Absolute hardness: companion parameter to absolute electronegativity (English)
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- New search for: Parr, Robert G.
- New search for: Pearson, Ralph G.
- New search for: Parr, Robert G.
- New search for: Pearson, Ralph G.
In:
Journal of the American Chemical Society
;
105
, 26
;
7512-7516
;
1983
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ISSN:
- Article (Journal) / Electronic Resource
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Title:Absolute hardness: companion parameter to absolute electronegativity
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Additional title:J. Am. Chem. Soc.
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Contributors:Parr, Robert G. ( author ) / Pearson, Ralph G. ( author )
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Published in:Journal of the American Chemical Society ; 105, 26 ; 7512-7516
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Publisher:
- New search for: American Chemical Society
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Publication date:1983-12-01
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ISSN:
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Coden:
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DOI:
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Type of media:Article (Journal)
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Type of material:Electronic Resource
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Language:English
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Source:
Table of contents – Volume 105, Issue 26
The tables of contents are generated automatically and are based on the data records of the individual contributions available in the index of the TIB portal. The display of the Tables of Contents may therefore be incomplete.
- 7479
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Polarized nonvertical excited states: FORS MCSCF and CI study of torsion and bending in alleneLam, Brenda / Johnson, Richard P. et al. | 1983
- 7484
-
Reactions of iron(1+) ion and (olefin)iron(1+) ion complexes with alkenes in the gas phase using Fourier transform mass spectrometryJacobson, D. B. / Freiser, B. S. et al. | 1983
- 7492
-
Reactions of Group 8 transition-metal ions (iron(1+), cobalt(1+), and nickel(1+)) with cyclic hydrocarbons in the gas phaseJacobson, D. B. / Freiser, B. S. et al. | 1983
- 7500
-
Ab Initio Calculation of Resonance Energies. Benzene and CyclobutadieneHess, B. A. / Schaad, L. J. et al. | 1983
- 7506
-
Analytic energy second derivatives for two-configuration self-consistent-field wave functions. Application to twisted ethylene and to the trimethylene diradicalYamaguchi, Yukio / Osamura, Yoshihiro / Schaefer, Henry F. et al. | 1983
- 7512
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Absolute hardness: companion parameter to absolute electronegativityParr, Robert G. / Pearson, Ralph G. et al. | 1983
- 7516
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ESR study of the electronic structure and dynamic Jahn-Teller effect in nickelocenium cationRajasekharan, M. V. / Bucher, R. / Deiss, E. / Zoller, L. / Salzer, A. K. / Moser, E. / Weber, J. / Ammeter, J. H. et al. | 1983
- 7523
-
Carbon-13{deuteron} polarization transfer studies: new NMR methods for isotopic labeling studiesRinaldi, Peter L. / Baldwin, Nicholas J. et al. | 1983
- 7528
-
Energy disposal in the photofragmentation of keteneSonobe, Blake I. / Rosenfeld, Robert N. et al. | 1983
- 7531
-
Photoionization study of hydrogen sulfide ((H2S)2 and (H2S)3)Prest, H. F. / Tzeng, W. B. / Brom, J. M. / Ng, C. Y. et al. | 1983
- 7536
-
Analysis of fully anisotropic overall molecular tumbling with group internal rotation: steroid examplesLevy, George C. / Kumar, Anil / Wang, Dehua et al. | 1983
- 7541
-
Mechanism for forming sodium pyrosulfate from sodium chloride, sulfur dioxide, and oxygenAnderson, Alfred B. / Hung, S. C. et al. | 1983
- 7543
-
Theoretical study of the triple metal bond in d3-d3 binuclear complexes of chromium, molybdenum, tungsten by the Hartree-Fock-Slater transition state methodZiegler, Tom et al. | 1983
- 7549
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Anion coordination chemistry. Chlorine-35 NMR studies of chloride anion cryptatesKintzinger, Jean Pierre / Lehn, Jean Marie / Kauffmann, Elizabeth / Dye, James L. / Popov, Alexander I. et al. | 1983
- 7553
-
Origin of asymmetry in nitrogen hyperfine interactions in metmyoglobinMishra, K. C. / Mishra, Santosh K. / Scholes, C. P. / Das, T. P. et al. | 1983
- 7556
-
Alterdentate ligands: determination of the energy barrier for intramolecular metal ion exchange in complexes of ninhydrin and alloxan radical ions with zinc(2+), magnesium(2+), cadmium(2+), and yttrium(3+)Daul, C. / Deiss, E. / Gex, J. N. / Perret, D. / Schaller, D. / Von Zelewsky, A. et al. | 1983
- 7563
-
Nuclear magnetic resonance and calorimetric studies on the solvation of cryptand C221 and its sodium(+) and potassium(+) ion complexes in nonaqueous solventsSchmidt, Emmanuel / Popov, Alexander I. / Kintzinger, Jean Pierre / Tremillon, Jean-Michel et al. | 1983
- 7567
-
Imidazole complexes of low-spin iron(III) porphyrin .pi.-cation radical species. Models for the compound I .pi.-cation radical state of peroxidasesGoff, Harold M. / Phillippi, Martin A. et al. | 1983
- 7572
-
Thermochemical splitting of sulfur dioxide with cerium(IV) oxidePeterson, E. J. / Foltyn, E. M. / Onstott, E. I. et al. | 1983
- 7574
-
Synthesis of molybdenum-rhodium and molybdenum-iridium compounds linked by a heterodifunctional ligand and formation of molybdenum-iridium dihydrides by reaction with molecular hydrogenCasey, Charles P. / Bullock, R. Morris / Nief, Francois et al. | 1983
- 7580
-
A reversible chemical reaction in a single crystal. The dimerization of .eta.5-cyclopentadienyl(o-dithiobenzene)cobalt [CpCo(S2C6H4-o)]Miller, Edward J. / Brill, Thomas B. / Rheingold, Arnold L. / Fultz, William C. et al. | 1983
- 7585
-
Symmetry of the magnetic orbitals and exchange interaction in copper iron (CuIIFeIII) and copper chromium (CuIICrIII) heterobinuclear complexes. Crystal structure of CuFe[(fsa)2en]Cl(H2O)(CH3OH).CH3OHJournaux, Yves / Kahn, Olivier / Zarembowitch, Jacqueline / Galy, Jean / Jaud, Joel et al. | 1983
- 7592
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Model studies of coenzyme B12 dependent diol dehydratase. 1. Synthetic, physical property, and product studies of two key, cobalt-bound, putative diol dehydratase intermediatesFinke, Richard G. / McKenna, William P. / Schiraldi, David A. / Smith, Brad L. / Pierpont, Cortlandt et al. | 1983
- 7605
-
Model studies of coenzyme B12 dependent diol dehydratase. 2. A kinetic and mechanistic study focusing upon the cobalt participation or nonparticipation questionFinke, Richard G. / Schiraldi, David A. et al. | 1983
- 7617
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On the structure and stability of 1,3-dilithiopropanes and other .alpha.,.omega.-dilithioalkanes. The importance of lithium hydride complexes as structural alternatives and reaction intermediatesSchleyer, Paul v. R. / Kos, Alexander J. / Kaufmann, Elmar et al. | 1983
- 7624
-
Kinetics of the superoxide radical oxidation of [cobalt sepulchrate](2+) ion. A flash photolytic studyBakac, Andreja / Espenson, James H. / Creaser, Inge I. / Sargeson, Alan M. et al. | 1983
- 7629
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Isotope effects on hydride transfer between NAD+ analogsOstovic, Drazen / Roberts, Roger M. G. / Kreevoy, Maurice M. et al. | 1983
- 7631
-
Energetics of twisting in the lowest stilbene triplet stateSaltiel, Jack / Rousseau, Alan D. / Thomas, Babu et al. | 1983
- 7638
-
Synthesis of sinefungin and its C-6' epimerGeze, M. / Blanchard, P. / Fourrey, J. L. / Robert-Gero, M. et al. | 1983
- 7640
-
Total synthesis of (.+-.)-elwesine, (.+-.)-epielwesine, and (.+-.)-oxocrinineSanchez, Ignacio H. / Lopez, Francisco J. / Soria, Jose J. / Larraza, Maria Isabel / Flores, Humberto J. et al. | 1983
- 7644
-
Bond fixation in annulenes. 15. A titanium(0)-mediated synthesis of a cyclooctatetraene. Probe of the relative size of the interstitial phenyl substituent in 1,3-dimethyl-2-phenylcyclooctatetraene by means of racemization kineticsPaquette, Leo A. / Gardlik, John M. / McCullough, Kevin J. / Hanzawa, Yuji et al. | 1983
- 7649
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Bond fixation in annulenes. 16. Synthesis of the 1,2-dimethyl-3-phenylcyclooctatetraene .dblarw. 1,8-dimethyl-2-phenylcyclooctatetraene bond shift isomer pair. Probe of the relative size of a flanking phenyl substituent by means of racemization kineticsPaquette, Leo A. / Gardlik, John M. / McCullough, Kevin J. / Samodral, Rodney / DeLucca, George / Ouellette, Robert J. et al. | 1983
- 7655
-
Chemiluminescence mechanism of cyclic hydrazides such as luminol in aqueous solutionsLind, J. / Merenyi, G. / Eriksen, T. E. et al. | 1983
- 7662
-
A plausible mechanism for the chemiexcitation of cyclic hydrazides. The "double-crossing" modelLjunggren, S. / Merenyi, G. / Lind, J. et al. | 1983
- 7666
-
Carbon-14 kinetic isotope effects and mechanisms of addition of 2,4-dinitrobenzenesulfenyl chloride to substituted styrenes-1-14C and styrenes-2-14CKanska, Marianna / Fry, Arthur et al. | 1983
- 7672
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Mechanisms of epoxidations and chlorinations of hydrocarbons by inorganic hypochlorite in the presence of a phase-transfer catalystFonouni, Hossein E. / Krishnan, S. / Kuhn, David G. / Hamilton, Gordon A. et al. | 1983
- 7676
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Pressure effect on tunneling of the proton- and deuteron-transfer reaction of 2,4,6-trinitrotoluene with 1,8-diazabicyclo[5.4.0]undec-7-ene in acetonitrileSugimoto, Naoki / Sasaki, Muneo / Osugi, Jiro et al. | 1983
- 7681
-
Gas-phase reactions. 36. Pyrolysis of vinyl azideBock, Hans / Dammel, Ralph / Aygen, Sitki et al. | 1983
- 7685
-
Cyclobutane-bicyclobutane systems. 5. Zwitterionic bicyclobutane: an intermediate in the course of nucleophilic vinylic-like substitution reaction on 3-halobicyclobutanecarbonitrileHoz, Shmaryahu / Aurbach, Doron et al. | 1983
- 7691
-
Oxygenation by superoxide ion of tetrachloromethane, trichlorofluoromethane, trichloromethane, p,p'-DDT and related trichloromethyl substrates (RCCl3) in aprotic solventsRoberts, Julian L. / Calderwood, Thomas S. / Sawyer, Donald T. et al. | 1983
- 7696
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Diels-Alder reactions of 1-azadienesCheng, Yea Shun / Lupo, Andrew T. / Fowler, Frank W. et al. | 1983
- 7703
-
Heterocycles as masked diamide/dipeptide equivalents. Formation and reactions of substituted 5-(acylamino)oxazoles as intermediates en route to the cyclopeptide alkaloidsLipshutz, Bruce H. / Hungate, Randall W. / McCarthy, Keith E. et al. | 1983
- 7713
-
Camphorae: chiral intermediates for the enantiospecific total synthesis of steroids. 1Stevens, Robert V. / Gaeta, Fred C. A. / Lawrence, David S. et al. | 1983
- 7719
-
Studies on the synthesis of vitamin B-12. 3Stevens, Robert V. / Chang, Jun H. / Lapalme, Richard / Schow, Steven / Schlageter, Markus G. / Shapiro, Rafael / Weller, Harold N. et al. | 1983
- 7729
-
Electronic structure of ferricytochrome c and associated hyperfine interactionsMishra, K. C. / Mishra, Santosh K. / Das, T. P. et al. | 1983
- 7735
-
Antifungal peroxide-containing acids from two Caribbean spongesPhillipson, Douglas W. / Rinehart, Kenneth L. et al. | 1983
- 7737
-
Molecular and crystal structure of O4-methyluridine. Reaction coordinates for an incipient nucleophilic attack seen by short intermolecular sugar-base interactionsBrennan, Richard G. / Prive, Gilbert G. / Blonski, Wayne J. P. / Hruska, Frank E. / Sundaralingam, Muttaiya et al. | 1983
- 7742
-
An examination of relaxation reagents for conformational analysis of peptides in aqueous solutionKopple, Kenneth D. / Zhu, Peng Peng et al. | 1983
- 7747
-
Hydrogen oxide bridging ligands in a classical coordination compoundArdon, Michael / Bino, Avi et al. | 1983
- 7748
-
Sequence-specific double-strand cleavage of DNA by bis(EDTA-distamycin.iron(II)) and EDTA-bis(distamycin).iron(II)Schultz, P. G. / Dervan, P. B. et al. | 1983
- 7750
-
Syntheses and x-ray crystal structures of two new transition metal complexes having diphosphene ligands in novel bonding modesFlynn, Kathy M. / Hope, Hakon / Murray, Brendan D. / Olmstead, Marilyn M. / Power, Philip P. et al. | 1983
- 7751
-
Reactivity of diphosphenes and phosphaarsenes toward metal carbonylsCowley, A. H. / Kilduff, J. E. / Lasch, J. G. / Norman, N. C. / Pakulski, M. / Ando, F. / Wright, T. C. et al. | 1983
- 7752
-
Six-membered ring phosphites in twist conformations. The methyl and phenyl trans-3',5'-cyclic phosphites of thymidineNelson, Keith A. / Sopchik, Alan E. / Bentrude, Wesley G. et al. | 1983
- 7754
-
Chiral 1,4-dihydropyridine equivalents: a new approach to the asymmetric synthesis of alkaloids. The enantiospecific synthesis of (+)- and (-)-coniine and dihydropinidineGuerrier, Luc / Royer, Jacques / Grierson, David S. / Husson, Henri Philippe et al. | 1983
- 7755
-
Oxidation of organic compounds by zinc permanganateWolfe, Saul / Ingold, Christopher F. et al. | 1983
- 7757
-
Tungsten-catalyzed allylic alkylations. New avenues for selectivityTrost, Barry M. / Hung, Ming Hong et al. | 1983
- 7759
-
Cyclization of the N-butyl-5-methyl-1-hex-4-enaminyl radical and the use of N-lithio-N-butyl-5-methyl-1-hex-4-enamine as a mechanistic probe for electron-transfer processesNewcomb, Martin / Burchill, Michael T. et al. | 1983
- 7760
-
Decamethyl[5]pericyclyne. A novel homoconjugated cyclic polyacetyleneScott, L. T. / DeCicco, G. J. / Hyun, J. L. / Reinhardt, G. et al. | 1983
- 7761
-
Confirmation of the Mayo mechanism for the initiation of the thermal polymerization of styreneChong, Yen K. / Rizzardo, Ezio / Solomon, David H. et al. | 1983
- 7763
-
Experimental evidence for a high barrier to internal rotation in hexaisopropylbenzeneSiegel, Jay / Mislow, Kurt et al. | 1983
- 7764
-
Photochemical and chemical reduction of vicinal dibromides via phase transfer of 4,4'-bipyridinium radical: the role of radical disproportionationGoren, Zafrir / Willner, Itamar et al. | 1983
- 7765
-
Kinetics of long-distance ruthenium-to-copper electron transfer in [pentaammineruthenium histidine-83]azurinKostic, Nenad M. / Margalit, Ruth / Che, Chi Ming / Gray, Harry B. et al. | 1983
- 7767
-
Stereochemistry of oxidative addition of an optically active allyl acetate to a palladium(0) complexHayashi, Tamio / Hagihara, Toshiya / Konishi, Mitsuo / Kumada, Makoto et al. | 1983
- 7768
-
Low-temperature photochemistry of (.eta.5-C5R5)W(CO)3CH2SiMe2H: loss of carbon monoxide followed by .beta.-hydrogen transferLewis, Claudia / Wrighton, Mark S. et al. | 1983
- 7770
-
Mechanistic investigation of olefin insertion into the rhodium-hydrogen bondRoe, D. Christopher et al. | 1983
- 7771
-
A new model for the study of multistep electron transfer in photosynthesisNishitani, Shinji / Kurata, Nobuyuki / Sakata, Yoshiteru / Misumi, Soichi / Karen, Akiya / Okada, Tadashi / Mataga, Noboru et al. | 1983
- 7772
-
Stereoselectivity and kinetic control of hydrogen oxidative addition to iridium(I) complexesJohnson, Curtis E. / Fisher, Barbara J. / Eisenberg, Richard et al. | 1983
- 7774
-
Cleavage of carbon monoxide by mononuclear zirconium dialkyls: formation of a (.mu.-oxo)dialkyl and an enolatePlanalp, Roy P. / Andersen, Richard A. et al. | 1983
- 7775
-
Photoisomerization of trimesitylvinyl alcohol. Indirect evidence for the keto formHart, Harold / Giguere, Raymond J. et al. | 1983
- 7776
-
1,1,2,2-Tetrakis(2,6-dimethylphenyl)-1,2-disilacyclopropaneMasamune, Satoru / Murakami, Shu / Tobita, Hiromi / Williams, David J. et al. | 1983
- 7778
-
Crystal structure of 1,3,5-triphenyl-2,4,6-trithia-1,3,5-tristannaadamantaneBeauchamp, Andre L. / Latour, Stephan / Olivier, Marc J. / Wuest, James D. et al. | 1983
- 7780
-
Cooperativity in oxygen binding to Lingula reevii hemerythrin: spectroscopic comparison to the sipunculid hemerythrin coupled binuclear iron active siteRichardson, David E. / Reem, Richard C. / Solomon, Edward I. et al. | 1983
- 7781
-
Iron-histidine stretching Raman lines of the aa3-type cytochrome oxidasesOgura, Takashi / Honnami, Koyu / Oshima, Tairo / Yoshikawa, Shinya / Kitagawa, Teizo et al. | 1983
- 7783
-
Facile syntheses of bridge-oxygen-labeled pyrophosphates: The preparation of adenosine 5'-[.beta..gamma.-18O]triphosphateCullis, Paul M. et al. | 1983
- 7784
-
Soluble metal sulfides. Synthesis and structures of [M6S17]4- (M = niobium or tantalum): icosahedral-fragment cages containing four types of coordinated sulfideSola, Joan / Do, Youngkyu / Berg, Jeremy M. / Holm, R. H. et al. | 1983
- 7786
-
Photochemical Wolff rearrangement of a triplet ground state carbeneHayes, Richard A. / Hess, Thomas C. / McMahon, Robert J. / Chapman, Orville L. et al. | 1983
- 7787
-
Mechanism of Ziegler-Natta polymerization of acetylene: a nutation NMR studyClarke, T. C. / Yannoni, C. S. / Katz, T. J. et al. | 1983
- 7789
-
Tungsten vinylidenes and carbynes from terminal alkyne reagentsBirdwhistell, K. R. / Burgmayer, S. J. Nieter / Templeton, J. L. et al. | 1983
- 7790
-
Ortho lithiation of monosubstituted benzenes: a quantitative determination of pKa values in tetrahydrofuranFraser, Robert R. / Bresse, Monique / Mansour, Tarek S. et al. | 1983
- 7792
-
Pyridinium salts structurally related to NAD(P)+ as enolate transferring agentsMashraqui, Sabir H. / Kellogg, Richard M. et al. | 1983
- 7793
-
Book Reviews| 1983
- 7793
-
Additions and Corrections - Selectivities of π -and σ-Succinimidyl Radicals in Substitution and Addition Reactions. Appendix: Response to Walling, El-Taliawi, and Zhao.Skell, P. / Tlumak, R. / Seshadri, S. et al. | 1983
-
Masthead| 1983