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    Kinetic regularities of thermal transformations in nanosized bismuth films (English)

    In: Russian Journal of Physical Chemistry A ; 86 , 4 ; 621-627  ; 2012

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    Abstract Transformations in a nanosized bismuth layer are studied by means of optical spectroscopy, microscopy, and gravimetry, depending on the thickness (d = 3–120 nm), thermal treatment temperature (T = 373–673 K) and time (τ] = 0.05–2500 min). It is established that, depending on the initial thickness of the bismuth films and the thermal treatment temperature, the kinetic curves of the degree of transformation are satisfactorily described within linear, inverse logarithmic, cubic, and logarithmic laws. The contact potential difference for the Bi, Bi2O3 films and the photo-electromotive force for the Bi-Bi2O3 systems is measured. An energy-band diagram for the Bi-Bi2O3 systems is constructed. A model for the thermal transformation of Bi films that includes the stage of oxygen adsorption, the redistribution of charge carriers in the Bi-Bi2O3 contact field, and the formation of bismuth(III) oxide is proposed.

    Table of contents – Volume 86, Issue 4

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    The tables of contents are generated automatically and are based on the data records of the individual contributions available in the index of the TIB portal. The display of the Tables of Contents may therefore be incomplete.

    527
    The standard enthalpies of formation and thermal stability of diacyldiperoxides
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    533
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    Zagnit’ko, A. V. / Ignat’ev, V. V. et al. | 2012
    539
    Thermodynamics of cross-linked and branched (co)polymers based on tris- and bis-(pentafluorophenyl)germanes
    Smirnova, N. N. / Zakharova, Yu. A. / Ruchenin, V. A. / Zamyshlyayeva, O. G. et al. | 2012
    548
    Formation energies of molecules and anions of europium bromides
    Butman, M. F. / Sergeev, D. N. / Motalov, V. B. / Kudin, L. S. / Krämer, K. W. et al. | 2012
    553
    Structure of associates of vinyl molecules and maleic anhydride in CCl4 solution
    Zaitseva, V. V. / Tyurina, T. G. / Shtonda, A. V. / Zaitsev, S. Yu. et al. | 2012
    563
    Density and viscosity of methanol-heptane (octane) mixtures at low alkane concentrations over the temperature range 288.15–328.15 K
    Dyshin, A. A. / Eliseeva, O. V. / Kiselev, M. G. et al. | 2012
    568
    Thermophysical and thermoacoustical properties of benzaldehyde mixtures with ethylbenzene at 303.15, 308.15, and 313.15 K and a pressure of 0.1 MPa
    Saravanakumar, K. / Lavanya, T. G. / Baskaran, R. / Kubendran, T. R. et al. | 2012
    577
    Maleic acid solvation in mixed water-ethanol solvents
    Usacheva, T. R. / Kuz’mina, I. A. / Sharnin, V. A. / Tukumova, I. R. et al. | 2012
    580
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    Li, Hua / Wang, Hongkai / Chen, Xiaoshuang / Zhao, Lei et al. | 2012
    584
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    Levanov, A. V. / Antipenko, E. E. / Lunin, V. V. et al. | 2012
    590
    Phase formation in the LiCl-LiNO3-KCl-Sr(NO3)2 system
    Gasanaliev, A. M. / Gamataeva, B. Yu. / Umarova, Yu. A. et al. | 2012
    595
    Electronic states of XC3H3Si five-membered rings (X = CH, N, P, and As)
    Vessally, E. / Edjlali, L. / Shabrendi, H. / Rezaei, M. et al. | 2012
    600
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    606
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    Kuznetsova, T. G. / Sadykov, V. A. / Lunin, V. V. et al. | 2012
    621
    Kinetic regularities of thermal transformations in nanosized bismuth films
    Surovoi, E. P. / Bugerko, L. N. / Surovaya, V. E. / Bin, S. V. et al. | 2012
    628
    Silica-supported vanadium oxide nanoparticles as efficient heterogeneous catalyst for hydrolysis of sucrose
    Samadani Langeroodi, N. et al. | 2012
    632
    The influence of fluctuation inhomogeneity in a volume phase on one-layer adsorption
    Bulavin, L. A. / Gavryushenko, D. A. / Sysoev, V. M. / Yakunov, P. A. et al. | 2012
    635
    Adsorption isotherms of linoleic and linolenic acids from solutions in carbon tetrachloride on surfaces of highly dispersed manganese and copper ferrites
    Balmasova, O. V. / Korolev, V. V. / Ramazanova, A. G. et al. | 2012
    639
    Adsorption and electrophysical properties of semiconductors of the InSb-CdS system
    Kirovskaya, I. A. / Filatova, T. N. et al. | 2012
    645
    Reductive sorption of molecular oxygen from water by nanodisperse metals in an ion-exchanger matrix
    Polyanskii, L. N. / Khorol’skaya, S. V. / Kravchenko, T. A. / Peshkov, S. V. / Kipriyanova, E. S. / Starodubova, S. P. et al. | 2012
    653
    Thermodynamic and kinetic parameters of ofloxacin adsorption from aqueous solution onto modified coal fly ash
    Zhang, C. -L. / Zhao, F. / Wang, Y. et al. | 2012
    658
    Model of the nucleation and growth of amorphous and crystalline films of diamond-like materials: The (100) plane
    Tarala, V. A. / Sinel’nikov, B. M. et al. | 2012
    664
    The states of hydrogen adsorbed on the surface of skeleton nickel
    Ryazanov, M. A. et al. | 2012
    667
    Effect of the relaxation of high-frequency vibrational modes on the kinetics of charge separation and recombination
    Rogozina, M. V. / Ionkin, V. N. / Ivanov, A. I. et al. | 2012
    675
    Improved visible light photocatalytic activity of titania loaded with silver on discoloration of a heterocyclic aromatic chemical dye solution
    Zhang, Dongfang et al. | 2012
    681
    Carboxylato-bis-dibenzoylmethanates of europium(III): Luminescence and magnetic properties
    Tkachenko, I. A. / Petrochenkova, N. V. / Mirochnik, A. G. / Karasev, V. E. / Kavun, V. Ya. et al. | 2012
    685
    The precipitation of the dispersed phase of liquid medium impurities in a magnetized ferrito-ferromagnetic nozzle
    Garashchenko, V. I. / Garashchenko, A. V. / Luk’yanchuk, A. P. et al. | 2012
    689
    Photocatalytic degradation of anionic surfactant using zinc oxide nanoparticles
    Giahi, M. / Habibi, S. / Toutounchi, S. / Khavei, M. et al. | 2012
    694
    Thermochemical characteristics of nicotinamide protolytic equilibria in water-dimethylsulfoxide mixtures
    Grazhdan, K. V. / Gamov, G. A. / Dushina, S. V. / Sharnin, V. A. et al. | 2012
    697
    An empirical equation of state of liquid diethyl ketone for isochoric processes at 333–513 K
    Atoyan, V. A. et al. | 2012
    700
    Thermodynamic properties of sophocarpine and oxysophocarpine alkaloids in aqueous glucose solutions
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    702
    The temperature dependence of mercury saturated vapor pressure over the whole range of its liquid state
    Turdukozhaeva, A. M. et al. | 2012
    705
    Refinement of taking into account molecule sizes in the lattice gas model
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    709
    On the presumed kinetic consequences of pre-equilibrium. Implications for the Michaelis-Menten equation
    Chandrasekhar, S. et al. | 2012

    How to get this title?

    Check access
    Download
    Commercial Copyright fee: €39.95 Basic fee: €4.00 Total price: €43.95
    Academic Copyright fee: €15.00 Basic fee: €2.00 Total price: €17.00

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