-^* Electronic Transition of the Di- and Trinuclear Complexes Ru(E)-(E')(CO)~2(iPr-DAB): Resonance Raman, Electronic Absorption, Emission, and Density Functional Study (E = Me, SnPh~3, M(CO)~5; E' = M(CO)~5; M = Mn, Re; iPr-DAB = N,N'-Diisopropyl-1,4-diaza-1,3-butadiene) (English)
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In:
ORGANOMETALLICS
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16
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2055-2062
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1997
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ISSN:
- Article (Journal) / Print
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Title:-^* Electronic Transition of the Di- and Trinuclear Complexes Ru(E)-(E')(CO)~2(iPr-DAB): Resonance Raman, Electronic Absorption, Emission, and Density Functional Study (E = Me, SnPh~3, M(CO)~5; E' = M(CO)~5; M = Mn, Re; iPr-DAB = N,N'-Diisopropyl-1,4-diaza-1,3-butadiene)
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Contributors:Aarnts, M. P. ( author ) / Wilms, M. P. ( author ) / Stufkens, D. J. ( author ) / Baerends, E. J. ( author ) / Vlcek, A. ( author )
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Published in:ORGANOMETALLICS ; 16, 10 ; 2055-2062
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Publication date:1997-01-01
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Size:8 pages
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ISSN:
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Type of media:Article (Journal)
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Type of material:Print
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Language:English
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© Metadata Copyright the British Library Board and other contributors. All rights reserved.
Table of contents – Volume 16, Issue 10
The tables of contents are generated automatically and are based on the data records of the individual contributions available in the index of the TIB portal. The display of the Tables of Contents may therefore be incomplete.
- 1997
-
Isolation of the Transmetalation Step in the Hiyama Cross-Coupling Reaction of OrganosilanesMateo, Cristina / Fernández-Rivas, Carolina / Echavarren, Antonio M. / Cárdenas, Diego J. et al. | 1997
- 2000
-
First NMR Observation of the Intermolecular Dynamic Proton Transfer Equilibrium between a Hydride and Coordinated Dihydrogen: (dppm)2HRuH···H−OR = [(dppm)2HRu(H2)]+(OR)-Ayllón, José A. / Gervaux, Corinne / Sabo-Etienne, Sylviane / Chaudret, Bruno et al. | 1997
- 2003
-
Novel α,β-C,C-Coupling Reaction of 1-Alkynyl Groups via I2 Oxidation at Nickelate(II) CentersKlein, Hans-F. / Heiden, Monika / He, Mengzhen / Jung, Thomas / Röhr, Caroline et al. | 1997
- 2003
-
Novel a,b-C,C-Coupling Reaction of 1-Alkynyl Groups via I2 Oxidation at Nickelate(II) CentersKlein, Hans-F. et al. | 1997
- 2005
-
Preparation of Linear a-Olefins Using Cationic Nickel(II) a-Diimine CatalystsKillian, Christopher M. et al. | 1997
- 2005
-
Preparation of Linear α-Olefins Using Cationic Nickel(II) α-Diimine CatalystsKillian, Christopher M. / Johnson, Lynda K. / Brookhart, Maurice et al. | 1997
- 2008
-
Synthesis, Structure, and Reactivity of Polymetallic C3OMe Complexes of the Formula (h5-C5Me5) Re(NO)(PPh3)(C(equivalent)CC-(OMe)=)Mm(CO)n (M-m-nFalloon, Stephen B. et al. | 1997
- 2008
-
Synthesis, Structure, and Reactivity of Polymetallic C~3OMe Complexes of the Formula (eta^5-C~5Me~5)Re(NO)(PPh~3)(CCC-(OMe)=)M~m(CO)~n (M/m/n = Re/2/9, Os/3/11): A New Form of Coordinated Carbon in Which a C~3 Chain Links Two Metals and Spans a ThirdFalloon, S. B. / Weng, W. / Arif, A. M. / Gladysz, J. A. et al. | 1997
- 2008
-
Synthesis, Structure, and Reactivity of Polymetallic C3OMe Complexes of the Formula (η5-C5Me5)Re(NO)(PPh3)(C⋮CC(OMe))M m (CO) n (M/m/n = Re/2/9, Os/3/11): A New Form of Coordinated Carbon in Which a C3 Chain Links Two Metals and Spans a ThirdFalloon, Stephen B. / Weng, Weiqing / Arif, Atta M. / Gladysz, J. A. et al. | 1997
- 2016
-
C−C Activation in Biphenylene. Synthesis, Structure, and Reactivity of (C5Me5)2M2(2,2‘-biphenyl) (M = Rh, Co)Perthuisot, Christophe / Edelbach, Brian L. / Zubris, Deanna L. / Jones, William D. et al. | 1997
- 2016
-
C-C Activation in Biphenylene. Synthesis, Structure, and Reactivity of (C5Me5)2M2(2,2'-biphenyl) (MPerthuisot, Christophe et al. | 1997
- 2024
-
Bi- and Trimetallic σ-Acetylide Complexes Connected through a Phenyl Ring in the Fe(Cp*)(dppe) SeriesWeyland, Tania / Lapinte, Claude / Frapper, Gilles / Calhorda, Maria José / Halet, Jean-François / Toupet, Loic et al. | 1997
- 2024
-
Bi- and Trimetallic (zigma)-Acetylide Complexes Connected through a Phenyl Ring in the Fe(Cp*)(dppe) SeriesWeyland, Tania et al. | 1997
- 2032
-
Synthesis of Luminescent Trinuclear Silver(I) Acetylides of Bis(diphenylphosphino)methane and Bis(diphenylphosphino)-n-propylamine. X-ray Crystal Structures of [Ag3(μ-dppm)3(μ3-η1-C⋮C-C6H4-NO2-p)]2+ and [Ag3(μ-dppm)3(μ3-η1-C⋮C-C6H4-NO2-p)2]+Yam, Vivian Wing-Wah / Fung, Wendy Kit-Mai / Cheung, Kung-Kai et al. | 1997
- 2032
-
Synthesis of Luminescent Trinuclear Silver(I) Acetylides of Bis(diphenylphosphino)methane and Bis(diphenylphosphino)-n-propylamine. X-ray Crystal Structures of [Ag~3(-dppm)~3(~3-eta^1-CC-C~6H~4-NO~2-p)]^2^+ and [Ag~3(-dppm)~3(~3-eta^1-CC-C~6H~4-NO~2-p)~2]^+Yam, V. W.-W. / Fung, W. K.-M. / Cheung, K.-K. et al. | 1997
- 2033
-
Synthesis of Luminescent Trinuclear Silver(I) Acetylides of Bis(diphenylphosphino)methane and Bis(diphenylphosphino)-n- propylamine. X-ray Crystal Structures of (Ag3(m-dppm)3(m3-h1- C(equivalent)C-C6H4-NO2-p))2+ and (Ag3(m-dppm)3(m3-h1- C(equivalent)C-C6H4-NO2-p)2)+Yam, Vivian Wing-Wah et al. | 1997
- 2038
-
Syntheses and Reactivity of Ruthenium (zigma)-PyridylacetylidesWu, Iuan-Yuan et al. | 1997
- 2038
-
Syntheses and Reactivity of Ruthenium σ-PyridylacetylidesWu, Iuan-Yuan / Lin, Jiann T. / Luo, Jimmy / Sun, Shih-Sheng / Li, Chyi-Shiun / Lin, Kuan J. / Tsai, Chiitang / Hsu, Chia-Chen / Lin, Jiunn-Lih et al. | 1997
- 2049
-
Reactivity of a (eta^5-Phospholyl)cobalt Dicarbonyl Complex. Synthesis of [Co~2(eta^5-PC~4H~2^tBu~2)~2(CO)~2] and [Co~2(eta^5-PC~4-H~2^tBu~2)~2(-CHCO~2Et)(CO)~2]Caffyn, A. J. M. / Carmichael, D. / Mathey, F. / Ricard, L. et al. | 1997
- 2049
-
Reactivity of a (η5-Phospholyl)cobalt Dicarbonyl Complex. Synthesis of [Co2(η5-PC4H2 tBu2)2(CO)2] and [Co2(η5-PC4H2 tBu2)2(μ-CHCO2Et)(CO)2]Caffyn, Andrew J. M. / Carmichael, Duncan / Mathey, François / Ricard, Louis et al. | 1997
- 2049
-
Reactivity of a (h5-Phospholyl)cobalt Dicarbonyl Complex. Synthesis of (CO2(h5-PC4H2t Bu2)2(CO)2) and (CO2 (h5-PC4-H2tBu2)2 (m-CHCO2Et)(CO)2)Caffyn, Andrew J.M. et al. | 1997
- 2055
-
(zigma)-P* Electronic Transition of the Di- and Trinuclear Complexes Ru(E)-(E')(CO)2(iPr-DAB): Resonance Raman, Electronic Absorption, Emission, and Density Functional Study (EAarnts, Maxim P. et al. | 1997
- 2055
-
σ−π* Electronic Transition of the Di- and Trinuclear Complexes Ru(E)(E‘)(CO)2(iPr-DAB): Resonance Raman, Electronic Absorption, Emission, and Density Functional Study (E = Me, SnPh3, M(CO)5; E‘ = M(CO)5; M = Mn, Re; iPr-DAB = N,N‘-Diisopropyl-1,4-diaza-1,3-butadiene)Aarnts, Maxim P. / Wilms, Maikel P. / Stufkens, Derk J. / Baerends, Evert Jan / Vlček, Antonín et al. | 1997
- 2063
-
A New Series of Mono- and Dinuclear Hydridosilylrhodium(III) Complexes, RhCl(H)(SiAr3)L2 and RhL(SiAr3)H(μ-Cl)(μ-H)RhH(SiAr3)L (L = P(i-Pr3)). Preparation by Oxidative Addition of HSiAr3 and Molecular Structures of the ComplexesOsakada, Kohtaro / Koizumi, Take-aki / Yamamoto, Takakazu et al. | 1997
- 2063
-
A New Series of Mono- and Dinuclear Hydridosilylrhodium(III) Complexes, RhCl(H)(SiAr3)L2 and RhL(SiAr3)H (m-Cl)(m-H)RhH(SiAr3)L (LOsakada, Kohtaro et al. | 1997
- 2070
-
Organic-Organometallic Crystal Synthesis. 1. Hosting Paramagnetic ((h6-Arene)2Cr)+ (AreneBraga, Dario et al. | 1997
- 2070
-
Organic-Organometallic Crystal Synthesis. 1. Hosting Paramagnetic [eta^6-Arene)~2Cr]^+ (Arene = Benzene, Toluene) in Organic Anion Frameworks via O-HO and C-HO Hydrogen BondsBraga, D. / Costa, A. L. / Grepioni, F. / Scaccianoce, L. / Tagliavini, E. et al. | 1997
- 2070
-
Organic−Organometallic Crystal Synthesis. 1. Hosting Paramagnetic [(η6-Arene)2Cr]+ (Arene = Benzene, Toluene) in Organic Anion Frameworks via OH···O and CH···O Hydrogen BondsBraga, Dario / Costa, Anna Luisa / Grepioni, Fabrizia / Scaccianoce, Laura / Tagliavini, Emilio et al. | 1997
- 2080
-
Core Excitation Spectroscopy of Phenyl- and Methyl-Substituted Silanol, Disiloxane, and Disilane Compounds: Evidence for π-Delocalization across the Si−Cphenyl BondUrquhart, Stephen G. / Turci, Cássia C. / Tyliszczak, Tolek / Brook, Michael A. / Hitchcock, Adam P. et al. | 1997
- 2080
-
Core Excitation Spectroscopy of Phenyl- and Methyl-Substituted Silanol, Disiloxane, and Disilane Compounds: Evidence for P-Delocalization across the Si-Cphenyl BondUrquhart, Stephen G. et al. | 1997
- 2080
-
Core Excitation Spectroscopy of Phenyl-and Methyl-Substituted Silanol, Disiloxane, and Disilane Compounds: Evidence for -Delocalization across the Si-C~p~h~e~n~y~lUrquhart, S. G. / Turci, C. C. / Tyliszczak, T. / Brook, M. A. / Hitchcock, A. P. et al. | 1997
- 2089
-
Study of the Bonding Properties of the New Ligands C5H3N(2-R‘)(6-CH2PPhR) toward Rhodium(I). Evidence for a Dynamic Competition for Bonding between O- and N-Donor Centers When R = o-Anisyl, R‘ = MeYang, Hong / Lugan, Noël / Mathieu, René et al. | 1997
- 2089
-
Study of the Bonding Properties of the New Ligands C5H3N(2-R')(6-CH2PPhR) toward Rhodium(I) Evidence for a Dynamic Competition for Bonding between O- and N-Donor Centers When RYang, Hong et al. | 1997
- 2096
-
Ab Initio Studies of Rhodium(I)−N-Alkenylamide Complexes with cis- and trans-Coordinating Phosphines: Relevance for the Mechanism of Catalytic Asymmetric Hydrogenation of Prochiral Dehydroamino AcidsKless, Achim / Börner, Armin / Heller, Detlef / Selke, Rüdiger et al. | 1997
- 2101
-
Site Preference of Ligand and Metal Substitution in Trigonal-Bipyramidal Metal Carbonyl ClustersMacchi, Piero / Proserpio, Davide M. / Sironi, Angelo et al. | 1997
- 2110
-
Unusual Coordination Chemistry of Organoaluminum and -gallium Complexes in N2S and NS Coordination Environments. Synthesis and Crystal Structure of (Me2Al)[NC5H4CMeNNC(S)NC3H7](AlMe2) and (Me2Ga)[PhMeCNNC(S)NPh](GaMe2)Paek, Cheolki / Kang, Sang Ook / Ko, Jaejung / Carroll, Patrick J. et al. | 1997
- 2116
-
Bis[(2-pyridyl)bis(trimethylsilyl)methyl-C,N]germanium(II): A Base-Stabilized Germylene and the Corresponding Germanethione, Germaneselenone, and GermanetelluroneOssig, Günter / Meller, Anton / Brönneke, Christiane / Müller, Olaf / Schäfer, Martina / Herbst-Irmer, Regine et al. | 1997
- 2121
-
Spectroscopic and Oxidation Studies of meso-Tetraphenyltetrabenzoporphyrin Carbonyl Complexes of Ruthenium(II): CO as the Probe to Elucidate the Bonding Characteristics of PorphyrinsCheng, Ru-Jen / Lin, Shang-Ho / Mo, Hsiao-Mei et al. | 1997
- 2127
-
The Difficulty of Coordinating Mutually trans Phosphine and Aryl Ligands in Palladium Complexes and Its Relation to Important Coupling Processes. Syntheses and Crystal Structures of a Family of Palladium Phosphino, Triflato, Perchlorato, and Aquo-2-(arylazo)aryl ComplexesVicente, José / Arcas, Aurelia / Bautista, Delia / Jones, Peter G. et al. | 1997
- 2139
-
Cationic Bis- and Tris(h2-(pyrazol-1-yl)-methane) Acetyl Complexes of Iron(II) and Ruthenium(II): Synthesis, Characterization, Reactivity, and Interionic Solution Structure by NOESY NMR SpectroscopyMacchioni, Alceo et al. | 1997
- 2139
-
Cationic Bis- and Tris(eta^2-(pyrazol-1-yl)methane) Acetyl Complexes of Iron(II) and Ruthenium(II): Synthesis, Characterization, Reactivity, and Interionic Solution Structure by NOESY NMR SpectroscopyMacchioni, A. / Bellachioma, G. / Cardaci, G. / Gramlich, V. / Rueegger, H. / Terenzi, S. / Venanzi, L. M. et al. | 1997
- 2139
-
Cationic Bis- and Tris(η2-(pyrazol-1-yl)methane) Acetyl Complexes of Iron(II) and Ruthenium(II): Synthesis, Characterization, Reactivity, and Interionic Solution Structure by NOESY NMR SpectroscopyMacchioni, Alceo / Bellachioma, Gianfranco / Cardaci, Giuseppe / Gramlich, Volker / Rüegger, Heinz / Terenzi, Silvia / Venanzi, Luigi M. et al. | 1997
- 2146
-
Synthesis of Palladium Sulfonium Ylides and the Structures of trans-[PdCl(CH2SR2)(PBut 2H)2]X (X = CF3SO3, SR2 = Tetrahydrothiophene; X = PF6, R = Et)Leoni, Piero / Marchetti, Fabio / Paoletti, Marco et al. | 1997
- 2146
-
Synthesis of Palladium Sulfonium Ylides and the Structures of trans-(PdCl-(CH2SR2)(PBut2H)2)X (XLeoni, Piero et al. | 1997
- 2152
-
Trinuclear Cluster Complexes Containing the Furyne Ligand: Synthesis, Structure, and Properties of the Cycloalkyne Complexes (CpCo) n (Cp*Co)3-n (CO)(μ3-η2-C4H4O) (n = 3, 2)King, William D. / Barnes, Craig E. / Orvis, Jeffery A. et al. | 1997
- 2152
-
Trinuclear Cluster Complexes Containing the Furyne Ligand: Synthesis, Structure, and Properties of the Cycloalkyne Complexes (CpCO)n(Cp*Co)3-n(CO)(m3-h2- C4H4O) (nKing, William D. et al. | 1997
- 2152
-
Trinuclear Cluster Complexes Containing the Furyne Ligand: Synthesis, Structure, and Properties of the Cycloalkyne Complexes (CpCo)~n(Cp^*Co)~3~-~n(CO)(~3-eta^2-C~4H~4O) (n = 3, 2)King, W. D. / Barnes, C. E. / Orvis, J. A. et al. | 1997
- 2160
-
Reactions of a Dicarbenium Fulvalenyl Complex with Aromatic Nucleophiles and Synthesis of (μ-Alkyne)(fulvalenyl)tetracarbonyldimolybdenum Compounds: A Structure−Reactivity RelationshipAmouri, H. / Besace, Y. / Ricard, L. et al. | 1997
- 2160
-
Reactions of a Dicarbenium Fulvalenyl Complex with Aromatic Nucleophiles and Synthesis of (m-Alkyne)(fulvalenyl) tetracarbonyldimolybdenum Compounds: A Structure-Reactivity RelationshipAmouri, H. et al. | 1997
- 2165
-
Models for Platinum−Rhenium Bimetallic Catalysts: Sulfidation of Pt3Re ClustersHao, Leijun / Xiao, Jianliang / Vittal, Jagadese J. / Puddephatt, Richard J. et al. | 1997
- 2175
-
Water and Protic Acids as Oxidants for Platinum(II): Diorgano(hydrido)platinum(IV) and Diorgano(hydroxo)platinum(IV) Chemistry, Including Structural Studies of Poly(pyrazol-1-yl)borate Complexes Pt(OH)R2{(pz)3BH} (R = Methyl, p-Tolyl) and Pt(OH)Me2{(pz)4B}·H2OCanty, Allan J. / Fritsche, Steven D. / Jin, Hong / Patel, Jim / Skelton, Brian W. / White, Allan H. et al. | 1997
- 2175
-
Water and Protic Acids as Oxidants for Platinum(II): Diorgano(hydrido)platinum(IV) and Diorgano(hydrexo)platinum(IV) Chemistry, Including Structural Studies of Poly(pyrazol-1-yl)borate Complexes Pt(OH)R~2{(pz)~3BH} (R = Methyl, p-Tolyl) and Pt(OH)Me~2{(pz)~4B}H~2OCanty, A. J. / Fritsche, S. D. / Jin, H. / Patel, J. / Skelton, B. W. / White, A. H. et al. | 1997
- 2175
-
Water and Protic Acids as Oxidants for Platinum(II): Diorgano(hydrido)platinum(IV)' and Diorgano(hydroxo)platinum(IV) Chemistry, Including Structural Studies of Poly(pyrazol-1-yl)borate Complexes Pt(OH)R2((pz)3BH) (RCanty, Allan J. et al. | 1997
- 2183
-
C−H and C−S Bond Cleavage in Cyclopentadienyltitanium Phenoxide Thiolate ComplexesFirth, Andrea V. / Stephan, Douglas W. et al. | 1997
- 2189
-
Rearrangement of Rhenium Allyl Vinyl Ketone ComplexesCasey, Charles P. / Underiner, Todd L. / Vosejpka, Paul C. / Slough, Greg A. / Gavney, James A. / Hayashi, Randy K. et al. | 1997
- 2200
-
Reactivity of a Donor-Stabilized Bis(silylene)ruthenium Complex toward Nucleophiles ROH (RWada, Hiroaki et al. | 1997
- 2200
-
Reactivity of a Donor-Stabilized Bis(silylene)ruthenium Complex toward Nucleophiles ROH (R = Me, H)Wada, Hiroaki / Tobita, Hiromi / Ogino, Hiroshi et al. | 1997
- 2204
-
Preparation of Silyl Enol Ethers by the Reaction of Ketones with Silylamines and Methyl IodideYamamoto, Yasushi / Matui, Chinami et al. | 1997
- 2207
-
Synthesis of Olefins by the Reaction of β-((Trimethylsilyl)oxy)alkyl Iodides with ZincYamamoto, Yasushi / Saito, Kenji et al. | 1997
- 2207
-
Synthesis of Olefins by the Reaction of b-((Trimethylsilyl)oxy)alkyl Iodides with ZincYamamoto, Yasushi et al. | 1997
- 2209
-
Nickel(II) Complexes of N-Heterocyclic Carbenes †Herrmann, Wolfgang A. / Gerstberger, Gisela / Spiegler, Michael et al. | 1997
- 2213
-
Reactions of Cobaltadithiolenes with GermanorbornadieneFormation and Structure of Unique Binuclear Cobalt Complexes Containing a Bridging Dimethylgermylene MoietyKajitani, Masatsugu / Adachi, Sachiyo / Takayama, Chikako / Sakurada, Masami / Yamazaki, Mikio / Akiyama, Takeo / Sugimori, Akira et al. | 1997
- 2216
-
Reaction of Alkenylzirconocenes with Dialkylzirconocenes: Unexpected Formation of Bimetallic (μ-Alkynyl)zirconocene ComplexesTakahashi, Tamotsu / Nishihara, Yasushi / Sun, Wen-Hua / Fischer, Reinald / Nakajima, Kiyohiko et al. | 1997
- 2216
-
Reaction of Alkenylzirconocenes with Dialkylzirconocenes: Unexpected Formation of Bimetallic (m-Alkynyl)zirconocene ComplexesTakahashi, Tamotsu et al. | 1997
- 2220
-
Diastereospecific Dimerization in Bridging Amido Complexes of DipalladiumCuevas, José V. / García-Herbosa, Gabriel / Muñoz, Asunción / García-Granda, Santiago / Miguel, Daniel et al. | 1997
- 2223
-
Inhibition of the Cyclotrimerization of Benzonitrile and the Likely Mechanism of the Cyclotrimerization Process: Structure of a New Tetrameric α-Amino Lithium Imide Demonstrating Intramolecular Stabilization of the Metal CentersDavies, Robert P. / Raithby, Paul R. / Shields, Gregory P. / Snaith, Ronald / Wheatley, Andrew E. H. et al. | 1997
- 2223
-
Inhibition of the Cyclotrimerization of Benzonitrile and the Likely Mechanism of the Cyclotrimerization Process: Structure of a New Tetrameric a-Amino Lithium Imide Demonstrating Intramolecular Stabilization of the Metal CentersDavies, Robert P. et al. | 1997
- 2226
-
Electronic Effects in Asymmetric Catalysis. Synthesis and Structure of Model Rhodium Complexes Containing Ferrocenyl Ligands for Use in the Hydroboration Reaction.Schnyder, Anita / Togni, Antonio / Wiesli, Ursula et al. | 1997