-
1
-
Level 1 — Case 1 A Surprise in the Synthesis of Guanacastepene A
-
1
-
Reactions of Aldehydes and Ketones and Their Derivatives
-
1
-
Reactions of Aldehydes and Ketones and Their Derivatives
-
7
-
Level 1 — Case 2 Sulfenylation of Indole
-
13
-
Level 1 — Case 3 Substrate Selective Reactions in the Presence of Lewis Acids
-
21
-
Level 1 — Case 4 Diastereoselective Reductions of β-Ketoesters
-
27
-
Level 1 — Case 5 Rearrangements from Tetrahydropyran Derivatives
-
33
-
Level 1 — Case 6 Stereospecific Substitution Reactions of Epoxy Sulfides
-
39
-
Level 1 — Case 7 NaBH<Subscript>4</Subscript> Reduction of α,β-Unsaturated Chromium Carbene Complexes
-
45
-
Reactions of Carboxylic, Phosphoric and Sulfonic Acids and Their Derivatives
-
47
-
Level 1 — Case 8 Addition of Hydroxylamines to α,β-Unsaturated Esters
-
49
-
Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and Their Derivatives
-
55
-
Level 1 — Case 9 Solvolysis of Electron-Deficient Norbornyl Triflates
-
63
-
Level 1 — Case 10 Nucleophile Versus Base Catalysis
-
69
-
Level 1 — Case 11 The Hydrolysis of <Emphasis Type="Italic">p</Emphasis>-Substituted Styrene Oxides
-
79
-
Level 1 — Case 12 Elimination Reactions of Benzaldehyde <Emphasis Type="Italic">O</Emphasis>-Benzoyloximes
-
87
-
Level 1 — Case 13 Oxygen Versus Sulfur Stabilization of Carbenium Ions
-
97
-
Level 1 — Case 14 Cyclization of 2,3-Dibenzylidenesuccinates
-
101
-
Level 1 — Case 15 Oxazoline <Emphasis Type="Italic">N</Emphasis>-Oxides as Dipoles in [3+2] Cycloadditions
-
107
-
Level 1 — Case 16 Light-Induced Cycloadditions of <Emphasis Type="BoldItalic">N</Emphasis>-Phthaloyl α-Amino Acids
-
113
-
Level 2 — Case 17 Change in Rate-Determining Step in an E1cB Mechanism: Aminolysis of Sulfamate Esters
-
115
-
Radical Reactions: Part 1
-
119
-
Level 2 — Case 18 Unusual Diels-Alder Reactivity of Acyclic 2-Azadienes
-
125
-
Level 2 — Case 19 Chelate-Controlled Carbonyl Addition Reactions
-
125
-
Radical Reactions: Part 1
-
131
-
Level 2 — Case 20 Esterification of Carboxylic Acids with Dimethyl Carbonate and DBU
-
139
-
Level 2 — Case 21 A Hammett Analysis in a Multistep Reaction: Rhodium(II)-Catalyzed Decomposition of α-Diazo Esters
-
145
-
Level 2 — Case 22 Tandem Cycloadditions with Nitronates
-
149
-
Radical Reactions: Part 2
-
153
-
Level 2 — Case 23 Hydrolysis of 2-Aminobenzoate Esters
-
159
-
Level 2 — Case 24 Rearrangements of Cyclobutenones
-
163
-
Level 2 — Case 25 Epoxi Ester-Orthoester Rearrangement
-
163
-
Radical Reactions: Part 2
-
169
-
Level 2 — Case 26 2-Chloro-1,3,5-triazines as Activating Groups of Carboxylic Acids in the Formation of Peptide Bonds
-
177
-
Level 2 — Case 27 Acid-Catalyzed Isomerization of Imines
-
179
-
Oxidation and Reduction
-
183
-
Level 2 — Case 28 A Dearomatizing Disrotatory Electrocyclic Ring Closure
-
189
-
Level 2 — Case 29 Stereoselective Debromination of Vicinal Dibromides
-
197
-
Level 2 — Case 30 Diels-Alder Reactions of <Emphasis Type="Italic">N</Emphasis>-Acyl-1,2,4,5-tetrazines
-
203
-
Level 2 — Case 31 Stereoselective Synthesis of 2-Acylaziridines
-
203
-
Oxidation and Reduction
-
209
-
Carbenes and Nitrenes
-
211
-
Level 3 - Case 32 The Baylis-Hillman Reaction
-
217
-
Level 3 - Case 33 The Rate-Determining Step in the S<Subscript>N</Subscript>Ar Reaction
-
225
-
Level 3 - Case 34 Helicenophanes and their Racemization
-
229
-
Nucleophilic Aromatic Substitution
-
231
-
Level 3 - Case 35 Solvolysis of Vinyl Iodonium Salts
-
237
-
Level 3 - Case 36 Vicarious Nucleophilic Substitution
-
239
-
Electrophilic Aromatic Substitution
-
243
-
Level 3 - Case 37 Base-promoted HF Elimination from 4-Fluoro-4-(4’nitrophenyl)butan-2-one
-
249
-
Carbocations
-
251
-
Level 3 - Case 38 Substitution of β-Halostyrenes by MeS<Superscript>-</Superscript>
-
259
-
Carbenes and Nitrenes
-
259
-
Level 3 - Case 39 Periodinane-Mediated Cyclization of Anilides
-
269
-
Level 3 - Case 40 Solvolysis of 8-Deltacyclyl Brosylates
-
277
-
Nucleophilic Aliphatic Substitution
-
283
-
Nucleophilic Aromatic Substitution
-
295
-
Electrophilic Aromatic Substitution
-
305
-
Carbocations
-
307
-
Carbanions and Electrophilic Aliphatic Substitution
-
341
-
Nucleophilic Aliphatic Substitution
-
351
-
Elimination Reactions
-
373
-
Carbanions and Electrophilic Aliphatic Substitution
-
375
-
Addition Reactions: Polar Addition
-
413
-
Elimination Reactions
-
427
-
Addition Reactions: Cycloaddition
-
443
-
Addition Reactions: Polar Addition
-
475
-
Molecular Rearrangements
-
499
-
Addition Reactions: Cycloaddition
-
553
-
Molecular Rearrangements
-
601
-
Author Index
-
643
-
Subject Index
-
669
-
Author Index
-
711
-
Subject Index
-
i
-
Front Matter
-
i
-
Front Matter