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Pre-configured powders were mixed uniformly through bonding granulation method. The boracic iron based self-lubricating composites with copper of different mass were prepared by the powder metallurgy press-sinter process. The tribological properties under different conditions of load were investigated on HDM20 end-face tribometer. The composite structure, the wear mechanism which copper affect the friction and wear behaviors of boracic iron based composites were analyzed by using X-ray diffraction, EDS and metallographic microscope. The results show that elementary copper which forming alloy phase could strengthen the combination of each phase in composites, playing the role of binder, improve the tribological properties. The synergistic effect between the phases combination, hardness and strength of Cu-20w composite were observably, which lead to the excellent tribological properties synthetically.