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Titelbild: Multicomponent Reactions for the Synthesis of Complex Piperidine Scaffolds (Angew. Chem. 32/2009)
A Spiro-Fused Triarylaminium Radical Cation with a Triplet Ground State This work was supported by a Grant-in-Aid for Scientific Research (C) from Japan Society for the Promotion of Science (JSPS). Numerical calculations were partly carried out at the Supercomputer Laboratory of the Institute for Chemical Research of Kyoto University.
Resonanzstrukturen und Elektronendichteanalyse Der Autor dankt Dr. C. Gatti (CNR-ISTM, Mailand) und Prof. A. Sironi (Universität Mailand) für ihre hilfreichen Kommentare. Diese Arbeit wurde vom Schweizerischen Nationalfonds unterstützt (Projekt 200021_125313). Auch dem UBELIX-Zentrum der Universität Bern wird gedankt.
Ein Kalium-modifiziertes Mg(NH2)2-2 LiH-System für die Wasserstoffspeicherung Wir danken der National University of Singapore, dem Dalian Institute of Chemical Physics und STINT für finanzielle Unterstützung sowie SNIC und UPPMAX für die Bereitstellung von Rechenzeit.
Herstellung von Proteinmustern durch Schreiben in proteinabweisende Matrizen Dieses Projekt wurde durch die DFG gefördert (ZH 63/9-2 und Te 247/6-2). Wir danken M. Grunze für seine Unterstützung und S. Schilp für die Hilfe bei der Elektronenstrahllithographie.
Niederkoordinierte Boridliganden: ein "echtes" Trimetalloboran Diese Arbeit wurde von der Deutschen Forschungsgemeinschaft und dem Fonds der Chemischen Industrie gefördert. R.D.D. dankt der Alexander-von-Humboldt-Stiftung für ein Stipendium.
Polystyrolsulfonylchlorid - ein hochorthogonales Linkerharz für die Synthese von Stickstoffheterocyclen Diese Arbeit wurde unterstützt von der Max-Planck-Gesellschaft, dem Fonds der Chemischen Industrie (Liebig-Stipendium für R.B.), der Deutschen Forschungsgemeinschaft (Br2324-1-1), dem Land Nordrhein-Westfalen und der Universität Leipzig.
Die zwei Strukturen des Hexafluorbenzol-Radikalkations C6F6.+ Wir danken der Deutschen Forschungsgemeinschaft und dem Fonds der Chemischen Industrie für finanzielle Unterstützung.
Molekularer Mechanismus der Inhibierung des Komplexes aus humanem Hsp90 und humanem Cdc37, einem Kinomchaperon‐Cochaperon‐System, durch das Triterpen Celastrol
Molekularer Mechanismus der Inhibierung des Komplexes aus humanem Hsp90 und humanem Cdc37, einem Kinomchaperon-Cochaperon-System, durch das Triterpen Celastrol Cdc37: Cell-division-cycle protein 37, Hsp90: Heat-shock protein 90. Wir danken Frédéric Tournay am Jardin Botanique de l'Université Louis Pasteur, Frankreich, für das Bild der Pflanze Tripterygium wilfordii. Die Arbeiten wurden vom SPINEII-Projekt der Europäischen Kommission und vom DFG-geförderten Cluster of Excellence: Macromolecular Complex unterstützt.
The Efficient One-Pot Reaction of up to Eight Components by the Union of Multicomponent Reactions This work was financially supported by the Dutch Science Foundation (NWO, VICI grant). Dr. M. T. Smoluch (Vrije Universiteit Amsterdam) and J. W. H. Peeters (University of Amsterdam) are kindly acknowledged for conducting HRMS measurements.
Synthesis of the Monomeric Unit of the Lomaiviticin Aglycon We thank Dr. D. H. Huang and Dr. L. Pasterneck for assistance with NMR spectroscopy and Dr. G. Siuzdak for assistance with mass spectrometry. Financial support for this work was provided by grants from the National Institutes of Health (U.S.A.) and the Skaggs Institute for Chemical Biology, and predoctoral fellowships from the American Chemical Society (A.L.N.) and Bristol-Myers Squibb (A.L.N.).
A Strategy for Producing Pure Single-Layer Graphene Sheets Based on a Confined Self-Assembly Approach We gratefully acknowledge the financial support from the National Science Foundation of China (20533050, 20772071, 50673048), transregional Project (TRR6) and 973 Program (2006CB806200).
Building Addressable Libraries: Site-Selective Lewis Acid (Scandium(III)) Catalyzed Reactions We thank the U.S. National Science Foundation (grant no.: CHE-0613077) and Combimatrix Co. for their generous support of our program.
Highly Water-Dispersible Biocompatible Magnetite Particles with Low Cytotoxicity Stabilized by Citrate Groups This work was supported by the NSF of China (20721063, 2021140537, 20871030, 20890120), the State Key Basic Research Program of the PRC (2006CB932302), Shanghai Leading Academic Discipline Project (B108), Shanghai Rising Star program (08A14010), and the Doctoral Program Foundation of the State Education Commission of China (200802461013).
Multicomponent Reactions for the Synthesis of Complex Piperidine Scaffolds This work was generously supported by UCB S.A. and IECB. We thank K. Bathany (mass spectra), A. Grelard (NMR), and B. Kauffmann (X-ray diffraction analyses) for their assistance and P. Talaga for his support.
Enzyme-Responsive Controlled Release Using Mesoporous Silica Supports Capped with Lactose The authors wish to express their gratitude to the Spanish Ministerio de Ciencia y Tecnología (projects CTQ2006-15456-C04-01 and CIBER-BBN CB07-01-2012) for their support. A.B. and E.A. are grateful to the Polytechnic University of Valencia and Spanish Ministerio de Ciencia e Innovación for grants.
Fe3O4 Core-Layered Double Hydroxide Shell Nanocomposite: Versatile Magnetic Matrix for Anionic Functional Materials This work was supported by the National Nature Foundation of China (grant no. 20633090), Shanghai Pujiang Program (grant no. 08PJ14035), and Shanghai Nature Science Foundation (grant no. 07ZR14028).
Triflic Acid Catalyzed Synthesis of Spirocycles via Acetylene Cations We thank the faculty members of the Instrumental Analysis Center at Tohoku University for the measurement of NMR and mass spectra.
Deglycosylation of Glucose Oxidase for Direct and Efficient Glucose Electrooxidation on a Glassy Carbon Electrode This research was financed by a European Young Investigator Award (EURYI) and la Région Aquitaine. We thank Prof. Heller for helpful discussions, Hassan Saadoui for help with the AFM experiments, and Maryse Maugey for help with the DLS experiments.
Towards Photocatalytic Alkane Oxidation: The Insertion of Dioxygen into a Platinum(II)-Methyl Bond We are grateful to BP Chemicals Ltd. and the EPSRC for a CASE award for R.A.T., and to Johnson Matthey for a generous loan of Pt salts. Peter Haycock and Dick Sheppard are thanked for NMR measurements, and Hugo Bronstein for his assistance with emission spectroscopy studies. Dr. Steve Rigby (Queen Mary University, London) is thanked for EPR measurements. G.J.P.B. thanks Prof. Gerhard Erker and the International Research Training Group (IRTG) for a Visiting Lectureship at the University of Münster in Germany during the writing of this paper.
Fusing Pentagons in a Fullerene Cage by Chlorination: IPR D2-C76 Rearranges into non-IPR C76Cl24 This work was partly supported by the Deutsche Forschungsgemeinschaft (Ke 489/26-2) and the Russian Foundation for Basic Research (09-03-00433, 09-03-01131, and 09-03-91337). We also thank the MSU Supercomputer Center for support in quantum chemical calculations.
Microfluidic Confinement of Single Cells of Bacteria in Small Volumes Initiates High‐Density Behavior of Quorum Sensing and Growth and Reveals Its Variability
Boedicker, James Q.
/ Vincent, Meghan E.
/ Ismagilov, Rustem F.et al.
| 2009
Microfluidic Confinement of Single Cells of Bacteria in Small Volumes Initiates High-Density Behavior of Quorum Sensing and Growth and Reveals Its Variability This research was supported by the NIH Director's Pioneer Award DP1 OD003584 to R.F.I. We thank S. Molin for generously providing the reporter strain, J. Shapiro and O. Zaborina for helpful discussion, and E.B. Haney for contributions to writing this manuscript.
Copper-Catalyzed Alkylation of Sulfonamides with Alcohols This research was supported by the Chinese Academy of Sciences, the DFG (SPP 1118 and Leibniz Prize), and the BMBF. F. Shi thanks the Alexander-von-Humboldt-Stiftung for an AvH Fellowship.
Functionalized Chitosan as a Green, Recyclable, Biopolymer-Supported Catalyst for the [3+2] Huisgen Cycloaddition This research was supported by the French National Research Agency (ANR) as part of the GreenCat project.
Silver Nanoparticles with Broad Multiband Linear Optical Absorption F.S. acknowledges the Packard Foundation and an ENI-MITEI Solar Frontier grant; O.M.B. acknowledges KAUST and the Saudi Ministry of Higher Education; V.A. thanks the Fondazione Ing. Aldo Gini; C.M.A. thanks Kansas State University; W.W. acknowledges the Fund for Scientific Research - Flanders (FWO group project G.0129.07) and thanks Cor E. Van Hove for the use of the ultracentrifuge; L.D.N. acknowledges the US Army Research Laboratory (W911NF-06-2-0040 and W911 NF-07-1-0618) G.C.S. acknowledges NSF grant CHE-0550497 and AFOSR-DARPA Project BAA07-61 (FA9550-08-1-0221).
Addition Reactions of Sulfonylimidates with Imines Catalyzed by Alkaline Earth Metals This work was partially supported by a Grant-in-Aid for Scientific Research from Japan Society of the Promotion of Science (JSPS). H.V.N. thanks the JSPS for a postdoctoral research fellowship.
Imaging of Catenated, Figure-of-Eight, and Trefoil Knot Polymer Rings The Centre National de la Recherche Scientifique is gratefully acknowledged for supporting this work. We also thank RogerC. Hiorns for assistance with the English translation.
Supramolecular Chemistry on a Cluster Surface: Fixation-Complexation of Potassium and Ammonium Ions with Crown-Ether-Like Rings A.M. gratefully acknowledges the long-term financial support of the Deutsche Forschungsgemeinschaft, the Fonds der Chemischen Industrie, and the European Union. F.L.S. thanks the Fundação para a Ciência e a Tecnologia (FCT, Portugal) for the Ph.D. scholarship No. SFRH-BD-16284-2004. J.M.P. and C.B. acknowledge CTQ2008-06549, Consolider Ingenio 2010 CSD2006-0003, and the ICIQ Foundation. P.M. thanks DIUE for grant 2009FIC00029. We also thank B.S.C. for allocation of CPU time.
An Efficient Dye-Sensitized Solar Cell with an Organic Sensitizer Encapsulated in a Cyclodextrin Cavity This work was supported by the Korea Science and Engineering Foundation (KOSEF) through the National Research Lab. Program funded by the Ministry of Science and Technology (no. R0A-2005-000-10034-0) and WCU (the Ministry of Education and Science) Program (no. R31-2008-000-10035-0) and ERC (the Korean government(MEST)) Program (no. R11-2009-088-02001-0). Computations were performed using a supercomputer of the Korea Institute of Science and Technology Information under grant KSC-2008-S03-0008.
Synthesis of Well-Defined Hyperbranched Polyamides by Condensation Polymerization of AB2 Monomer through Changed Substituent Effects This work was supported in part by a Grant-in-Aid (Grant 19550128) for Scientific Research and a Scientific Frontier Research Project from the Ministry of Education, Culture, Sports, Science, and Technology (Japan).
Light-Triggered Bioactivity in Three Dimensions This work was supported by the National Science Foundation under grant DMR-0505772 and by the Department of Energy under grant DE-FG02-00ER45810. T.M. thanks the JSPS for his Research Fellowship for Young Scientists. We thank L. Palmer for a fruitful discussion. We thank M. Greenfield for help with the rheometer and the following Northwestern University facilities for use of their instruments: BIF, EPIC, IMSERC, Keck, and MRC.
A Light-Activated DNA Polymerase We gratefully acknowledge financial support from the Department of Chemistry at North Carolina State University. D.D.Y. acknowledges a graduate research fellowship from the ACS Medicinal Chemistry Division. A.D. is a Beckman Young Investigator and a Cottrell Scholar. We thank P. G. Schultz (TSRI) for providing the pSupONBY plasmid, R. M. Kelly (NCSU) for FPLC, and T. A. Cropp (UMD) for the pTaq plasmid.
Noncovalent Interactions in the Asymmetric Synthesis of Rigid, Conjugated Helical Structures We thank the National Science Foundation for support of this work through grants CHE-0414936 and CHE-0718117. ChemMatCARS Sector15 is principally supported by the National Science Foundation/Department of Energy under grant number CHE-0535644. Use of the Advanced Photon Source was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under contract no.DE-AC02-06CH11357. Dr. Yu-Sheng Chen is thanked for help with data collection.
Mechanistic Insight into the Palladium-Catalyzed 1,4-Oxidation of 1,3-Dienes to 1,4-Dicarboxy-alk-2-enes We thank Dr. Wendel Doubleday, Dr. Rajendra Deshpande, Dr. David Kronenthal, and Dr. Robert Waltermire for supporting this work, Prof. Donna Blackmond and Dr. Chris Sfouggatakis for useful discussions, and Michael Peddicord for HRMS data.
Quantifying End-to-End Conformational Communication of Chirality through an Achiral Peptide Chain We are grateful to the EPSRC and to the Leverhulme Trust for financial support of this work, and to the Departament d'Innovació Universitats i Empresa de la Generalitat de Catalunya for a postdoctoral fellowship to J.S.