1,3-Diadamantylallene. Trapping of a biradical intermediate in thermal dimerization of substituted allenes (English)
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- New search for: Jacobs, Thomas L.
- New search for: Kammerer, R. Craig
- New search for: Jacobs, Thomas L.
- New search for: Kammerer, R. Craig
In:
Journal of the American Chemical Society
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94
, 20
;
7190-7191
;
1972
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ISSN:
- Article (Journal) / Electronic Resource
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Title:1,3-Diadamantylallene. Trapping of a biradical intermediate in thermal dimerization of substituted allenes
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Additional title:J. Am. Chem. Soc.
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Contributors:Jacobs, Thomas L. ( author ) / Kammerer, R. Craig ( author )
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Published in:Journal of the American Chemical Society ; 94, 20 ; 7190-7191
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Publisher:
- New search for: American Chemical Society
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Publication date:1972-10-01
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ISSN:
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Coden:
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DOI:
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Type of media:Article (Journal)
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Type of material:Electronic Resource
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Language:English
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Source:
Table of contents – Volume 94, Issue 20
The tables of contents are generated automatically and are based on the data records of the individual contributions available in the index of the TIB portal. The display of the Tables of Contents may therefore be incomplete.
- 1A
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Masthead| 1972
- 6877
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Evaluation of models and effects contributing to solvent-transfer energiesNozari, Russell S. et al. | 1972
- 6883
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Triplet energy transfer. VIII. Sterically indifferent triplet energy transferWagner, Peter J. / McGrath, Joseph M. / Zepp, Richard G. et al. | 1972
- 6886
-
Rate constants for radical recombination. IV. Activation energy for ethyl radical recombinationHiatt, R. / Benson, S. W. et al. | 1972
- 6888
-
Singlet-triplet energy separation, Walsh-Mulliken diagrams, and singlet d-polarization effects in methyleneBender, Charles F. / Schaefer, Henry F. / Franceschetti, Donald R. / Allen, Leland C. et al. | 1972
- 6894
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Methyl rotation barriers and hyperconjugationLiberles, Arno / O'Leary, Brian / Eilers, James E. / Whitman, Donald R. et al. | 1972
- 6899
-
Core-level binding energy shifts and the average quantum mechanical potential at a nucleus from CNDO [complete neglect of differential overlap] theorySchwartz, Maurice E. et al. | 1972
- 6901
-
Molecular orbital theory of the electronic structure of organic compounds. XV. Protonation of benzeneHehre, Warren J. / Pople, John A. et al. | 1972
- 6904
-
Ab initio calculations on large molecules using molecular fragments. Characterization of nitrogen-containing moleculesGenson, Donald W. / Christoffersen, Ralph E. et al. | 1972
- 6914
-
Intermolecular interactions in nuclear magnetic resonance. VII. Role of the internal reference in aromatic solvent induced shiftsRummens, Frans H. A. / Krystynak, Ronald H. et al. | 1972
- 6921
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Proton nuclear magnetic resonance study of diamagnetic cation association with hydroxylic substates. Interpretation of ionic molal shifts in methanol and waterStockton, Gerald W. / Martin, John S. et al. | 1972
- 6930
-
ENDOR-detected nuclear magnetic resonance studies of small ring systems. I. (CH2)3C(COOD)2 [1,1-cyclobutanedicarboxylic acid d2]Dalton, Larry R. / Kwiram, Alvin L. et al. | 1972
- 6938
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Phenalenyl dimer cation and its electron paramagnetic resonance spectrumPaskovich, D. H. / Reddoch, A. H. et al. | 1972
- 6940
-
Topological representation of permutational isomerization reactionsKlemperer, W. G. et al. | 1972
- 6944
-
Mechanism of reduction of cobalt(III) and ruthenium(III) hexaammine complexes by several aliphatic radicalsCohen, H. / Meyerstein, D. et al. | 1972
- 6949
-
Synthesis and solution behavior of some .pi.-allyl monothiodibenzoylmethanatopalladium(II) complexesLippard, Stephen J. / Morehouse, Sheila M. et al. | 1972
- 6956
-
Crystal and molecular structure of monothiodibenzoylmethanato-.pi.-syn-1-tert-butyl-2-methallylpalladium(II)Lippard, Stephen J. / Morehouse, Sheila M. et al. | 1972
- 6961
-
Reactions of eitht-coordinate metal cyanide complexes. IV. Synthesis and spectroscopic and structural properties of tetracyanotetrakis(alkyl isocyanide)molybdenum(IV) complexesNovotny, M. / Lewis, D. F. / Lippard, S. J. et al. | 1972
- 6968
-
Chemical evolution. IX. Mechanism of the oligomerization of hydrogen cyanide and its possible role in the origins of lifeFerris, J. P. / Donner, D. B. / Lotz, W. et al. | 1972
- 6975
-
Substitution at a saturated carbon atom. XIV. Case for discrete, distinct allylically related ion pairsSneen, Richard A. / Bradley, William A. et al. | 1972
- 6983
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Substitution at a saturated carbon atom. XV. Ion-pair phenomena in selected allylic systemsSneen, Richard A. / Kay, Peter S. et al. | 1972
- 6990
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Substitution at a saturated carbon atom. XVI. Supporting evidence for discrete, distinct allylically related ion pairsSneen, Richard A. / Carter, John V. et al. | 1972
- 6998
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Structural effects on rates and equilibriums. XVI. Effect of adjacent unshared electron pairs on ease of carbanion formationHine, Jack / Dalsin, Philip D. et al. | 1972
- 7002
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Effect of solvent on the ground states and transition states in the reactions of 2,4,6-tri-tert-butylphenoxy radical with phenolsMahoney, L. R. / DaRooge, M. A. et al. | 1972
- 7010
-
Solvolytic behavior of the four epimeric 7-chloro-2-hydroxybicyclo[2.2.1]heptane p-toluenesulfonatesGassman, Paul G. / Hornback, Joseph M. et al. | 1972
- 7016
-
Vinyl ether hydrolysis. II. General acid catalyzed hydration of 3-alkyloxy- and 3-aryloxycrotonic acid derivativesBrynes, Steven D. / Fedor, Leo R. et al. | 1972
- 7020
-
Acetopyruvic acid. Rate and equilibrium constants for hydration and enolizationGuthrie, J. Peter et al. | 1972
- 7024
-
Acetopyruvate. Enamine formation with aminoacetonitrile. Models for acetoacetate decarboxylaseGuthrie, J. Peter et al. | 1972
- 7030
-
Isomeric distributions and relative reactivities in the uncatalyzed chlorination of benzonitrile, nitrobenzene, and benzotrifluoride. Directive effects of electron-withdrawing substituents as a function of reagent and solventBaciocchi, Enrico / Cacace, Fulvio / Ciranni, Giovanna / Illuminati, Gabriello et al. | 1972
- 7034
-
Reversible hydrogen abstraction. Mechanism of trichlorovinylationTanner, Dennis D. / Lewis, Stephen C. / Wada, Naoto et al. | 1972
- 7040
-
Kinetic applications of electron paramagnetic resonance spectroscopy. VII. Self-reactions of iminoxy radicalsBrokenshire, J. L. / Roberts, J. R. / Ingold, K. U. et al. | 1972
- 7049
-
Stable free radicals. X. Nitronyl nitroxide monoradicals and biradicals as possible small molecule spin labelsUllman, Edwin F. / Osiecki, Jeanne H. / Boocock, D. G. B. / Darcy, R. et al. | 1972
- 7059
-
Kinetics of the reaction of methyllithium with 2,4-dimethyl-4'-methylthiobenzophenoneSmith, Stanley G. / Charbonneau, L. F. / Novak, David P. / Brown, Theodore L. et al. | 1972
- 7063
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Bishomotropylium ions under conditions of long and short lifeAhlberg, Per / Harris, D. L. / Roberts, Mark / Warner, P. / Seidl, P. / Sakai, M. / Cook, D. / Diaz, A. / Dirlam, J. P. et al. | 1972
- 7074
-
Siloxy-Cope and oxy-Cope rearrangements of the cis-1-vinylcyclonon-3-en-1-o1 system. Effective two-carbon ring expansionThies, Richard W. et al. | 1972
- 7081
-
Intramolecular and intermolecular pathways to nortricyclane in Bamford-Stevens reactionsNickon, Alex / Werstiuk, Nick H. et al. | 1972
- 7087
-
Wittig reactions of 1,2-benzocyclobutadienequinone. Synthesis of 2-thianorbiphenylene (benzo[3,4]cyclobuta[1,2-c]thiopheneGarratt, P. J. / Vollhardt, K. Peter C. et al. | 1972
- 7092
-
Bicyclo[3.3.3.]undecane and 1-azabicyclo[3.3.3]undecane. Geometry, strain, and spectroscopic behavior of these systemsColl, John C. / Crist, DeLanson R. / Barrio, Maria del C. G. / Leonard, Nelson J. et al. | 1972
- 7100
-
Crystal and molecular structure of 1-azabicyclo [3.3.3] undecane hydrochloride. Correlation of some molecular dimensions with spectroscopic propertiesWang, Andrew H. J. / Missavage, Roger J. / Byrn, Stephen R. / Paul, Iain C. et al. | 1972
- 7105
-
Nuclear magnetic resonance spectra of bridgehead diazabicyclo[3.3.1]nonanes and -[3.2.1]octanes and adamantanes. Effects of alkyl substitutionNelsen, Stephen F. / Hintz, P. J. / Landis, R. T. et al. | 1972
- 7108
-
Electrochemical oxidation of tetraalkylhydrazines. Effects of hydrazine and hydrazine radical cation geometryNelsen, S. F. / Hintz, P. J. et al. | 1972
- 7114
-
Electrochemical oxidation of tertiary amines. Effect of structure upon reversibilityNelsen, S. F. / Hintz, P. J. et al. | 1972
- 7118
-
Functionalization reactions of[4.4.2]propella-3,11-dienePaquette, Leo A. / Thompson, Gerald L. et al. | 1972
- 7127
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Stereochemical features of the thermal and photochemical fragmentations of [4.4.2]propella-2,4-dienesPaquette, Leo A. / Thompson, Gerald L. et al. | 1972
- 7132
-
Total synthesis of longifoleneMcMurry, John E. / Isser, Stephen J. et al. | 1972
- 7137
-
Direct determination of the spatial geometry of molecules in solution. I. Conformation of chloroquine, an antimalarialAngerman, Neil S. / Danyluk, Steven S. / Victor, Thomas A. et al. | 1972
- 7147
-
Boat and chair transition states of 1,5-hexadieneGoldstein, M. J. / Benzon, M. S. et al. | 1972
- 7149
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Linear analysis of labeling experiments. Application to sigmatropic rearrangements of 1,5-hexadieneGoldstein, M. J. / Benzon, M. S. et al. | 1972
- 7151
-
Mechanisms of photochemical reactions in solution. LXXII. Electronic pathways in the photodissociation of 3-methyl-1-phenoxybut-2-eneCarroll, Felix A. / Hammond, George S. et al. | 1972
- 7152
-
Photochemical behavior of trans-chloroisothiocyanatobis(ethylenediamine)chromium(III)Gandolfi, M. T. / Manfrin, M. F. / Moggi, L. / Balzani, V. et al. | 1972
- 7154
-
Selenium dioxide oxidation of olefins. Evidence for the intermediacy of allylseleninic acidsSharpless, K. B. / Lauer, R. F. et al. | 1972
- 7155
-
Reactions of .pi.-allylnickel bromide complexes with conjugated systems. I. Reaction with quinones. Synthesis of coenzyme Q1 and plastoquinone-1Hegedus, L. S. / Waterman, E. L. / Catlin, J. et al. | 1972
- 7157
-
Energy-dependent ring opening of cycloalkane parent ionsSieck, L. W. / Gorden, R. / Ausloos, P. et al. | 1972
- 7159
-
Lithium tri-sec-butylborohydride. New reagent for the reduction of cyclic and bicyclic ketones with super stereoselectivity. Remarkably simple and practical procedure for the conversion of ketones to alcohols in exceptionally high stereochemical purityBrown, Herbert C. / Krishnamurthy, S. et al. | 1972
- 7161
-
Novel iron carborane .mu. and .pi. complexes derived from nido-C2B4H8. Paramagnetic small carborane sandwich compoundSneddon, Larry G. / Grimes, Russell N. et al. | 1972
- 7162
-
Medium effects on the lifetime and reactivity of triplet exciplexesRoy, J. K. / Whitten, David G. et al. | 1972
- 7164
-
Stereospecific synthesis of the (E,E)- and (Z,E)-5,6-diphenyl-o-xylylene dianions. Stereochemistry of cycloreversion of the cis- and trans-3,4-diphenylbenzocyclobutene anion radicalsBauld, Nathan L. / Chang, Chiu-Shan / Farr, Frank R. et al. | 1972
- 7165
-
Carbon-hydrogen insertion in the copper-catalyzed decomposition of diazomethane in hexamethyldisilane. Silicon .alpha. effectConlin, Robert T. / Gaspar, Peter P. / Levin, Ronald H. / Jones, Maitland et al. | 1972
- 7166
-
Dimerization of nortropane N-oxylMendenhall, G. D. / Ingold, K. U. et al. | 1972
- 7168
-
Generation of dimethylenecyclobutenes from cyclobutadieneiron tricarbonyl complexes. Synthesis of cyclobutadienopleiadiene and .alpha.,.alpha.,-diphenyldimethylenecyclobuteneRoberts, Bryan W. / Wissner, Allan et al. | 1972
- 7169
-
Azetidinone antibiotics. V. Reversible interconversions of penam and cepham systems via a common thiiranium ion intermediateKukolja, Stjepan / Lammert, S. R. et al. | 1972
- 7170
-
Stereospecific reduction of epoxides with sodium (cyclopentadienyl)dicarbonylferrate. New route to cationic iron-olefin complexesGiering, W. P. / Rosenblum, M. / Tancrede, J. et al. | 1972
- 7172
-
Total synthesis of cephalotaxineAuerbach, Joseph / Weinreb, Steven M. et al. | 1972
- 7173
-
Coordinated nitrene formation by the photolysis of azidopentaammine complexes of rhodium(III) and iridium(III)Reed, James L. / Wang, Francis / Basolo, Fred et al. | 1972
- 7174
-
Carbene radical anions. New species of reactive intermediateSargent, G. Dann / Tatum, Charles M. / Kastner, Scott M. et al. | 1972
- 7176
-
Epimerization in the preparation of purine nucleosides by the fusion reactionMontgomery, John A. / Hewson, Kathleen / Laseter, Anne G. / Thorpe, Martha C. et al. | 1972
- 7178
-
Activated metals. I. Preparation of highly reactive magnesium metalRieke, Reuben D. / Hudnall, Phillip M. et al. | 1972
- 7179
-
Mechanism of rearrangement of molecules containing cyclobutane rings 1,3 bridged by ethyleneGold, Avram / Borden, Weston Thatcher et al. | 1972
- 7180
-
Reaction of oxazoles with singlet oxygen. Mechanism of the rearrangement of triamidesWasserman, H. H. / Vinick, F. J. / Chang, Y. C. et al. | 1972
- 7182
-
Chemical model for thymidylate synthetase catalysisWilson, Raymond S. / Mertes, Mathias P. et al. | 1972
- 7183
-
Chemistry of bent bonds. XXX. Diels-Alder approach to inside-outside bicyclicsGassman, Paul G. / Thummel, Randolph P. et al. | 1972
- 7184
-
Bicyclo[8.8.8]hexacosane. Out, in isomerismPark, C. H. / Simmons, H. E. et al. | 1972
- 7186
-
Corborundanes. II. Derivative chemistry of a very reluctantly reactive bridgehead silicon centerFrye, C. L. / Klosowski, J. M. et al. | 1972
- 7187
-
Mechanism of interconversion of (Z)-and (E)-ketiminesJennings, W. Brian / Boyd, Derek R. et al. | 1972
- 7189
-
Ligand-induced disproportionation of silver(I)Kestner, M. O. / Allred, A. L. et al. | 1972
- 7190
-
1,3-Diadamantylallene. Trapping of a biradical intermediate in thermal dimerization of substituted allenesJacobs, Thomas L. / Kammerer, R. Craig et al. | 1972
- 7191
-
Electron spectroscopy of organic ions. III. Alkyl- and aryloxocarbenium ions (acyl cations)Mateescu, Gheorghe D. / Riemenschneider, J. Louise / Svoboda, James J. / Olah, George A. et al. | 1972
- 7192
-
Ratio of terminal to central addition of fluorine atoms to propyleneWilliams, Ronald L. / Iyer, R. Subramonia / Rowland, F. S. et al. | 1972
- 7194
-
Tumor inhibitors. LXXIV. Triptolide and tripdiolide, novel antileukemic diterpenoid triepoxides from Tripterygium wilfordiiKupchan, S. Morris / Court, William A. / Dailey, Richard G. / Gilmore, Christopher J. / Bryan, Robert F. et al. | 1972
- 7195
-
Cholesteric solidsMahler, Walter / Panar, M. et al. | 1972
- 7197
-
Photochemically induced dynamic electron spin polarization. 1,4-Naphthosemiquinone radical in 2-propanolWong, S. K. / Wan, J. K. S. et al. | 1972
- 7198
-
Stable transition metal .pi. complex of dimethylaminopentaleneHunt, D. F. / Russell, J. W. et al. | 1972
- 7199
-
Inverse .beta.-deuterium isotope effect in the solvolysis of a 1-azabicyclo[1.1.0]butaneGillard, Baiba K. / Kurz, Joseph L. et al. | 1972
- 7201
-
Energetics of the cis-trans interconversion of a bicyclo[5.1.0]octane systemPirkle, W. H. / Lunsford, W. B. et al. | 1972
- 7202
-
Carbon-carbon bond formations promoted by transition metal carbonyls. III. Mechanistic aspects of the reaction of .alpha.,.alpha.1-dibromo ketones and iron carbonyl. Reductive rearrangements of dibromo ketonesNoyori, R. / Hayakawa, Y. / Funakura, M. / Takaya, H. / Murai, Shinji / Kobayashi, Ryoichi / Tsutsumi, Shigeru et al. | 1972
- 7204
-
Orientation dilemma in alkaline halogenation of 2-butanoneSwain, C. Gardner / Dunlap, Richard P. et al. | 1972
- 7205
-
Stereochemistry of metal anion substitutions on carbonKoermer, G. S. / Hall, M. L. / Traylor, T. G. et al. | 1972
- 7206
-
Solvent and counterion control of stereochemistry in a formal nucleophilic displacement reaction. Mechanisms of reaction of trimethyltin alkalis with alkyl halidesKuivila, H. G. / Considine, J. L. / Kennedy, J. D. et al. | 1972
- 7208
-
Aprotic solvent effects on the fluorine nuclear magnetic resonance shifts of p-substituted fluorobenzenesBrownlee, R. T. C. / Dayal, S. K. / Lyle, J. L. / Taft, R. W. et al. | 1972
- 7210
-
Mixed cuprate reagents of type R1R2CuLi which allow selective group transferCorey, E. J. / Beames, David J. et al. | 1972
- 7211
-
Intermediate species in aluminum(III)-catalyzed transamination in methanolMatsumoto, Shigenobu / Matsushima, Yoshikazu et al. | 1972
- 7213
-
Mixed oxidation states in osmium ammine dinitrogen complexesMagnuson, R. H. / Taube, H. et al. | 1972
- 7215
-
Book Reviews| 1972