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Fluoride ion as a nucleophile and a leaving group in aromatic nucleophilic substitution reactions (English)

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In: Journal of Fluorine Chemistry   ;  61 ,  3  ;  193-216  ;  1992
  • ISSN:
    0022-1139
  • Article (Journal)  /  Electronic Resource

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Abstract This paper analyzes the behaviour of the fluoride ion as a nucleophile and a leavinggroup in S NAr reactions in the gas phase and in solution. Attention is focused onquantitative data relating to fluoride ion reactivity in S NAr reactions relative to otherhalide ions and groups. The factors governing the regioselectivity of fluorine atomsubstitution in S NAr reactions are discussed, as well as the synthetic consequences ofsuch substitution.

  • Title:
    Fluoride ion as a nucleophile and a leaving group in aromatic nucleophilic substitution reactions
  • Author / Creator:
    Vlasov, V.M.
  • Published in:
    Journal of Fluorine Chemistry ; 61 ; 3 ; 193-216
  • Publisher:
    • New search for:
  • Publication date:
    1992-07-08
  • Size:
    24 pages
  • ISSN:
    0022-1139
  • DOI:
    https://doi.org/10.1016/S0022-1139(00)80104-9
  • Type of media:
    Article (Journal)
  • Type of material:
    Electronic Resource
  • Language:
    English
  • Source:
    Elsevier
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  • Citation:

Table of contents – Volume 61, Issue 3

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The tables of contents are generated automatically and are based on the data records of the individual contributions available in the index of the TIB portal. The display of the Tables of Contents may therefore be incomplete.

193
Fluoride ion as a nucleophile and a leaving group in aromatic nucleophilic substitution reactions
Vlasov, V.M. | 1992
217
A novel synthesis of per(poly)fluoroalkyl aldehydes
Hu, Chang-Ming / Tang, Xiao-Qing | 1992
223
Trifluoromethylthiocopper — stability and reaction chemistry
Clark, James H. / Smith, Helen | 1992
233
Products of the condensation reaction of 2-(4-fluorobenzoyl)benzoic acid with m-cresol
Gronowska, J. / Kalinowska, A. | 1992
239
Anionic polymerization of fluorine-containing vinyl monomers. II. �-Fluoroacrylates
Narita, T. / Hagiwara, T. / Hamana, H. / Arai, H. | 1993
239
Anionic polymerization of fluorine-containing vinyl monomers. 11. a-Fluoro-acrylates
Narita, T. / Hagiwara, T. / Hamana, H. / Arai, H. / Okajima, Y. | 1993
239
Anionic polymerization of fluorine-containing vinyl monomers. 11. α-Fluoroacrylates
Narita, Tadashi / Hagiwara, Tokio / Hamana, Hiroshi / Arai, Hideo / Okajima, Yogo | 1992
247
A convenient palladium-catalyzed synthesis of a-fluoro-a,b-unsaturated esters
Shen, Y. / Zhou, Y. | 1993
247
A convenient palladium-catalyzed synthesis of α-fluoro-α,β-unsaturated esters
Shen, Yanchang / Zhou, Yuefen | 1992
253
Synthesis of perfluoro-oxa-alkylated compounds by the use of perfluoro-oxa-alkanoyl peroxides and their applications
Sawada, Hideo | 1992
273
A new one-pot synthesis of trifluoromethyl-2-enyl and 2,4-enynyl amides
Shen, Yanchang / Gao, Shu | 1992
279
Trifluoromethylation of organic halides with methyl halodifluoroacetates — a process via difluorocarbene and trifluoromethide intermediates
Duan, Jian-Xing / Su, De-Bao / Chen, Qing-Yun | 1992

How to get this document?

Download
Download

Download is DRM protected.

Commercial Copyright fee: €36.00 Basic fee: €4.00 Total price: €40.00
Academic Copyright fee: €36.00 Basic fee: €2.00 Total price: €38.00
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