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Titelbild: Isostructural Coordination Capsules for a Series of 10 Different d5–d10 Transition‐Metal Ions (Angew. Chem. 39/2006)
Molekulare Hauptgruppenelementchemie, global vernetzt. 2. Core-to-Core-Symposium über Hauptgruppenelementchemie vom 26. bis 28. August 2006 an der Universität Tokio (Japan).
Entwicklungen in der katalytischen enantioselektiven intermolekularen C-H-Funktionalisierung. Diese Arbeit wurde durch die National Science Foundation unterstützt (CHE-0350536).
Diameter-Tunable CdTe Nanotubes Templated by 1D Nanowires of Cadmium Thiolate Polymer. The current investigations were financially supported by NSFC projects (20225313, 90206024).
Boron-Containing Two-Photon-Absorbing Chromophores: Electronic Interaction through the Cyclodiborazane Core. Boron-Containing Two-Photon-Absorbing Chromophores, Part 1. This work was supported by the CNRS and University Louis Pasteur of Strasbourg. A.H. is grateful to the French ministry of research for a fellowship. We thank Prof. Dr. R. Welter and Dr. A. De Cian for the solution of the X-ray crystal structure.
Photoinduced Reversible Formation of Microfibrils on a Photochromic Diarylethene Microcrystalline Surface. This work was partly supported by Grants-in-Aid for Scientific Research (B) (18350101) from the Ministry of Education, Culture, Sports, Science, and Technology (MEXT) of the Japanese Government. We thank Prof. Takahiro Seki and Mitsuo Hara for the powder X-ray analysis. We also express thanks to Prof. Hiroshi Komatsu, Prof. Tsuyoshi Tsujioka, Dr. Takao Matsuzaki, Prof. Nobuo Niimura, Dr. Seiya Kobatake, and S. Matsumoto for their helpful discussions.
Direct Observation of Photochromic Dynamics in the Crystalline State of an Organorhodium Dithionite Complex. This work was financially supported by the Grant-in-Aids for Scientific Research (KAKENHI) in Priority Area "Molecular Nano Dynamics", "Dynamic Complex", and "Chemistry of Coordination Space" and by the Grant-in-Aids "15350036" and "Nanotechnology Support Project" from Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan, and "Tokuyama Science Foundation". We thank Professor P. Coppens (State University of New York) for valuable discussions.
Molecular Mapping of the Recognition Interface between the Islet Amyloid Polypeptide and Insulin. We thank Steve Manch for editing the manuscript, Michal Sadovnic for graphical artwork, and members of the Gazit laboratory for helpful discussions. Support from the BIO-DISC Research and Development program is gratefully acknowledged.
Structurally Characterized Quadruple-Stranded Bisbidentate Helicates. Coordination Number Incommensurate Cluster Formation part 33. This research was supported by the Director, Office of Science, Office of Advanced Scientific Computing Research, Office of Basic Energy Sciences (U.S. Department of Energy) under contract DE-AC02-05CH11231. The authors would like to thank Modi Wetzler, Matt Stavis, Geza Szigethy, Dr. Christoph Jocher, and Dr. Michael Seitz for helpful discussions and suggestions.
Colorimetric Identification of Carbohydrates by a pH Indicator-pH Change Inducer Ensemble. This work was supported by the National Science Foundation (CHE-0449139). Components of this work were conducted in a Shared Instrumentation Facility constructed with support from Research Facilities Improvement Grant C06 RR-16572 from the NCRR-NIH. J.-S.L. was supported by the Korea Research Foundation Grant funded by the Korean Government (MOEHRD, Basic Research Promotion Fund: KRF-2005-C00088).
Isostructural Coordination Capsules for a Series of 10 Different d5-d10 Transition-Metal Ions. We thank Dr. Misako Imachi (Bruker BioSpin K.K.) for useful discussions and technical support for DOSY measurements. This work was supported by a Grant-in-Aid for The 21st Century COE Program for Frontiers in Fundamental Chemistry; a Grant-in-Aid for Scientific Research (S) to M.S. (no. 16105001); a Grant-in-Aid for Young Scientists (A) to S.H. (no. 17685005) from the Ministry of Education, Culture, Sports, Science, and Technology of Japan; a PRESTO (Precursory Research for Embryonic Science and Technology) project from the Japan Science and Technology Agency; and the Kurata Foundation.
A Family of Nanoporous Materials Based on an Amino Acid Backbone. We thank the EPSRC for funding under EPSRC-C511794 and for access to the SRS, and the Leverhulme Trust for support of J.N.R.
Intercalation of Organic Molecules into Vanadium(IV) Benzenedicarboxylate: Adsorbate Structure and Selective Absorption of Organosulfur Compounds. The Robert A. Welch Foundation is acknowledged for support of this work.
Intrinsic Chirality in a Bent-Core Mesogen Induced by Extrinsic Chiral Structures. This work was supported in part by Grants-in-Aid for Scientific Research (16105003) by the Ministry of Education, Culture, Sports, Science and Technology, Japan. We acknowledge Dr. Y. Saitoh and Dr. H. Satoh for kindly supplying glass substrates with DLC films.
Acetylene Absorption and Binding in a Nonporous Crystal Lattice. We acknowledge the Department of Energy (USA) and the National Research Foundation (South Africa) for support of this work.
New Insights into the Classic Chiral Grignard Reagent (1R,2S,5R)-Menthylmagnesium Chloride. The Centre for Chiral and Molecular Technologies, Deakin University and Chirogen Pty. Ltd. are acknowledged for financial support. We thank Dr. I. Barta of Ubichem for useful discussions regarding the attempted synthesis of Men2Ph2Sn (1) on larger scales. We are grateful to the Alexander von Humboldt Foundation for providing a Feodor Lynen Scholarship (to J.B.).
Insights into the Mechanism of Methanol-to-Olefin Conversion at Zeolites with Systematically Selected Framework Structures. The authors thank the Natural Science Foundation of China (20121301), the Ministry of Science and Technology of China (2006CB806101), and the Chinese Academy of Sciences for financial support. Z.-M.C. and Q.L. thank Professor Chun-Li Bai for valuable advice.
A Lesson from the Unusual Morphology of Silica Mesoporous Crystals: Growth and Close Packing of Spherical Micelles with Multiple Twinning. O.T. thanks the Swedish Science Research Council (VR) and the Japan Science and Technology Agency (JST) for financial support. This work was also supported by the National Natural Science Foundation of China (Grant Nos. 20425102 and 20521140450), the China Ministry of Education, and the Shanghai Science Foundation (0452nm061 and 05XD14010).
Radical Additions of Xanthates to Vinyl Epoxides and Related Derivatives: A Powerful Tool for the Modular Creation of Quaternary Centers. N.C. thanks the Ministère de l'Education Nationale, de la Recherche et de la Technologie (France) for a fellowship.
Monodentate Phosphines Provide Highly Active Catalysts for Pd-Catalyzed CN Bond-Forming Reactions of Heteroaromatic Halides-Amines and (H)N-Heterocycles. We thank the National Institutes of Health (GM 58160) and the National Cancer Institute (Cancer Training Grant GM 5-T32-CAO9112-30) for support of this work. R.E.T. would like to thank Pfizer for a SURF fellowship and MIT (UROP) for financial support. T.I. thanks the Uehara Memorial Foundation for a fellowship. We are grateful to Merck, Amgen, and Engelhard (Pd(OAc)2) for additional support. The Bruker Advance 400 MHz instrument used in this study was purchased with funding from the National Institutes of Health (GM 1S10RR13886-01), and the Varian 300 and 500 MHz instruments were purchased with funding from the National Science Foundation (CHE 9808061 and DBI 9729592).
Monodentate Phosphines Provide Highly Active Catalysts for Pd‐Catalyzed CN Bond‐Forming Reactions of Heteroaromatic Halides/Amines and (H)N‐Heterocycles
Anderson, Kevin W.
/ Tundel, Rachel E.
/ Ikawa, Takashiet al.
| 2006
Total Synthesis of Marinomycins A-C. We thank Professor William Fenical for helpful discussions and Dr. Hak Cheol Kwon for assistance in the HPLC purification of synthetic marinomycins A-C. The assistance of Dr. D. H. Huang and Dr. R. Chadha with spectroscopic and X-ray crystallographic analyses, respectively, is also acknowledged. Financial support for this work was provided by a grant from the National Institutes of Health (USA) and the Skaggs Institute of Chemical Biology, the Pfeiffer Foundation (predoctoral fellowship to A.L.N.), and the Kurt Fordan Foundation (Germany) (fellowship to C.S.S.).
Total Synthesis and Absolute Stereochemistry of Polygalolides A and B. This research was in part supported by a Grant-in-Aid for Scientific Research on Priority Areas 17035002 from the Ministry of Education, Culture, Sports, Science and Technology (MEXT). We are grateful to Dr. X. Wei for providing spectra of the natural products. We thank H. Matsumoto, A. Maeda, S. Oka, M. Kiuchi, and T. Hirose of the Center for Instrumental Analysis, Hokkaido University, for technical assistance in obtaining MS and elemental analyses.
Structural Identification of Conjugated Molecules on Metal Surfaces by Means of Soft Vibrations. Dr. M.-L. Bocquet and Dr. F. Delbecq are acknowledged for helpful discussions, and Dr. J. Pilmé for valuable discussions about ELF interpretation. I thank IDRIS and PSMN for CPU time and assistance.
Alkali-Metal-Mediated Zincation of Polycyclic Aromatic Hydrocarbons: Synthesis and Structures of Mono- and Dizincated Naphthalenes. This study was supported by the UK Engineering and Physical Science Research Council through grant award no. GR-T27228-01.
Organocatalytic Enantioselective Nucleophilic Vinylic Substitution. This work was made possible by a grant from The Danish National Research Foundation. Thanks are given to Dr. Jacob Overgaard for performing the X-ray analysis.
One-Step Synthesis of Benzotetra- and Benzopentacyclic Compounds through Intramolecular [2+3] Photocycloaddition of Alkenes to Naphthalene. The authors thank Prof. H. Roth (The State University of New Jersey) for helpful discussions. The authors also thank Akihito Yamano and Motoo Shiro (Rigaku Corporation) for analysis of the X-ray crystallography data. This work was partially supported by Grants-in-Aid for Scientific Research on Priority Areas "Advanced Molecular Transformations of Carbon Resources" (18037063 to K.M.), Exploratory Research (16655018 to K.M.), and Young Scientists (B) (16750039 to H.M.) from the Ministry of Education, Culture, Sports, Science, and Technology of Japan.
Total Synthesis of (+)-Phyllantidine. We thank the Natural Sciences and Engineering Research Council (NSERC) of Canada and Boehringer Ingelheim Canada for funding. We are grateful to D. Hairsine for performing MS analyses. C.A.C. is the recipient of an NSERC CGSM postgraduate scholarship.
Template-Free, Low-Temperature Synthesis of Crystalline Barium Titanate Nanoparticles under Bio-Inspired Conditions. We thank E. Yoo for his help, as well as Dr. T. Mates and Dr. J. Löfvander for their assistance with the characterization. This work was supported in part by grants from the U.S. Department of Energy (DE-FG03-02ER46006), DARPA (HR0011-04-1-0059), the U.S. Army Research Office (DAAD19-03-D-0004 to the Institute for Collaborative Biotechnologies, and W911NF-05-1-0072), the Biologically Inspired Materials Institute of NASA (NCC-1-02037 and NAG1-01-003), the NOAA National Sea Grant College Program of the U.S. Department of Commerce through the California Sea Grant College System (NA36RG0537, Project R-MP-92), and the MRSEC Program of the National Science Foundation (DMR05-20415 to the UCSB Materials Research Laboratory). The U.S. Government is authorized to reproduce and distribute copies of this Communication for governmental purposes.
Lipase-Aluminium-katalysierte dynamische kinetische Racematspaltung von sekundären Alkoholen. Diese Arbeit wurde vom Fonds der Chemischen Industrie unterstützt.
Untersuchung der Reaktivität und Selektivität DNA-alkylierender Duocarmycin-Analoga mittels hochauflösender Massenspektrometrie. Die Untersuchungen wurden von der Deutschen Forschungsgemeinschaft (SFB 416) und dem Fonds der chemischen Industrie unterstützt. F.M. dankt der Studienstiftung des deutschen Volkes für ein Promotionsstipendium.
Antitumor-Wirkstoffe: Entwicklung hochpotenter glycosidischer Duocarmycin-Analoga für eine selektive Krebstherapie. Die Untersuchungen wurden von der Deutschen Forschungsgemeinschaft (SFB 416) und dem Fonds der chemischen Industrie unterstützt. F.M. dankt der Studienstiftung des deutschen Volkes für ein Promotionsstipendium.
Maßgeschneiderte Liganden für biokompatible Nanopartikel. Diese Arbeit wurde durch die Deutsche Forschungsgemeinschaft (SFB 508, GK 611) und den Fonds der Chemischen Industrie gefördert.
Antikörper gegen ein Kohlenhydrat-Antigen zum Nachweis von Anthrax-Sporen. Diese Arbeit wurde unterstützt von der ETH Zürich, durch ein Feodor Lynen-Stipendium der Alexander von Humboldt-Stiftung (AvH) und durch ein Emmy Noether-Stipendium der Deutschen Forschungsgemeinschaft (für D.B.W.).
Glycomimetische Cyclopeptide stimulieren Neuritenwachstum. Wir danken der Erika und Conrad W. Schnyder-Stiftung, der NRW Graduate School in Bioinformatics and Genome Research, Universität Bielefeld (Doktorandenstipendium an E.W.G.), der DFG (SFB 613) und dem FCI für die Förderung des Projektes.