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Titelbild: A Crystal‐Engineered Hydrogen‐Bonded Octachloroperylene Diimide with a Twisted Core: An n‐Channel Organic Semiconductor (Angew. Chem. 4/2010)
Das Oxyallyl-Diradikal: Beobachtung des Singulett- und Triplettzustands mit Negativionen-Photoelektronenspektroskopie Für hilfreiche Anmerkungen danke ich Prof. W. Sander, Prof. W.T. Borden und Prof. W.C. Lineberger.
Asymmetrische Synthese chiraler Tetraphenylene Wir bedanken uns bei der U.S. National Science Foundation für die finanzielle Unterstützung (CHE-0718117).
Multiresponsive Reversible Gels Based on Charge-Driven Assembly We acknowledge Dr. A.T.M. Marcelis for his help in the synthesis of the triblock copolymer, Prof. Armes for providing a detailed protocol for the triblock copolymer synthesis, and Prof. Detrembleur for doing the SEC analysis. This research is funded by the Dutch Polymer Institute (DPI), project no 657. I.K.V. is supported by a European Marie Curie Fellowship (FP7-PEOPLE-IEF-2008, Contract No. 236723) and by the Adolphe Merkle Foundation.
Ion- and Liquid-Assisted Grinding: Improved Mechanochemical Synthesis of Metal-Organic Frameworks Reveals Salt Inclusion and Anion Templating The Herchel Smith fund is acknowledged for a research fellowship (T.F.). M.J.D. and D.G.R. acknowledge BBSRC for funding. Financial support provided by the Bundesministerium für Bildung und Forschung (BMBF) and the Fonds der Chemischen Industrie (FCI) is acknowledged (I.H., R.E.D.). Prof. W. Jones, University of Cambridge, is acknowledged for helpful discussions.
Highly Stable Pleated-Sheet Secondary Structure in Assemblies of Amphiphilic α/β-Peptides at the Air-Water Interface This work was supported by the United States-Israel Binational Science Foundation (Grant No.2005132). M.-r.L. was supported by a Korea Research Foundation Grant funded by the Korean Government (MOEHRD) (KRF-2006-214-C00053) and by the Nanoscale Science and Engineering Center at UW-Madison (NSF DMR-0425880). GIXD studies at beam-line BW1, Hasylab, DESY, were supported by the European Community-Research Infrastructure Action under the FP6 "Structuring the European Research Area" Programme (through the Integrated Infrastructure Initiative "Integrating Activity on Synchrotron and Free Electron Laser Science").
Determinants of Ligand Affinity and Heme Reactivity in H-NOX Domains Funding for this research was provided by the National Institutes of Health National Heart, Lung, and Blood Institute Award F32L090174 (E.E.W.), NIH grant GM 070671 (M.A.M.), and a grant from the Rogers Family Foundation (M.A.M.). We are grateful to Dr. Jay Winkler and the Beckman Institute Laser Resource Center at the California Institute of Technology for assistance with on-rate measurements, and members of the Marletta laboratory for critical reading of this manuscript. H-NOX=heme nitric oxide/oxygen.
A Polysaccharide-Based Container Transportation System Powered by Molecular Motors This work was supported by Grant of Molecular and System Life Science, and Grant-in-Aid for Scientific Research A (20245036) from MEXT of the Japanese Government.
Asymmetric Synthesis of Chiral Silacarboxylic Acids and Their Ester Derivatives This research was supported in part by a Grant-in-Aid for Scientific Research) (B) No. 19350019 and Global COE Program (Kyushu Univ.) from MEXT (Japan). We thank Y. Tanaka, K. Ideta, and T. Matsumoto (IMCE, Kyushu Univ.) for HRMS measurements, 29Si NMR measurements, and single crystal X-ray diffraction analysis, respectively.
Strong Two-Photon Excited Fluorescence and Stimulated Emission from an Organic Single Crystal of an Oligo(Phenylene Vinylene) This project is supported by National Natural Science Foundation of China (NSFC. 20621091, 20873163, 90606004, 20903051), the Chinese Academy of Sciences ("100 Talents" program), the "111" program, and the National Research Fund for Fundamental Key Project 973 (2006CB806202, 2006CB932101).
Synthetic α-Helix Mimetics as Agonists and Antagonists of Islet Amyloid Polypeptide Aggregation We thank Prof. G.W. Brudvig for suggestions and Dr. C. Incarvito for assistance with X-ray crystallographic analysis. This work was supported by National Institutes of Health grants to A.D.H. (GM69850) and A.D.M. (NIDDK DK079829). J.A.H. was supported by a NRSA fellowship (AG031612).
A Crystal-Engineered Hydrogen-Bonded Octachloroperylene Diimide with a Twisted Core: An n-Channel Organic Semiconductor This work was supported by the BMBF within Forum Organic Electronics, project 13N10205 Polytos.
Catalytic Asymmetric Synthesis of Substituted 3-Hydroxy-2-Oxindoles This research was supported by start-up funds from the University of California, Davis and a grant from the ACS-PRF (49I8I-DNI1). N.V.H. is a recipient of the Eugene Cota-Robles Graduate Fellowship.
On the Chirality of Self-Assembled DNA Octahedra This research was supported by the Office of Naval Research (Award No. N000140910181). DLS studies were carried out in the Purdue Laboratory for Chemical Nanotechnology (PLCN). The cryoEM images were taken in the Purdue Biological Electron Microscopy Facility, and the Purdue Rosen Center for Advanced Computing (RCAC) provided the computational resources for the 3D reconstructions.
Substrate-Controlled Asymmetric Total Synthesis and Structure Revision of (+)-ItomanalleneA We thank Prof. M. Suzuki (Hokkaido University) for providing the spectra of itomanalleneA and neolaurallene. We are grateful to Dr. H.C. Ahn (KIST) for the measurement of 900MHz 1H NMR spectra of 3 c and ent-2. This work was supported by the SRC/ERC program of MOST/KOSEF (R11-2007-107-00000-0).
Synthesis of [8]Cycloparaphenylene from a Square-Shaped Tetranuclear Platinum Complex This work was partly supported by a Grant-in-Aid for Scientific Research from the Japan Society for the Promotion of Science. We thank Prof. Fumiyuki Ozawa of Kyoto University for stimulating discussions, Prof. Masaki Shimizu, Prof. Tamejiro Hiyama, and Youhei Takeda of Kyoto University for the fluorescent measurements and valuable suggestions, and Dr. Yasuyuki Nakamura of our group for the mass-spectroscopy measurements and helpful suggestions.
Mechanistic Insights into the Formation of InP Quantum Dots This work was supported in part by the MIT-Harvard NIH CCNE (1U54-CA119349) and the US ARO through the ISN (W911NF-07-D-0004).This work also made use of the DCIF (CHE-980806, DBI-9729592). B.J.W. was supported by a NSF Graduate Research Fellowship. Special thanks to Alejandro Lichtscheidl and Peter Reiss for helpful discussions, and Jeffrey Simpson for assistance with HMBC measurements.
Time-Resolved In Situ Diffraction Study of the Solvothermal Crystallization of Some Prototypical Metal-Organic Frameworks We thank DESY for provision of beamtime at HASYLAB, and we are grateful to the group of Prof.Dr. W. Bensch of the Christian-Albrechts-Universität zu Kiel, in particular Beatrix Seidlhofer and Elena Antonova, for their assistance with use of BeamlineF3 and the loan of their heating device. The ESRF provided beamtime on ID31 and we thank Dr. I. Margiolaki and Dr. A. Fitch for their assistance with measuring data there. We are grateful to Nikos Kourkoumelis, University of Ioannina, for modifying his PowDLL program to allow analysis of the EDXRD data. This work was supported by CNRS and French ANR "CONDMOFs" funding.
Autonomic Self-Healing of Hydrogel Thin Films This work was supported by the Georgia Tech/Emory Center (GTEC) for the Engineering of Living Tissues. A.B.S. is supported in part by the TI:GER (Technological Innovation: Generating Economic Results) program at Georgia Tech.
DHTP Ligands for the Highly Ortho-Selective, Palladium-Catalyzed Cross-Coupling of Dihaloarenes with Grignard Reagents: A Conformational Approach for Catalyst Improvement This work was supported by the Society of Synthetic Organic Chemistry (Japan), the Takeda Science Foundation, and by a Grant-in-Aid for Scientific Research on Priority Areas "Advanced Molecular Transformations of Carbon Resources" from the Ministry of Education, Culture, Sports, Science and Technology (Japan). DHTP=dihydroxyterphenylphosphine.
DHTP Ligands for the Highly Ortho‐Selective, Palladium‐Catalyzed Cross‐Coupling of Dihaloarenes with Grignard Reagents: A Conformational Approach for Catalyst Improvement
N‐Acyliminium Ion Chemistry: Highly Efficient and Versatile Carbon–Carbon Bond Formation by Nucleophilic Substitution of Hydroxy Groups Catalyzed by Sn(NTf2)4
Ben Othman, Raja
/ Affani, Radouane
/ Tranchant, Marie‐Joséet al.
| 2010
Platinum Sintering on H-ZSM-5 Followed by Chemometrics of CO Adsorption and 2D Pressure-Jump IR Spectroscopy of Adsorbed Species We would like to thank Toyota Motor Europe for financing this research project through the Open Call process. Dr. N. Takahashi, Dr. H. Shinjoh, and Dr. Y. Nagai from Toyota Central R&D Laboratory as well as Prof. S. Matsumoto and M. Miura from Toyota Motor Corporation are warmly thanked for their fruitful discussions. We also acknowledge Dr. Philippe Bazin and Dr. Francis Cruege for help in the development of the PJAS instrumentation and Dr. Chantal Gunther for her skilful assistance in electronics for the data acquisition.
A Toxic Disinfection By-product, 2,6-Dichloro-1,4-benzoquinone, Identified in Drinking Water We acknowledge the financial support of the Water Research Foundation, the UK Drinking Water Inspectorate, the Natural Sciences and Engineering Research Council of Canada, the Canadian Water Network, the Alberta Ingenuity Water Research Institute, and Alberta Health and Wellness. We thank Dr. Richard Bull and Dr. Dave Reckhow for providing insights on the potential importance of haloquinones as possible DBPs, Dr. SteveE. Hrudey for his perspectives on the public health risks of DBPs, and Dr. X.Chris Le for his constructive comments and suggestions.
C(sp3)-N Bond-Forming Reductive Elimination of Amines: Reactions of Bisphosphine-Ligated Benzylpalladium(II) Diarylamido Complexes This research was supported by the NSF as part of the Center for Enabling New Technologies through Catalysis (CENTC), CHE-0650456. We thank Luc Boisvert and Karen Goldberg at the University of Washington for helpful discussions.
Highly Enantioselective Hydrophosphonylation of Aldehydes: Base-Enhanced Aluminum-salalen Catalysis This work was supported by a Grant-in-Aid for Scientific Research (Specially Promoted Research 18002011) and the Global COE program "Science for Future Molecular Systems" from MEXT (Japan).
Direct Detection of Oxygen Ligation to the Mn4Ca Cluster of Photosystem II by X-ray Emission Spectroscopy This work was supported by the NIH grant (GM 55302) and the DOE, Director, Office of Science, Office of Basic Energy Sciences (OBES), Chemical Sciences, Geosciences, and Biosciences Division, under Contract DE-AC02-05CH11231. Portions of this research were carried out at SSRL, operated by Stanford University for DOE, OBES. The SSRL SMB Program is supported by the DOE, OBER and by the NIH, NCRR. We thank Prof. Steve Cramer for the use of his emission spectrometer (NIH Grant EB-001962) for some of the work and Prof. Ken Sauer for many useful discussions.
Regioselective Oxidative Cleavage of Benzylidene Acetals: Synthesis of α- and β-Benzoyloxy Carboxylic Acids We thank DST and CSIR, India for financial support and DST-FIST for providing NMR facilities. P.S.K. and A.B. thank DST (Unit on Nano Science and Technology) and CSIR, New Delhi, for research fellowships. We thank V. RamKumar for single-crystal X-ray analysis.
Effects of Partial Confinement on the Specificity of Monomolecular Alkane Reactions for Acid Sites in Side Pockets of Mordenite We acknowledge with thanks the financial support from the Chevron Energy Technology Company. We also thank Dr. Stacey I. Zones (Chevron) and Prof. Matthew Neurock (University of Virginia) for valuable technical discussions.
Saturnene Revealed: X-ray Crystal Structure of D5d-C60F20 Formed in Reactions of C60 with AxMFy Fluorinating Agents (A=Alkali Metal; M=3d Metal) This research was supported by the U.S. NSF (grant No. CHE-0707223), the Slovenian Research Agency (grant No. P1-0045, Inorganic Chemistry and Technology), and the Electrochemical Society (Fellowship to N.B.S.). ChemMatCARS Section15 is principally supported by the U.S. NSF/U.S. DOE (grant No. CHE-0822838). Use of the Advanced Photon Source was supported by the U.S. Department of Energy, Office of Basic Energy Sciences (contract No. DE-AC02-06CH11357). A.A.P. thanks the Humboldt Foundation for support.