Multipolymers with Fischer‐Tropsch olefins (English)

in Macromolecular Symposia ; 193 , 1 ; 13-28
Macromolecular Symposia


Multipolymers consisting of ethylene, 1‐heptene, 3‐methylpentene and 4‐methylpentene were prepared with a heterogeneous Ziegler‐Natta catalyst. The polymers were prepared in such a way that the molar fraction of the comonomers remained the same. Copolymers of ethylene/1‐heptene and ethylene/4‐methylpentene were prepared in order to study the changes in polymer characteristics as one moves from an ethylene/linear alpha olefin copolymer through ethylene multipolymers to an ethylene/4‐methylpentene copolymer. The mechanical, rheological and application properties showed expected trends.

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Table of contents – Volume 193, Issue 1

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New materials by polymerisation of olefins and styrene with metallocene catalysts
Kaminsky, Walter / Tran, Phu‐Dennis / Weingarten, Ulrich | 2003
Multipolymers with Fischer‐Tropsch olefins
Tincul, Ioan / Smith, Jaco / van Zyl, Pieter | 2003
Recent advances in the development of Fischer‐Tropsch catalysts at sasol
Bromfield, Tracy C. / Vosloo, Anton C. | 2003
Monitoring thermo‐oxidative degradation of polypropylene by CRYSTAF and SEC‐FTIR
de Goede, Stefan / Brüll, Robert / Pasch, Harald / Marshall, Niall | 2003
13C NMR studies of olefin copolymer microstructure: a tool for understanding active center behavior in ansa‐zirconocene‐based catalysis
Sacchi, Maria Carmela / Forlini, Fabrizio / Losio, Simona / Tritto, Incoronata / Locatelli, Paolo | 2003
Propene copolymers: an overview of recent research
van Reenen, Albert J. | 2003
Kinetic evaluation of various isospecific active sites on MgCl2‐supported Ziegler catalysts
Nishiyama, Isa / Liu, Boping / Matsuoka, Hitoshi / Nakatani, Hisayuki / Terano, Minoru | 2003
Toughening polypropylene with nanoscale rubber particles
Liu, Yiqun / Zhang, Manli / Zhang, Xiaohong / Gao, Jianming / Wei, Genshuan / Huang, Fan / Song, Zhihai / Qiao, Jinliang | 2003
Molecular characterization of functional polymers and oligomers by liquid chromatography
Trathnigg, Bernd / Rappel, Christina / Hoedl, Renate | 2003
Characterization of epoxy prepreg SPX 8800 system by isothermal differential scanning calorimetry
Wang, Qian / Storm, Birgit K. | 2003
Analysis of polyamides by size exclusion chromatography and laser light scattering
Chen, Jinglu / Radke, Wolfgang / Pasch, Harald | 2003
Fluorescence and biochemical characterization of glycated hemoglobin
Vigneshwaran, Nadanathangam / Bijukumar, Gopalakrishnapillai / Karmakar, Nivedita / Anand, Sneh / Misra, Anoop | 2003
Matrix‐assisted laser desorption/ionization mass spectrometry of synthetic polymers. 7. analysis of fatty alcohol ethoxylates by coupled liquid chromatography at the critical point of adsorption and MALDI‐TOF mass spectrometry
Spriestersbach, Karl‐Heinz / Rode, Karsten / Pasch, Harald | 2003
Triblock copolymers of lactide with poly(ethylene glycol) and influence of stereochemical composition
Onyari, John M. / Huang, Samuel J. | 2003
Synthesis and characterization of novel soluble and thermally stable polyamides based on pyridine monomer
Mehdipour‐Ataei, Shahram / Heidari, Hani | 2003
Ultraviolet (UV) curing of phosphated polyurethane‐acrylic dispersions
Mequanint, Kibret / Sanderson, Ronald D. | 2003
Low molar mass poly(styrene‐co‐acrylic acid) amphiphilic block copolymers: synthesis and characterization
Karakatsanis, Ekaterini / Focke, Walter / Summers, Gabriel | 2003
Investigation into the interactions between filler and elastomers used for tyre production
Costa, Giovanna / Dondero, Giovanni / Falqui, Luciano / Castellano, Maila / Turturro, Antonio / Valenti, Barbara | 2003
Copper‐mediated ATRP of methyl methacrylate in polar solvents using a bifunctional pyridinal diimine ligand
Iovu, Mihaela / Maithufi, Norah / Mapolie, Selwyn | 2003
The synthesis of HgS and CdS nanoparticles in polymer matrices
Sreekumari Nair, P. / Radhakrishnan, T. / Revaprasadu, N. | 2003
Water‐soluble polymeric materials with the ability to bind metal ions
Rivas, Bernabé L. / Pereira, Eduardo | 2003
The use of selected acrylate and acrylamide‐based surfmers and polysoaps in the emulsion polymerization of styrene
Tichagwa, Lilian / Götz, Christian / Tonge, Matthew / Sanderson, Ron / Pasch, Harald | 2003
Study of a new route by which to make fully cured thermoplastic elastomers with plastics and ultrafine powdered rubber
Zhang, Xiaohong / Wei, Genshuan / Liu, Yiqun / Gao, Jianming / Zhu, Yicai / Song, Zhihai / Huang, Fan / Zhang, Manli / Qiao, Jinliang | 2003
Electron spin resonance studies of reversible addition‐fragmentation transfer polymerisation
Calitz, F.M. / Tonge, M.P. / Sanderson, R.D. | 2003
RAFT polymerisation in water‐borne organic dispersions
Tonge, M.P. / McLeary, J.B. / Vosloo, J.J. / Sanderson, R.D. | 2003

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