. Y. Okamoto for valuable discussions. PMMA=poly(methyl methacrylate).

Theoretical Model for Nanoporous Carbon Supercapacitors

Theoretical Model for Nanoporous Carbon SupercapacitorsFNR HREF="nss"> FN ID="nss"> This research was sponsored by the Laboratory Directed Research and Development Program of Oak Ridge National Laboratory (ORNL) and by the Division of Materials Sciences and Engineering, U.S. Department of Energy under Contract No. DEAC05-00OR22725 with UT-Battelle, LLC at ORNL. We are indebted to Dr. Sheng Dai, Dr. Nancy J. Dudney, and Prof. Dr. Miklos Kertesz for their helpful discussions on pore shape, electrochemical aspects, and charge transfer from molecules inside nanotubes to nanotubes, respectively.

Ionothermal Synthesis of Oriented Zeolite AEL Films and Their Application as Corrosion‐Resistant Coatings

Ionothermal Synthesis of Oriented Zeolite AEL Films and Their Application as Corrosion-Resistant CoatingsFNR HREF="nss"> FN ID="nss"> We thank SERDP-DoD for financial support.

High-Pressure Polymorphism as a Step towards Destabilization of LiBH4FNR HREF="nss"> FN ID="nss"> The authors are grateful to SNBL for the provision of in-house beam time and to P. Pattison for critical reading of the manuscript.

High‐Pressure Polymorphism as a Step towards Destabilization of LiBH₄

Novel Reactivity of Side‐On (Disulfido)dicopper Complexes Supported by Bi‐ and Tridentate Nitrogen Donors: Impact of Axial Coordination

Novel Reactivity of Side-On (Disulfido)dicopper Complexes Supported by Bi- and Tridentate Nitrogen Donors: Impact of Axial CoordinationFNR HREF="nss"> FN ID="nss"> We thank the National Institutes of Health (grant GM47365 to W.B.T.) and the University of Minnesota (dissertation fellowship to J.T.Y.) for financial support of this research.

Are Environmentally Coupled Enzymatic Hydrogen Tunneling Reactions Influenced by Changes in Solution Viscosity?

Are Environmentally Coupled Enzymatic Hydrogen Tunneling Reactions Influenced by Changes in Solution Viscosity?FNR HREF="nss"> FN ID="nss"> This work was funded by the UK Biotechnology and Biological Sciences Research Council (BBSRC). N.S.S. is a BBSRC Professorial Research Fellow.

Synthesis, Characterization, and Catalytic Activity of a Well‐Defined Rhodium Siloxide Complex Immobilized on Silica

Synthesis, Characterization, and Catalytic Activity of a Well-Defined Rhodium Siloxide Complex Immobilized on SilicaFNR HREF="nss"> FN ID="nss"> Financial support from the Ministry of Science and Higher Education (Poland), Grant N204 162 32-4248 is gratefully acknowledged.

Highly Efficient Catalytic System for Enantioselective Michael Addition of Aldehydes to Nitroalkenes in Water

Highly Efficient Catalytic System for Enantioselective Michael Addition of Aldehydes to Nitroalkenes in WaterFNR HREF="nss"> FN ID="nss"> The authors are grateful to the Chinese Academy of Sciences and the National Natural Science Foundation of China (grant 20621062) for their financial support.

A Crown Ether as Template for Microporous and Nanostructured Uranium CompoundsFNR HREF="nss"> FN ID="nss"> This work was financially supported by DFG research grant to W.D. (De412-30-1) and Alexander von Humboldt Institutional Cooperation grant (to W.D. and S.V.K.). S.V.K. thanks Russian Ministry of Science and Education and RFBR for financial support (grants RNP 2.1.1.3077 and 06-03-32096, respectively).

A Crown Ether as Template for Microporous and Nanostructured Uranium Compounds

Layered Silicates by Swelling of AMH‐3 and Nanocomposite Membranes

Layered Silicates by Swelling of AMH-3 and Nanocomposite MembranesFNR HREF="nss"> FN ID="nss"> Funding for this work was provided mainly by NSF (CTS-0327811). Additional support was provided by DOE (DE-FG26-04NT42119) and Pall Corporation. J.C. acknowledges support from the Spanish Ministry of Education (Programa de Estancias de Profesores de Universidad of the Dirección General de Universidades), S.N. from NSF (CTS-0437621), and D.F.S. from the Petroleum Research Fund of the American Chemical Society (Award 43942-AC10). We gratefully acknowledge Sandeep Kumar for the TEM images of swollen AMH-3 particles.

Synthesis and Characterization of the Gold(I) Tris(ethylene) Complex [Au(C2H4)3][SbF6]FNR HREF="nss"> FN ID="nss"> H.V.R.D. thanks the Robert A. Welch Foundation (grant Y-1289) for financial support of this research. T.R.C. acknowledges the National Science Foundation (CHE-0701247) for its support of this research.

Synthesis and Characterization of the Gold(I) Tris(ethylene) Complex [Au(C₂H₄)₃][SbF₆]

Aluminum Triflate as a Highly Active and Efficient Nonprotic Cocatalyst in the Palladium‐Catalyzed Methoxycarbonylation Reaction

Aluminum Triflate as a Highly Active and Efficient Nonprotic Cocatalyst in the Palladium-Catalyzed Methoxycarbonylation ReactionFNR HREF="nss"> FN ID="nss"> The authors gratefully acknowledge funding from the University of Johannesburg, Sasol Ltd, THRIP, and the NRF.

Cobaloxime‐Based Photocatalytic Devices for Hydrogen Production

Cobaloxime-Based Photocatalytic Devices for Hydrogen ProductionFNR HREF="nss"> FN ID="nss"> The authors acknowledge Sébastien Camensuli for experimental work during his Master's training and the Life Science Division of the Commissariat à l'Energie Atomique for financial support within the BioHydrogen program.

Asymmetric Allenophanes: Synthesis of a Tris‐meta‐allenophane and Tetrakis‐meta‐allenophane by Sequential Cross‐Coupling

Asymmetric Allenophanes: Synthesis of a Tris-meta-allenophane and Tetrakis-meta-allenophane by Sequential Cross-CouplingFNR HREF="nss"> FN ID="nss"> We are grateful to the Natural Sciences and Engineering Research Council of Canada (NSERC) for financial support. We thank L.-L. Tay (NRC, Ottawa) for the Raman spectra, also K. Fagnou, T. Moon, and S. Gorelsky for the DFT calculations, and M. Frenette for CD spectral measurements.

Alkylzinc Carboxylates as Efficient Precursors for Zinc Oxocarboxylates and Sulfidocarboxylates

Alkylzinc Carboxylates as Efficient Precursors for Zinc Oxocarboxylates and SulfidocarboxylatesFNR HREF="nss"> FN ID="nss"> This work was supported by the State Committee for Scientific Research (grant nos. 3 T08E 053 27 and PBZ-KBN-118-T09-04).

Efficient Photoswitching of the Nonlinear Optical Properties of Dipolar Photochromic Zinc(II) Complexes

Efficient Photoswitching of the Nonlinear Optical Properties of Dipolar Photochromic Zinc(II) ComplexesFNR HREF="nss"> FN ID="nss"> We thank Région Bretagne for financial support (SIE 211-B3-11).

Benzimidazole/Amine‐Based Compounds Capable of Ambipolar Transport for Application in Single‐Layer Blue‐Emitting OLEDs and as Hosts for Phosphorescent Emitters

Benzimidazole-Amine-Based Compounds Capable of Ambipolar Transport for Application in Single-Layer Blue-Emitting OLEDs and as Hosts for Phosphorescent EmittersFNR HREF="nss"> FN ID="nss"> We thank the Academia Sinica, National Taiwan University, and the National Science Council for supporting this work.

Iron‐Catalyzed CO Cross‐Couplings of Phenols with Aryl Iodides

Iron-Catalyzed C&bond;O Cross-Couplings of Phenols with Aryl IodidesFNR HREF="nss"> FN ID="nss"> We are grateful to the Fonds der Chemischen Industrie for financial support. O.B. thanks the Alexander von Humboldt Foundation for a postdoctoral fellowship and A.C. thanks the Basque Government for support through the "Programa de Perfeccionamiento de Doctores en el extranjero del Departamento de Educación, Universidades e Investigación".

Reductive Coupling of Acetonitrile by Uranium and Thorium Hydride Complexes To Give Cyanopentadienyl Dianion (C₆N₃H₇)²⁻

Reductive Coupling of Acetonitrile by Uranium and Thorium Hydride Complexes To Give Cyanopentadienyl Dianion (C6N3H7)2-FNR HREF="nss"> FN ID="nss"> We thank the National Science Foundation for support of this research.

Asymmetrische Brønsted-Säure-Katalyse: enantioselektive nucleophile Substitutionen und 1,4-AdditionenFNR HREF="nss"> FN ID="nss"> Wir danken der Degussa GmbH und der DFG (Schwerpunktprogramm Organokatalyse) für die finanzielle Unterstützung sowie dem Fonds der chemischen Industrie für ein Stipendium für B.J.N.

Asymmetrische Bronsted-Saure-Katalyse: enantioselektive nucleophile Substitutionen und 1,4-Additionen

Asymmetrische Brønsted‐Säure‐Katalyse: enantioselektive nucleophile Substitutionen und 1,4‐Additionen

Die Totalsynthese von Chlorotonil A

Die Totalsynthese von Chlorotonil AFNR HREF="nss"> FN ID="nss"> Wir danken R. Jansen, H. Steinmetz und K. Gerth (HZI) für die Bereitstellung von authentischem Chlorotonil A.

Chlorotonil A, ein Macrolid mit einzigartiger gem‐Dichlor‐1,3‐dionfunktion aus Sorangium cellulosum, So ce1525

Chlorotonil A, ein Macrolid mit einzigartiger gem-Dichlor-1,3-dionfunktion aus Sorangium cellulosum, So ce1525FNR HREF="nss"> FN ID="nss"> Wir danken N. Dankers, K. Schober und K.-P. Conrad für ihre Mitarbeit bei der Isolierung und Fermentation ebenso wie A. Roß, H. Schüler und R. Krützfeld und ihren Mitarbeitern für die Unterstützung bei Fermentation und Aufarbeitung der Fermentationsbrühe sowie V. Wray, B. Jaschok-Kentner und C. Kakoschke für die Aufnahme der NMR-Spektren (HZI). Unser besonderer Dank gilt H.-J. Hecht (HZI) sowie N. Rahn, A. Kena Diba und M. Wiebcke (Leibniz-Universität Hannover) für die Röntgenstrukturanalyse.

Tetrazarsole - eine neue Klasse binarer Arsen-Stickstoff-Heterocyclen

Tetrazarsole – eine neue Klasse binärer Arsen‐Stickstoff‐Heterocyclen

Tetrazarsole - eine neue Klasse binärer Arsen-Stickstoff-HeterocyclenFNR HREF="nss"> FN ID="nss"> Wir danken der Deutschen Forschungsgemeinschaft für finanzielle Unterstützung (SCHU 1170-4-1) sowie Dr. D. Michalik für die NMR-Messungen.

Vorschau: Angew. Chem. 4/2008