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Inhaltsverzeichnis
4065
Titelbild: A Supramolecular Approach to Organic Alloys: Cocrystals and Three‐ and Four‐Component Solid Solutions of 1,4‐Diazabicyclo[2.2.2]octane and 4‐X‐Phenols (X=Cl, CH3, Br) (Angew. Chem. 22/2007)
Dabros, Marta
/ Emery, Paul R.
/ Thalladi, Venkat R.et al.
| 2007
Innentitelbild: Aerobic Oxidation of Alcohols at Room Temperature and Atmospheric Conditions Catalyzed by Reusable Gold Nanoclusters Stabilized by the Benzene Rings of Polystyrene Derivatives (Angew. Chem. 22/2007)
Ursprünge und Entwicklung der Begriffe Chiralität und Händigkeit in der chemischen SpracheFNR HREF="nss"> FN ID="nss"> Diese Arbeit wurde vom spanischen Ministerium für Erziehung und Wissenschaft (Fördernummer CTQ2005-07676) gefördert.
Supportless Pt and PtPd Nanotubes as Electrocatalysts for Oxygen-Reduction ReactionsFNR HREF="nss"> FN ID="nss"> This work was financially supported by the Department of Energy, the Pacific Fuel Cell Corp., and a UC Discovery Grant. We thank Dr. R. R. Adzic of Brookhaven National Laboratory for helpful discussion and encouragement.
Para-Hydrogen-Enhanced Hyperpolarized Gas-Phase Magnetic Resonance ImagingFNR HREF="nss"> FN ID="nss"> This work was supported by the Director, Office of Science, Office of Basic Energy Sciences, Materials Sciences and Engineering Division, of the U.S. Department of Energy (contract no. DE-AC03-76SF00098) and the CRDF (grant RU-C1-2581-NO-04) and was partially supported by grants from the RFBR (05-03-32472), SB RAS (integration grant no. 11), RAS (5.1.1 and 5.2.3), and the Russian President's Program of Support of the Leading Scientific Schools (grant NSch-4821.2006.3). S.R.B. thanks the U.S. Department of Homeland Security for support through a graduate fellowship, administered by ORISE under the DOE contract number DE-AC05-06OR23100. I.V.K. thanks the Russian Science Support Foundation for financial support.
Stereoselective Simmons-Smith Cyclopropanation of Chiral EnamidesFNR HREF="nss"> FN ID="nss"> We thank NIH-NIGMS (GM066055) and UW-Madison for financial support. We also thank Ben Kucera and Vic Young for solving the X-ray crystal structures.
A Hexacopper Fluoro Metallacrown Cavitand and its Alkali-Metal ComplexesFNR HREF="nss"> FN ID="nss"> The authors would like to thank Dr. H. J. Blythe (University of Sheffield) for the susceptibility measurements and the Leverhulme Trust and EPSRC for funding.
Synthesis of the Carbocyclic Core of Zoanthenol: Implementation of an Unusual Acid-Catalyzed CyclizationFNR HREF="nss"> FN ID="nss"> The authors wish to thank the Fannie and John Hertz Foundation (predoctoral fellowship to D.C.B), Novartis (predoctoral fellowship to J.L.S.), Merck, Pfizer, and Lilly for financial support.
Development and Biological Assessment of Fully Water-Soluble Helical Aromatic Amide FoldamersFNR HREF="nss"> FN ID="nss"> This work was supported by the European Commission (Marie Curie Postdoctoral Fellowship to E.R.G.) and by the Conseil Régional d'Aquitaine. We thank Katell Bathany for mass spectroscopy data.
Singlet Diradical Character of an Oxidized Ruthenium Trithiolate: Electronic Structure and ReactivityFNR HREF="nss"> FN ID="nss"> This research was supported in part by the National Science Foundation (CHE-0238137) and by the National Center for Supercomputing Applications utilizing the University of Kentucky High Performance Computing System. Acknowledgement is made to the Donors of the American Chemical Society Petroleum Research Fund (43917-AC3) for partial support of this work.
A Supramolecular Multiposition Rotary DeviceFNR HREF="nss"> FN ID="nss"> This work was supported by the Swiss National Science Foundation, the NCCR "Nanoscale Science", and the European Union through the Marie Curie Research Training Network PRAIRIES (MRTN-CT-2006-035810). We thank the Swiss Federal Commission for Technology and Innovation, KTI, and Nanonis Inc. for the fruitful collaboration on the data-acquisition system.
Colorimetric Detection of Mercuric Ion (Hg2+) in Aqueous Media using DNA-Functionalized Gold NanoparticlesFNR HREF="nss"> FN ID="nss"> C.A.M. acknowledges AFOSR, ARO, NSEC-NSF, and NIH for support of this research. C.A.M. is also grateful for a NIH Director's Pioneer Award.
"Intelligent" Fingerprinting: Simultaneous Identification of Drug Metabolites and Individuals by Using Antibody-Functionalized NanoparticlesFNR HREF="nss"> FN ID="nss"> This work was supported by the EPSRC (grant EP-D041007-1 and grant EP-D041082-1 for D.A.R. and S.M.J., respectively).
Molecular Printboards as a General Platform for Protein Immobilization: A Supramolecular Solution to Nonspecific AdsorptionFNR HREF="nss"> FN ID="nss"> We are grateful for financial support from the Council for Chemical Sciences of the Netherlands Organization for Scientific Research (NWO-CW) (M.J.W.L.; Vidi Vernieuwingsimpuls grant 700.52.423 to J.H.). Dr. M. Crego Calama is acknowledged for fruitful discussions.
Discovering and Verifying Elusive Fullerene Cage Isomers: Structures of C2-p11-(C74-D3h)(CF3)12 and C2-p11-(C78-D3h(5))(CF3)12FNR HREF="nss"> FN ID="nss"> This work was supported by the U.S. NIH (R01-EB000703-03 to R.D.B.), the Fonds der Chemischen Industrie (Germany) (to K.S.), and the Civilian Research and Development Foundation (RUC2-2830-MO-06 to A.A.P. and S.H.S.).
Molecular Basis for Trehalase Inhibition Revealed by the Structure of Trehalase in Complex with Potent InhibitorsFNR HREF="nss"> FN ID="nss"> R.P.G. and T.M.G. contributed equally to this work. This work was funded by the Biotechnology and Biological Sciences Research Council (BBSRC). G.J.D. holds a Royal Society Wolfson Merit Award. The authors thank Anthony O'Sullivan (Syngenta) for the provision of compound 2 and for useful discussions.
Efficient Fluorescence Enhancement and Cooperative Binding of an Organic Dye in a Supra-biomolecular Host-Protein AssemblyFNR HREF="nss"> FN ID="nss"> We thank Vanya Uzunova at Jacobs University for help with the NMR experiments. The respective host institutions are also acknowledged for financial and academic support.
Extremely Stable Photoinduced Charge Separation in a Colloidal System Composed of Semiconducting Niobate and Clay NanosheetsFNR HREF="nss"> FN ID="nss"> This work was partly supported by a Grant-in-Aid for Scientific Research (no. 16350107) from the Ministry of Education, Culture, Sports, Science, and Technology, Japan. We thank the referees for their useful comments.
Honeycomb-Patterned Photoluminescent Films Fabricated by Self-Assembly of Hyperbranched PolymersFNR HREF="nss"> FN ID="nss"> Financial support from the National Basic Research Program (2007CB808000), the National Natural Science Foundation of China (nos. 20304007, 50473010, and 50633010), the Program for New Century Excellent Talents in University, the Foundation for the Author of National Excellent Doctoral Dissertation of China (no. 200527), and the Fok Ying Tung Education Foundation (no. 91013) are greatly appreciated. We thank Prof. S. K. Yan and S. D. Jiang in the Institute of Chemistry Chinese Academy of Sciences for helping with the TEM analysis.
A Supramolecular Approach to Organic Alloys: Cocrystals and Three‐ and Four‐Component Solid Solutions of 1,4‐Diazabicyclo[2.2.2]octane and 4‐X‐Phenols (X=Cl, CH3, Br)
Dabros, Marta
/ Emery, Paul R.
/ Thalladi, Venkat R.et al.
| 2007
[4+1]-[2+1] Cycloaddition Reactions of Fischer Carbene Complexes with α,β-Unsaturated Ketones and AldehydesFNR HREF="nss"> FN ID="nss"> Financial support for this work from the Spanish MCYT (MCT-2001-BQO-3853) and MEC (MEC-04-CTQ-2004-08077-C02-01-BQU) as well as from the FICYT (PR-01-GE-9 and IB05-136) is gratefully acknowledged.
Stereoselective Synthesis of Ferrocene‐Based C2‐Symmetric Diphosphine Ligands: Application to the Highly Enantioselective Hydrogenation of α‐Substituted Cinnamic Acids
Chen, Weiping
/ McCormack, Peter J.
/ Mohammed, Karimet al.
| 2007
Direct Electrochemical Characterization of Archaeal ThioredoxinsFNR HREF="nss"> FN ID="nss"> This work was supported by the Richard Allan Barry Fund at the Boston Foundation (SJE), the Boston University Undergraduate Research Opportunities Program (SEC), and the National Institutes of Health (GM65337 to C.L.D.; F31-GM073569 and T32-GM08334 to H.H.H.). The authors thank C. Becker and B. A. Brown II for technical assistance.
A Sesquineolignan with a Spirodienone Structure from Pinus sylvestris L.FNR HREF="nss"> FN ID="nss"> This work was supported by the National Technology Agency in Finland and by the Finnish Cultural Foundation (grant to M.K.).
Aerobic Oxidation of Alcohols at Room Temperature and Atmospheric Conditions Catalyzed by Reusable Gold Nanoclusters Stabilized by the Benzene Rings of Polystyrene DerivativesFNR HREF="nss"> FN ID="nss"> This work was partially supported by a Grant-in-Aid for Scientific Research from the Japan Society of the Promotion of Sciences (JSPS).
Aerobic Oxidation of Alcohols at Room Temperature and Atmospheric Conditions Catalyzed by Reusable Gold Nanoclusters Stabilized by the Benzene Rings of Polystyrene Derivatives
From a Stable Silylene to a Mixed‐Valent Disiloxane and an Isolable Silaformamide–Borane Complex with Considerable Silicon–Oxygen Double‐Bond Character
Yao, Shenglai
/ Brym, Markus
/ van Wüllen, Christophet al.
| 2007
From a Stable Silylene to a Mixed-Valent Disiloxane and an Isolable Silaformamide-Borane Complex with Considerable Silicon-Oxygen Double-Bond CharacterFNR HREF="nss"> FN ID="nss"> Financal support by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie is gratefully acknowledged.
Rewritable Imaging on the Surface of Frozen Ionic LiquidsFNR HREF="nss"> FN ID="nss"> We thank the University of Nottingham discipline bridging initiative and the EPSRC DICE project for funding this work. P.L. thanks the Leverhulme Trust for an Early Career Research Fellowship and H.T. thanks the EU-EST Probiomat for funding. Prof. D. Briggs, Prof. M. Poliakoff, and Prof. R. G. Jones are acknowledged for helpful discussion throughout.
Formation of Potentially Prebiotic Amphiphiles by Reaction of β-Hydroxy-n-alkylamines with CyclotriphosphateFNR HREF="nss"> FN ID="nss"> This work was carried out as part of EU COST action D27 "Prebiotic Chemistry and Early Evolution" and was funded by the Engineering and Physical Sciences Research Council through the provision of a studentship to L.B.M. We thank Prof. A. Eschenmoser and Prof. R. Krishnamurthy (The Scripps Research Institute, La Jolla, USA) for bringing reference [15] to our attention.
Photochemical and Radiolytic Production of an Organic Hydride Donor with a RuII Complex Containing an NAD+ Model LigandFNR HREF="nss"> FN ID="nss"> Work performed at Brookhaven National Laboratory was funded under contract DE-AC02-98CH10886 with the U.S. Department of Energy and supported by its Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences. NAD+=nicotinamide adenine dinucleotide.
Synthese von pentaantennären N-Glycanen mit Bisecting-GlcNAc und Core-FucoseFNR HREF="nss"> FN ID="nss"> Wir danken der Deutschen Forschungsgemeinschaft und dem Fonds der Chemischen Industrie für die Unterstützung dieser Arbeit.
Carbanionen mit zwei N-Substituenten als nucleophile Acyltransfer-ReagentienFNR HREF="nss"> FN ID="nss"> Wir danken der Deutschen Forschungsgemeinschaft und dem Fonds der Chemischen Industrie für finanzielle Unterstützung.
DNA-vermittelte Immobilisierung spezifischer Zelloberflächenliganden zur Herstellung von Mikroarrays mit lebenden ZellenFNR HREF="nss"> FN ID="nss"> Diese Arbeit wurde durch das Zentrum für Angewandte Chemische Genomik (ZACG), eine gemeinsame Forschungsinitiative der Europäischen Union und des Ministeriums für Innovation, Wissenschaft, Forschung und Technologie des Landes Nordrhein-Westfalen, unterstützt. Wir bedanken uns für die finanzielle Unterstützung des Forschungsprogramms "Molekulare Aspekte der Biowissenschaften" der Universität Dortmund.
DNA-Photographie: eine ultraempfindliche Methode zur Detektion von DNA mithilfe photographischer TechnikenFNR HREF="nss"> FN ID="nss"> Wir danken M. Hadden von Ilford, Dr. P. Bergthaller und Dr. K. Wagner für hilfreiche Diskussionen sowie der Volkswagen-Stiftung, der DFG und der BASF AG für finanzielle Unterstützung. A.M. dankt dem EU Marie Curie Training and Mobility Program unter dem Vertrag MRTN-CT-2003-505086 [CLUSTOXDNA] für ein Promotionsstipendium. J.G. und P.M.E.G. danken dem FCI bzw. dem Cusanuswerk für Promotionsstipendien. G.A.B. dankt der Alexander-von-Humboldt-Stiftung für ein Forschungsstipendium.