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Organic Chemistry [1978]

1
Bimolecular electron transfer reactions of the excited states of transition metal complexes
1
Chairman's Opening Remarks
1
Free Radical Reactions
1
Introduction
1
Introduction
1
One-Determinental Theory of Chemical Reactivity
1
Stereochemistry of penta- and hexacoordinate phosphorus derivatives
2
Properties
3
Introduction
3
The Principle
5
Biosynthesis in Theory and Practice: Structure Determinations
10
Inclusion Complex Formation
15
Alkanes and Alkenes
16
Chemical Details of the Method
18
Configuration Interaction Overview of Chemical Reactivity
24
Aromatic, Heteroaromatic, and Fluoroaromatic Compounds
25
Ideas and Experiments in Biosynthesis
28
Catalyses by Cyclodextrins Leading to Practical Usages of Cyclodextrins
31
The Dynamic Linear Combination of Fragment Configurations Method
33
Covalent Catalyses
41
Halogen Compounds
49
Complex bases and complex reducing agents new tools in organic synthesis
50
Noncovalent Catalyses
51
Alcohols
51
Even-Even Intermolecular Multicentric Reactions
53
Design of a Specific Oxidant for Phenols
61
Asymmetric Catalyses by Cyclodextrins
61
Ethers, Peroxides, and Hydroperoxides
65
Improvement by Covalent and Noncovalent Modification
65
Photochemical reactivity of keto imino ethers
67
Synthesis of Sesquiterpenoids of Biogenetic Importance
69
Aldehydes and Ketones
72
Automatization of the Merrifield Peptide Synthesis
79
Conclusion
81
Carboxylic Acids and Their Derivatives
81
Critical View on the Applicability of the Merrifield Synthesis
85
Rules for Ring Closure
87
Conclusion
88
References
92
Nitrogen-containing Compounds
97
Computational methods of correlation energy
101
The Problem of Correlation Imposed Barriers
104
Reactivity Trends of Thermal Cycloadditions
105
Complex bases and complex reducing agents new tools in organic synthesis
107
Some Recent Developments in Quantum Organic Chemistry
111
Sulfur-containing Compounds
121
Organometallic Compounds
125
Aromatic and heteroaromatic compounds by electrocyclic ring-closure with elimination
126
Reactivity Trends of Singlet Photochemical Cycloadditions
131
Biomimetic Syntheses of Phenols from Polyketones
134
Stable Free Radicals
141
Naturally Ocurring and Related Compounds
147
Miscellaneous Intermolecular Multicentric Reactions
149
Selective Homogeneous and Heterogeneous Catalysis
154
π + σ Addition Reactions
160
Even-Odd Multicentric Intermolecular Reactions
165
A quantitative measure of chemical chirality and its application to asymmetric synthesis
167
Potential Energy Surfaces for Odd-Odd Multicentric Intermolecular Reactions
171
Even-Even Intermolecular Bicentric Reactions
175
Studies on Enzyme Models and on the Enzyme Carboxypeptidase A
186
Even-Odd Intermolecular Bicentric Reactions
192
Odd-Odd Intermolecular Bicentric Reactions. Potential Energy Surfaces for Geometric Isomerization and Radical Combination
198
Odd-Odd Intramolecular Multicentric Reactions
203
Summing Up
205
Index of Contributors
207
Subject Index
215
Even-Even Intramolecular Multicentric Reactions
221
Mechanisms of Electrocyclic Reactions
226
Triplet Reactivity
231
Some newer aspects of mass spectrometric <Emphasis Type="Italic">ortho</Emphasis> effects
250
Photophysical Processes
255
The Importance of Low Lying Nonvalence Orbitals
257
Divertissements
262
A Contrast of “Accepted” Concepts of Organic Reactivity and the Present Work
271
Epilogue
i
Frontmatter
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