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1
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Bimolecular electron transfer reactions of the excited states of transition metal complexes
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1
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Chairman's Opening Remarks
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1
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Free Radical Reactions
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1
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Introduction
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1
-
Introduction
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1
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One-Determinental Theory of Chemical Reactivity
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1
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Stereochemistry of penta- and hexacoordinate phosphorus derivatives
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2
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Properties
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3
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Introduction
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3
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The Principle
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5
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Biosynthesis in Theory and Practice: Structure Determinations
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10
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Inclusion Complex Formation
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15
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Alkanes and Alkenes
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16
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Chemical Details of the Method
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18
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Configuration Interaction Overview of Chemical Reactivity
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24
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Aromatic, Heteroaromatic, and Fluoroaromatic Compounds
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25
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Ideas and Experiments in Biosynthesis
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28
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Catalyses by Cyclodextrins Leading to Practical Usages of Cyclodextrins
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31
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The Dynamic Linear Combination of Fragment Configurations Method
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33
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Covalent Catalyses
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41
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Halogen Compounds
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49
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Complex bases and complex reducing agents new tools in organic synthesis
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50
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Noncovalent Catalyses
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51
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Alcohols
-
51
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Even-Even Intermolecular Multicentric Reactions
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53
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Design of a Specific Oxidant for Phenols
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61
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Asymmetric Catalyses by Cyclodextrins
-
61
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Ethers, Peroxides, and Hydroperoxides
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65
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Improvement by Covalent and Noncovalent Modification
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65
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Photochemical reactivity of keto imino ethers
-
67
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Synthesis of Sesquiterpenoids of Biogenetic Importance
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69
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Aldehydes and Ketones
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72
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Automatization of the Merrifield Peptide Synthesis
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79
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Conclusion
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81
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Carboxylic Acids and Their Derivatives
-
81
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Critical View on the Applicability of the Merrifield Synthesis
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85
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Rules for Ring Closure
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87
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Conclusion
-
88
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References
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92
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Nitrogen-containing Compounds
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97
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Computational methods of correlation energy
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101
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The Problem of Correlation Imposed Barriers
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104
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Reactivity Trends of Thermal Cycloadditions
-
105
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Complex bases and complex reducing agents new tools in organic synthesis
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107
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Some Recent Developments in Quantum Organic Chemistry
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111
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Sulfur-containing Compounds
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121
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Organometallic Compounds
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125
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Aromatic and heteroaromatic compounds by electrocyclic ring-closure with elimination
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126
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Reactivity Trends of Singlet Photochemical Cycloadditions
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131
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Biomimetic Syntheses of Phenols from Polyketones
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134
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Stable Free Radicals
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141
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Naturally Ocurring and Related Compounds
-
147
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Miscellaneous Intermolecular Multicentric Reactions
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149
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Selective Homogeneous and Heterogeneous Catalysis
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154
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π + σ Addition Reactions
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160
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Even-Odd Multicentric Intermolecular Reactions
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165
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A quantitative measure of chemical chirality and its application to asymmetric synthesis
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167
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Potential Energy Surfaces for Odd-Odd Multicentric Intermolecular Reactions
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171
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Even-Even Intermolecular Bicentric Reactions
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175
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Studies on Enzyme Models and on the Enzyme Carboxypeptidase A
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186
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Even-Odd Intermolecular Bicentric Reactions
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192
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Odd-Odd Intermolecular Bicentric Reactions. Potential Energy Surfaces for Geometric Isomerization and Radical Combination
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198
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Odd-Odd Intramolecular Multicentric Reactions
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203
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Summing Up
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205
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Index of Contributors
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207
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Subject Index
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215
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Even-Even Intramolecular Multicentric Reactions
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221
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Mechanisms of Electrocyclic Reactions
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226
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Triplet Reactivity
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231
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Some newer aspects of mass spectrometric <Emphasis Type="Italic">ortho</Emphasis> effects
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250
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Photophysical Processes
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255
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The Importance of Low Lying Nonvalence Orbitals
-
257
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Divertissements
-
262
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A Contrast of “Accepted” Concepts of Organic Reactivity and the Present Work
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271
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Epilogue
-
i
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Frontmatter