C II is one of the brightest emission lines from star-forming galaxies and is an excellent tracer for star formation. Recent work measured the C II emission line amplitude for redshifts 2 < z < 3.2 by cross-correlating Planck High Frequency Instrument emission maps with tracers of overdensity from the Baryon Oscillation Spectroscopic Sky Survey, finding I(CII)=6.6(sup +5.0, sub −4.8×10(exp 4) Jy/sr at 95per cent confidence level. In this paper, we present a refinement of this earlier work by improving the mask weighting in each of the Planck bands and the precision in the covariance matrix. We report a detection of excess emission in the 545 GHz Planck band separate from the cosmic infrared background (CIB) present in the 353–857 GHz Planck bands. This excess is consistent with redshifted C II emission, in which case we report b(CII)I(CII)=2.0(sup +1.2, sub −1.1×10(exp 5) Jy/sr at 95 per cent confidence level, which strongly favours many collisional excitation models of C II emission. Our detection shows strong evidence for a model with a non-zero C II parameter, though line intensity mapping observations at high spectral resolution will be needed to confirm this result.