Chemiluminescent iodine atom recombination (Englisch)

Nationallizenz
in Chemical Physics Letters ; 65 , 2 ; 251-256
Chemical Physics Letters
; 1979
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Abstract Photolysis of n-C3F7I at 266 nm produces metastable iodine atoms with a quantum yield of nearly 1. These particles have been observed to undergo spin-orbit relaxation in collisions with the parent molecules with a rate constant of (4.6 ± 0.3) × 10−17 cm3 molec−1 s−1. Excited and non-excited iodine atoms recombine in the presence of a third body to form I2 (B 3πOu +). The rate constant for this termolecular reaction is determined to be k 3 = (10 ± 5) × 10−33 cm6 molec−2 s−1 for the parent molecules as third bodies.

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