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Table of contents
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Cover Picture: Toroidal Micelles of Uniform Size from Diblock Copolymers (Angew. Chem. Int. Ed. 25/2009)
Iridium-Catalyzed Reactions of Trifluoromethylated Compounds with Alkenes: A Csp3&bond;H Bond Activation α to the Trifluoromethyl Group This work was supported by Grants-in-aid for Scientific Research, Ministry of Education, Culture, Sports, Science and Technology of Japan.
Is Enantioselectivity Predictable in Asymmetric Catalysis? We thank the Leverhulme Foundation for a Fellowship (J.M.B.) and Prof. R. W. Alder (Bristol) for valuable critical comments.
Coordination-Driven Self-Assembly of PEO-Functionalized Perylene Bisimides: Supramolecular Diversity from a Limited Set of Molecular Building Blocks Financial support from the Fonds der Chemischen Industrie (Chemiefonds-Stipendium for J.G.) and the Materials for the Life Sciences unit of the Swiss Competence Center for Materials Research and Technology of the ETH Domain is gratefully acknowledged. PEO=poly(ethylene oxide).
Miniemulsion Polymerization and the Structure of Polymer and Hybrid Nanoparticles Published on the occasion of the 25th anniversary of the Max Planck Institute for Polymer Research, Mainz.
A Supramolecularly Assisted Transformation of Block-Copolymer Micelles into Nanotubes The authors acknowledge support from the NSF Center for Polymer Interfaces and Macromolecular Assemblies (CPIMA: NSF-DMR-0213618). We thank Timothy Yeow and Andy Ong in FEI (Japan) for TEM support.
C&bond;H Hydroxylation Using a Heterocyclic Catalyst and Aqueous H2O2 We thank Prof. John Brauman for helpful discussions and A. Sloan Devlin for preparing and performing intial test reactions with the substrate appearing in entry 6 of Table 2. N.D.L. gratefully acknowledges the National Science Foundation and Novartis for predoctoral fellowships. We thank Pfizer, Inc. for support of this work.
A Unified Strategy for Exceptionally High Diastereoselectivity in the Photochemical Ring Closure of Chiral Diarylethenes This work was supported by a Grant-in-Aid for Scientific Research on Priority Areas (471) "Photochromism" from the Ministry of Education, Culture, Sports, Science, and Technology (MEXT) of the Japanese Government.
Efficient Replication Bypass of Size-Expanded DNA Base Pairs in Bacterial Cells We thank the U.S. National Institutes of Health (CA80024 to J.M.E. and GM63587 to E.T.K.) for support. J.G. and H.L. acknowledge Stanford Graduate Fellowships.
Palladium-Catalyzed Cyanation of Carbon&bond;Carbon Triple Bonds Under Aerobic Conditions We thank Professors Motohiro Akazome and Shinji Harada (Chiba University) for their kind support with the X-ray crystallographic analysis. S.A. thanks the Inohana Foundation (Chiba University) for financial support.
N-Heterocyclic Carbene Gold(I) Catalyzed Transformation of N-Tethered 1,5-Bisallenes to 6,7-Dimethylene-3-azabicyclo[3.1.1]heptanes This work was supported by the Korean Government (MOEHRD) (KRF-2008-341-C00022), and the SRC-ERC program of MOST-KOSEF (R11-2005-065). J.H.P. acknowledges support of the Brain Korea 21 fellowships and S.M.K. acknowledges the receipt of the Brain Korea 21 fellowships and a Seoul Science Fellowship.
Low‐Temperature Atomic Layer Deposition of Copper Metal Thin Films: Self‐Limiting Surface Reaction of Copper Dimethylamino‐2‐propoxide with Diethylzinc
Lee, Byoung H.
/ Hwang, Jae K.
/ Nam, Jae W.et al.
| 2009
Low-Temperature Atomic Layer Deposition of Copper Metal Thin Films: Self-Limiting Surface Reaction of Copper Dimethylamino-2-propoxide with Diethylzinc This work was supported by a Korea Science and Engineering Foundation (KOSEF) grant funded by the Korea government (MOST) (No. 2008-02378), the SRC-ERC program of MOST-KOSEF (grant R11-2005-048-00000-0), a Korea Research Foundation Grant funded by the Korea government (MOEHRD, Basic Research Promotion Fund) (KRF-2007-313-C00383), and the Priority Program "Anorganische Materialien durch Gasphasensynthese" (SPP 1119) of the Deutsche Forschungsgemeinschaft.
Nickel-Catalyzed Formation of a Carbon-Nitrogen Bond at the β Position of Saturated Ketones This work was supported by the Global-COE program "Science of Future Molecular Systems". We acknowledge Prof. Tsutomu Katsuki for GCMS analyses.
Indirect Optical Analysis of a Dynamic Chemical System We acknowledge financial support from the University of Padova (CPDA054893) and MIUR (PRIN2006).
Facile Dissociation of [(LNiII)2E2] Dichalcogenides: Evidence for [LNiIIE2] Superselenides and Supertellurides in Solution Financial support from the Cluster of Excellence "Unifying Concepts in Catalysis" (EXC 314-1) funded by the Deutsche Forschungsgemeinschaft and administered by the Technische Universität Berlin is gratefully acknowledged. We sincerely thank Prof. Dr. K. Wieghardt for helpful discussions, Dr. E. Bill for magnetic measurements and Dr. T. Weyhermüller (Max Planck Institute for Bioinorganic Chemistry, Mülheim)) for crystallographic measurements. X.Z. is grateful to the Alexander von Humboldt Stiftung for a postdoctoral fellowship. L=β-diketiminate; E=Se, Te.
Phosphonium Salts as Chiral Phase-Transfer Catalysts: Asymmetric Michael and Mannich Reactions of 3-Aryloxindoles This work was supported by a Grant-in-Aid for Scientific Research on the Priority Area "Advanced Molecular Transformation of Carbon Resources" from the Ministry of Education, Culture, Sports, Science and Technology (Japan).
Self-Healing Colloidal Crystals The authors thank Zhiyong Meng for providing the pNIPAm-AAc microgels and Profs. Victor Breedveld and Alberto Fernandez-Nieves for many valuable discussions. L.A.L. acknowledges support from the ACS-PRF.
Oxidative Carbocation Formation in Macrocycles: Synthesis of the Neopeltolide Macrocycle We thank the National Institutes of Health (GM062924) and the National Science Foundation (CHE-139851) for generous support of this research, and the NIH for the 700 MHz NMR instrument at the University of Pittsburgh (S10RR023404). We thank Dr. Steve Geib for crystallographic analysis.
Indoles from Simple Anilines and Alkynes: Palladium-Catalyzed C&bond;H Activation Using Dioxygen as the Oxidant Financial support from Peking University, the National Science Foundation of China (Nos. 20702002, 20872003), and the National Basic Research Program of China (973 Program 2009CB825300) are greatly appreciated.
Regio- and Stereoselective Generation of Alkenylindium Compounds from Indium Tribromide, Alkynes, and Ketene Silyl Acetals This work was supported by a Grant-in-Aid for Scientific Research on Priority Areas (grant no. 18065015, "Chemistry of Concerto Catalysis" and grant no. 20036036, "Synergistic Effects for Creation of Functional Molecules") and for Scientific Research (grant no. 19550038) from the Ministry of Education, Culture, Sports, Science and Technology (Japan). We thank Dr. Nobuko Kanehisa for the valuable advice regarding X-ray crystallography. Y. N. thanks The Global COE Program "Global Education and Research Center for Bio-Environment Chemistry" of Osaka University.
Fast Attrition-Enhanced Deracemization of Naproxen by a Gradual In Situ Feed The SNN agency (Cooperation Northern Netherlands) and the European Fund for Regional Development (EFRO) are acknowledged for partial financial support of this work.
9,10-Dihydro-9,10-diboraanthracene: Supramolecular Structure and Use as a Building Block for Luminescent Conjugated Polymers A.L. thanks the Fonds der Chemischen Industrie for a Ph.D. grant. F.J. thanks the NSF (CHE-0809642) and the Alexander von Humboldt Foundation for a Friedrich Wilhelm Bessel Research Award. This work was supported by the Deutsche Forschungsgemeinschaft, the Chemetall GmbH, and the City Solar AG, Bad Kreuznach.
Multicompartmental Microcylinders Published on the occasion of the 25th anniversary of the Max Planck Institute for Polymer Research, Mainz. We thank Dr. Xuwei Jiang, University of Michigan, for synthesizing the acetylene-functionalized PLGA, Chris Edwards, Microscopy and Image Analysis Lab, University of Michigan, for guidance in cryosectioning, and Prof. David C. Martin, University of Michigan for valuable discussions. J.L. gratefully acknowledges financial support from the Department of Defense (Idea Award, W81XWH-06-1-0271).
Toroidal Micelles of Uniform Size from Diblock Copolymers Published on the occasion of the 25th anniversary of the Max Planck Institute for Polymer Research, Mainz. This work was supported by NRL (R0A-2007-000-20125-0), SRC (R11-2008-052-03002-0), and WCU (R31-2008-000-10059-0) programs.
An Aqueous Route to Multicolor Photoluminescent Carbon Dots Using Silica Spheres as Carriers Published on the occasion of the 25th anniversary of the Max Planck Institute for Polymer Research, Mainz. We thank Dr. Y. Zhang for the AFM characterization, K. Kirchhoff for the TEM characterization, and Prof. N. Heckenberg for the helpful discussions. R.L. and S.L. acknowledge Alexander von Humboldt (AvH) Fellowships. S.L. also thanks Singapore Millennium Foundation (SMF) for financial support. Q.L. is grateful to Dr. E.-K. Sinner's Bio-lab at the Max Planck Institute for Polymer Research for hosting, the technical assistance from M. Droege, E. Conrad, and A. Arslan, and the partial support from Australian Research Council under DP0558727.
Subliming the Unsublimable: How to Deposit Nanographenes This work was financially supported by the DFG project OPTOELEKTRONIK (MU 334-28-1; AOBJ: 539724), and the EU project NAIMO (NMP-CT-2004-500355).
Asymmetric Hydroxylative Phenol Dearomatization through In Situ Generation of Iodanes from Chiral Iodoarenes and m-CPBA We thank Simafex, the Association Nationale de la Recherche Technique (CIFRE Grants No. 457-2005 & 301-2002), and the Institut Universitaire de France for their financial support. m-CPBA=meta-chloroperoxybenzoic acid.
Hyperbranched: A Universal Conjugated Polymer Platform Published on the occasion of the 25th anniversary of the Max Planck Institute for Polymer Research, Mainz. We thank the Department of Energy-Basic Energy Sciences (DE-FG02-04ER46141)for generous financial support. J.T. thanks Junta de Comunidades de Castilla La Mancha (Fondo Social Europeo FSE 2007-2013) for his postdoctoral grant.
Spontaneous Formation of Giant Unilamellar Vesicles from Microdroplets of a Polyion Complex by Thermally Induced Phase Separation We are grateful to Dr. S. Fukuda (the University of Tokyo Hospital) for his valuable help with the TEM measurements. This research was supported in part by KAKENHI (no. 19031003, no. 20034008) from MEXT, JAPAN. A.K. thanks the Inoue Foundation for Science, the Izumi Science and Technology, and the Kao Foundation for Arts and Sciences.
Local and Collective Motions in Precise Polyolefins with Alkyl Branches: A Combination of 2H and 13C Solid-State NMR Spectroscopy Published on the occasion of the 25th anniversary of the Max Planck Institute for Polymer Research, Mainz. Support by the National Science Foundation under grant DMR-0703261, and by the International Max Planck Research School for Polymer Materials, Mainz is greatly acknowledged. We also thank Dr. Giovanni Rojas for kindly providing the ADMET PE sample.
Cooperative Molecular Motion within a Self-Assembled Liquid-Crystalline Molecular Wire: The Case of a TEG-Substituted Perylenediimide Disc Published on the occasion of the 25th anniversary of the Max Planck Institute for Polymer Research, Mainz. M.R.H. thanks the Carlsberg Foundation for a Research Fellowship. We thank Dr. Daniel Sebastiani for quantum chemical calculations of 13C NMR chemical shifts. TEG=triethyleneglycol.
Taking Fingerprints of DNA Polymerases: Multiplex Enzyme Profiling on DNA Arrays We gratefully acknowledge funding by the DFG (SPP1170) and BMBF (BioChancePlus).
Controlled Oligomerization of Lewis Acid-Base-Stabilized Phosphanylalanes This work was supported by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie.
Enantiospecific Synthesis and Allylation of All-Carbon-Substituted α-Chiral Allylic Stannanes We thank the Deutsche Forschungsgemeinschaft (Oe 249-3-1) for financial support as well as BASF AG (Ludwigshafen, Germany) for the generous donation of enzymes. M.O. is indebted to the Aventis Foundation for a Karl-Winnacker-Stipendium (2006-2008).
Improving the Hydrogen-Adsorption Properties of a Hydroxy-Modified MIL-53(Al) Structural Analogue by Lithium Doping This project was supported by General Motors Fuel Cell Activities in addition to the basic funding provided by the Universität Augsburg. The authors are very grateful to Dr. Ulrich Eberle (GM Fuel Cell Activities) for interesting discussions and perspectives on hydrogen and fuel cell technologies for automotive applications.
Low-Energy-Electron-Induced Hydroamination of an Alkene P.S. thanks Sven Doye for an inspiring GDCh lecture on hydroamination. This work was funded by the DFG and has profited from exchange within COST action ECCL.