The Absorption Spectrum of Methyl Alcohol Vapor in the Photographic Infrared (English)

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In: The Journal of Chemical Physics   ;  4 ,  8  ;  469-473  ;  1936

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The absorption of methyl alcohol vapor in the photographic infrared has been explored under low dispersion. Absorption regions were found at λ9500 and λ7300, which correspond to two harmonics of the O&sngbnd;H vibration, and at λ12,000 which is a harmonic of the C&sngbnd;H vibration. The two O&sngbnd;H harmonic bands were investigated under high dispersion and a somewhat complex rotational structure was resolved. The complete interpretation of the spectrum must be postponed until the theory of the torsion oscillator rotator is further developed.

Table of contents – Volume 4, Issue 8

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The Reactions of Deuterium Atoms with Methane and Ethane
Steacie, E. W. R. / Phillips, N. W. F. | 1936
The Absorption Spectrum of Methyl Alcohol Vapor in the Photographic Infrared
Badger, Richard M. / Bauer, Simon H. | 1936
The Continuous Absorption Spectrum of Bromine: A New Interpretation
Acton, A. P. / Aickin, R. G. / Bayliss, N. S. | 1936
The Theoretical Treatment of Chemical Reactions Produced by Ionization Processes Part I. The Ortho‐Para Hydrogen Conversion by Alpha‐Particles
Eyring, Henry / Hirschfelder, J. O. / Taylor, Hugh S. | 1936
The Electron Affinity of Bromine Atoms from Space‐Charge Effects
Glockler, Geo. / Calvin, Melvin | 1936
The Limiting High Temperature Rotational Partition Function of Nonrigid Molecules VI. The Methanol Equilibrium
Kassel, Louis S. | 1936
Kinetics of Recombination of Iodine Atoms
Rabinowitch, E. / Wood, W. C. | 1936
The Homogeneous Unimolecular Decomposition of Gaseous Alkyl Nitrites VI. The Decomposition of n‐Butyl Nitrite
Steacie, E. W. R. / Smith, W. McF. | 1936
The Normal Vibrations and the Isotope Effect of Molecules of the Type X2YN with an N‐Fold Axis of Symmetry
Schimmel, Herbert | 1936
Transfer of Rotational Energy in Molecular Collisions I. Elementary Processes Which Lead to Abnormal Rotation of the HgH Molecule
Rieke, F. F. | 1936
The Effect of Rotational Distortion on the Thermodynamic Properties of Water and Other Polyatomic Molecules
Wilson, E. Bright | 1936
Thermodynamic Properties of Phosphorus Compounds
Anderson, Thomas F. / Yost, Don M. | 1936
Atomic Dimensions from the Coefficients of Compressibility and Thermal Expansion
Djang, G. F. | 1936
The Structure of Rubrene and Some Remarks on the ``Ortho‐Effect''
Bergmann, E. / Herlinger, E. | 1936
The Raman Spectra of Deutero‐acetones and Methyl Alcohol‐d
Bates, J. R. / Anderson, Leigh C. / Halford, J. O. | 1936
Raman Spectrum of Deutero‐Acetaldehyde
Wood, R. W. | 1936
Preliminary Note on the Phase Relationships in the Nickel‐Tin System
Fetz, Erich / Jette, Eric R. | 1936