Sm[I.sub.2]-mediated radical coupling strategy to securinega alkaloids: total synthesis of -14,15-dihydrosecurinine and formal total synthesis of -securinine (English)
- New search for: Xiao Zheng
- New search for: Xiao Zheng
- New search for: Juan Liu
- New search for: Chen-Xi Ye
- New search for: Ao Wang
- New search for: Ai-E Wang
- New search for: Pei-Qiang Huang
In:
The journal of organic chemistry
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80
, 2
; 1034
;
2015
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ISSN:
- Article (Journal) / Print
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Title:Sm[I.sub.2]-mediated radical coupling strategy to securinega alkaloids: total synthesis of -14,15-dihydrosecurinine and formal total synthesis of -securinine
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Contributors:
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Published in:The journal of organic chemistry ; 80, 2 ; 1034
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Publisher:
- New search for: Soc.
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Place of publication:Washington, DC [u.a.]
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Publication date:2015
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ISSN:
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ZDBID:
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Type of media:Article (Journal)
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Type of material:Print
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Language:English
- New search for: 35.00 / 35.50
- Further information on Basic classification
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Source:
Table of contents – Volume 80, Issue 2
The tables of contents are generated automatically and are based on the data records of the individual contributions available in the index of the TIB portal. The display of the Tables of Contents may therefore be incomplete.
- 705
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Synthetic Access to the Chemical Diversity of DNA and RNA 5′‑Aldehyde LesionsLartia, Rémy / Constant, Jean-François et al. | 2015
- 711
-
Spirodi(iminohydantoin) Products from Oxidation of 2′-Deoxyguanosine in the Presence of NH4Cl in Nucleoside and Oligodeoxynucleotide ContextsFleming, Aaron M. / Armentrout, Erin I. / Zhu, Judy / Muller, James G. / Burrows, Cynthia J. et al. | 2015
- 722
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Synthesis of Fluorenes via Tandem Copper-Catalyzed [3 + 2] Cycloaddition and Rhodium-Catalyzed Denitrogenative Cyclization in a 5-Exo Mode from 2‑Ethynylbiaryls and N‑Sulfonyl Azides in One PotSeo, Boram / Jeon, Woo Hyung / Kim, Jaeeun / Kim, Sunghwa / Lee, Phil Ho et al. | 2015
- 733
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Preparation and Self-Assembly Study of Amphiphilic and Bispolar Diacetylene-Containing GlycolipidsWang, Guijun / Goyal, Navneet / Mangunuru, Hari P. R. / Yang, Hao / Cheuk, Sherwin / Reddy, Puram V. Narasimha et al. | 2015
- 744
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Computational Analysis of the Stereochemical Outcome in the Imidazolidinone-Catalyzed Enantioselective (4 + 3)-Cycloaddition ReactionKrenske, Elizabeth H. / Houk, K. N. / Harmata, Michael et al. | 2015
- 751
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Synthesis of Fused 1‑Aminoindole Polycycles by a Sequence of Palladium-Catalyzed N–H and C(sp2)–H ArylationsLuong, Thi Thanh Huyen / Brion, Jean-Daniel / Alami, Mouad / Messaoudi, Samir et al. | 2015
- 762
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Stereoselective Formation of Quaternary Stereogenic Centers via Alkylation of α‑Substituted Malonate-ImidazolidinonesBixa, Thobela / Hunter, Roger / Andrijevic, Ana / Petersen, Wade / Su, Hong / Dhoro, Francis et al. | 2015
- 770
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Application of 2‑Substituted Benzyl Groups in Stereoselective GlycosylationBuda, Szymon / Nawój, Mirosław / Gołębiowska, Patrycja / Dyduch, Karol / Michalak, Artur / Mlynarski, Jacek et al. | 2015
- 781
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Electrochemically Induced Ring-Opening/Friedel–Crafts Arylation of Chalcone Epoxides Catalyzed by a Triarylimidazole Redox MediatorLu, Nan-ning / Zhang, Ni-tao / Zeng, Cheng-Chu / Hu, Li-Ming / Yoo, Seung Joon / Little, R. Daniel et al. | 2015
- 790
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Synthesis of Benzofused Five-Ring Sultams via Rh-Catalyzed C–H Olefination Directed by an N‑Ac-Substituted Sulfonamide GroupLi, Xueyuan / Dong, Yi / Qu, Fengyu / Liu, Gang et al. | 2015
- 799
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2D Ultrafast HMBC 1H,31P: Obtaining Mechanistic Details on the Michaelis–Arbuzov ReactionFernández-Valle, María Encarnación / Martínez-Álvarez, Roberto / Molero-Vílchez, Dolores / Pardo, Zulay D. / Sáez-Barajas, Elena / Herrera, Antonio et al. | 2015
- 799
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2D ultrafast HMBC [.sup.1H],[.sup.31P]: Obtaining mechanistic details on the Michaelis-Arbuzov reactionFernandez-Valle, Maria Encarnacion et al. | 2015
- 806
-
Organocatalyzed Asymmetric Aldol Reactions of Ketones and β,γ‑Unsaturated α‑Ketoesters and Phenylglyoxal HydratesKonda, Swapna / Guo, Qun-Sheng / Abe, Manabu / Huang, Huicai / Arman, Hadi / Zhao, John C.-G. et al. | 2015
- 816
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Asymmetric Synthesis of gem-Difluoromethylenated Linear Triquinanes via Cascade gem-Difluoroalkyl Radical CyclizationThaharn, Watcharaporn / Soorukram, Darunee / Kuhakarn, Chutima / Tuchinda, Patoomratana / Pakawatchai, Chaveng / Saithong, Saowanit / Reutrakul, Vichai / Pohmakotr, Manat et al. | 2015
- 828
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Modularly Evolved 2‑AminoDMAP/Squaramides as Highly Active Bifunctional Organocatalysts in Michael AdditionIşık, Murat / Unver, M. Yagiz / Tanyeli, Cihangir et al. | 2015
- 836
-
Systemic study on the biogenic pathways of yezo'otogirins: total synthesis and antitumor activities of ([+ or -])-yezo'otogirin C and its structural analoguesWei Yang et al. | 2015
- 836
-
Systemic Study on the Biogenic Pathways of Yezo’otogirins: Total Synthesis and Antitumor Activities of (±)-Yezo’otogirin C and Its Structural AnaloguesYang, Wei / Cao, Jingming / Zhang, Mengxun / Lan, Rongfeng / Zhu, Lizhi / Du, Guangyan / He, Shuzhong / Lee, Chi-Sing et al. | 2015
- 847
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Selective Transfer Semihydrogenation of Alkynes with Nanoporous Gold CatalystsWagh, Yogesh S. / Asao, Naoki et al. | 2015
- 852
-
Photogenerated α,n‑Didehydrotoluenes from Chlorophenylacetic Acids at Physiological pHRavelli, Davide / Protti, Stefano / Fagnoni, Maurizio et al. | 2015
- 859
-
Stereoselective Synthesis of the C1–C29 Part of Amphidinol 3Tsuruda, Takeshi / Ebine, Makoto / Umeda, Aya / Oishi, Tohru et al. | 2015
- 872
-
Multiple transformations of 2-alkynyl-1,8-bisnaphthalenes into benzo[g]indoles. Pd/Cu-dependent switching of the electrophilic and nucleophilic sites in acetylenic bond and a puzzle of porcelain catalysisFilatova, Ekaterina A et al. | 2015
- 872
-
Multiple Transformations of 2‑Alkynyl-1,8-bis(dimethylamino)naphthalenes into Benzo[g]indoles. Pd/Cu-Dependent Switching of the Electrophilic and Nucleophilic Sites in Acetylenic Bond and a Puzzle of Porcelain CatalysisFilatova, Ekaterina A. / Pozharskii, Alexander F. / Gulevskaya, Anna V. / Ozeryanskii, Valery A. et al. | 2015
- 882
-
Synthesis and Optoelectronic Properties of Janus-Dendrimer-Type Multivalent Donor–Acceptor SystemsDengiz, Cagatay / Breiten, Benjamin / Gisselbrecht, Jean-Paul / Boudon, Corinne / Trapp, Nils / Schweizer, W. Bernd / Diederich, François et al. | 2015
- 897
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Symmetric Diarylsulfoxides as Asymmetric Sulfinylating Reagents for Dialkylmagnesium CompoundsRuppenthal, Simon / Brückner, Reinhard et al. | 2015
- 911
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Silver-Catalyzed C(sp2)–H Functionalization/C–O Cyclization Reaction at Room TemperatureDai, Jian-Jun / Xu, Wen-Tao / Wu, Ya-Dong / Zhang, Wen-Man / Gong, Ying / He, Xia-Ping / Zhang, Xin-Qing / Xu, Hua-Jian et al. | 2015
- 920
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Unsaturated syn- and anti-1,2-Amino Alcohols by Cyclization of Allylic Bis-trichloroacetimidates. Stereoselectivity Dependence on Substrate ConfigurationGrigorjeva, Liene / Kinens, Artis / Jirgensons, Aigars et al. | 2015
- 928
-
“Transition-Metal-Free” Synthesis of Carbazoles by Photostimulated Reactions of 2′-Halo[1,1′-biphenyl]-2-aminesGuerra, Walter D. / Rossi, Roberto A. / Pierini, Adriana B. / Barolo, Silvia M. et al. | 2015
- 942
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Palladium-Catalyzed ortho-Selective C–H Fluorination of Oxalyl Amide-Protected BenzylaminesChen, Changpeng / Wang, Chao / Zhang, Jingyu / Zhao, Yingsheng et al. | 2015
- 950
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Biocatalytic Route to Chiral Acyloins: P450-Catalyzed Regio- and Enantioselective α‑Hydroxylation of KetonesAgudo, Rubén / Roiban, Gheorghe-Doru / Lonsdale, Richard / Ilie, Adriana / Reetz, Manfred T. et al. | 2015
- 957
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Development of a Brønsted Acid-Promoted Arene–Ynamide Cyclization toward the Total Syntheses of Marinoquinolines A and C and Aplidiopsamine AYamaoka, Yousuke / Yoshida, Takahiro / Shinozaki, Makiko / Yamada, Ken-ichi / Takasu, Kiyosei et al. | 2015
- 965
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Strategies to Control Alkoxy Radical-Initiated Relay Cyclizations for the Synthesis of Oxygenated Tetrahydrofuran MotifsZhu, Hai / Leung, Joe C. T. / Sammis, Glenn M. et al. | 2015
- 980
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C–H Arylation of Unsubstituted Furan and Thiophene with Acceptor Bromides: Access to Donor–Acceptor–Donor-Type Building Blocks for Organic ElectronicsMatsidik, Rukiya / Martin, Johannes / Schmidt, Simon / Obermayer, Johannes / Lombeck, Florian / Nübling, Fritz / Komber, Hartmut / Fazzi, Daniele / Sommer, Michael et al. | 2015
- 988
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Reversible Photocapture of a [2]Rotaxane Harnessing a Barbiturate TemplateTron, Arnaud / Thornton, Peter J. / Lincheneau, Christophe / Desvergne, Jean-Pierre / Spencer, Neil / Tucker, James H. R. / McClenaghan, Nathan D. et al. | 2015
- 997
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Hydrocarbon binding by proteins: structures of protein binding sites for greater than equal to [C.sub.10] linear alkanes or long-chain alkyl and alkenyl groupsPark, Jiyong et al. | 2015
- 997
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Hydrocarbon Binding by Proteins: Structures of Protein Binding Sites for ≥C10 Linear Alkanes or Long-Chain Alkyl and Alkenyl GroupsPark, Jiyong / Pham, Hung V. / Mogensen, Kristian / Solling, Theis Ivan / Vad Bennetzen, Martin / Houk, K. N. et al. | 2015
- 1006
-
A Procedure for Transforming Indoles into IndolequinonesEastabrook, Andrew S. / Wang, Christy / Davison, Emma K. / Sperry, Jonathan et al. | 2015
- 1018
-
Synthesis of 2‑Amino-1,3,4-oxadiazoles and 2‑Amino-1,3,4-thiadiazoles via Sequential Condensation and I2‑Mediated Oxidative C–O/C–S Bond FormationNiu, Pengfei / Kang, Jinfeng / Tian, Xianhai / Song, Lina / Liu, Hongxu / Wu, Jie / Yu, Wenquan / Chang, Junbiao et al. | 2015
- 1018
-
Synthesis of 2-amino-1,3,4-oxadiazoles and 2-amino-1,3,4-thiadiazoles via sequential condensation and [I.sub.2]-mediated oxidative C-O/C-S bond formationPengfei Niu et al. | 2015
- 1025
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Multicomponent Strategy to Indeno[2,1‑c]pyridine and Hydroisoquinoline Derivatives through Cleavage of Carbon–Carbon BondFeng, Xian / Wang, Jian-Jun / Xun, Zhan / Huang, Zhi-Bin / Shi, Da-Qing et al. | 2015
- 1034
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SmI2‑Mediated Radical Coupling Strategy to Securinega Alkaloids: Total Synthesis of (−)-14,15-Dihydrosecurinine and Formal Total Synthesis of (−)-SecurinineZheng, Xiao / Liu, Juan / Ye, Chen-Xi / Wang, Ao / Wang, Ai-E / Huang, Pei-Qiang et al. | 2015
- 1034
-
Sm[I.sub.2]-mediated radical coupling strategy to securinega alkaloids: total synthesis of -14,15-dihydrosecurinine and formal total synthesis of -securinineXiao Zheng et al. | 2015
- 1042
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Torquoselectivity in the Nazarov Reactions of Allenyl Vinyl KetonesMorgan, Timothy D. R. / LeBlanc, Luc M. / Ardagh, Giselle H. / Boyd, Russell J. / Burnell, D. Jean et al. | 2015
- 1052
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Metal-Promoted Intermolecular Electron Transfer in Tetrathiafulvalene–Thiacalix[4]arene Conjugates and TetrachlorobenzoquinoneZhao, Bang-Tun / Peng, Qi-Ming / Zhu, Xiao-Min / Yan, Zhen-Ning / Zhu, Wei-Min et al. | 2015
- 1059
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Synthesis of ortho-Haloaminoarenes by Aryne Insertion of Nitrogen–Halide BondsHendrick, Charles E. / Wang, Qiu et al. | 2015
- 1070
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1,3-Diiodocalix[4]arene: Synthesis by Ullmann-Type Iodination of 1,3-Bistriflate Ester of Calix[4]arene, Conformational Analysis, and Transformation into 1,3-Dicarboxy‑, Diformyl‑, and Dialkylcalix[4]arenesTanaka, Shinya / Umetsu, Takafumi / Nebuya, Satoru / Morohashi, Naoya / Hattori, Tetsutaro et al. | 2015
- 1082
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Phosphonate–Phosphinate RearrangementQian, Renzhe / Roller, Alexander / Hammerschmidt, Friedrich et al. | 2015
- 1092
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A Stable N‑Heterocyclic Carbene Organocatalyst for Hydrogen/Deuterium Exchange Reactions between Pseudoacids and Deuterated ChloroformPerez, Fabien / Ren, Yajun / Boddaert, Thomas / Rodriguez, Jean / Coquerel, Yoann et al. | 2015
- 1098
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Nonafluorobutanesulfonyl Azide as a Shelf-Stable Highly Reactive Oxidant for the Copper-Catalyzed Synthesis of 1,3-Diynes from Terminal AlkynesSuárez, José Ramón / Collado-Sanz, Daniel / Cárdenas, Diego J. / Chiara, Jose Luis et al. | 2015
- 1107
-
Intramolecular Etherification and Polyene Cyclization of π‑Activated Alcohols Promoted by Hot WaterZhang, Feng-Zhi / Tian, Yan / Li, Guo-Xing / Qu, Jin et al. | 2015
- 1116
-
Construction of the Myrioneuron Alkaloids: A Total Synthesis of (±)-MyrioneurinolNocket, Anthony J. / Feng, Yiqing / Weinreb, Steven M. et al. | 2015
- 1130
-
Power of a Remote Hydrogen Bond Donor: Anion Recognition and Structural Consequences Revealed by IR SpectroscopySamet, Masoud / Danesh-Yazdi, Mohammad / Fattahi, Alireza / Kass, Steven R. et al. | 2015
- 1136
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Exploitation of in Situ Generated Sugar-Based Olefin Keto-Nitrones: Synthesis of Carbocycles, Heterocycles, and Nucleoside DerivativesDas, Soumendra Nath / Chowdhury, Arpan / Tripathi, Neha / Jana, Prithwish K. / Mandal, Sukhendu B et al. | 2015
- 1149
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Kinetic Solvent Effects on the Reactions of the Cumyloxyl Radical with Tertiary Amides. Control over the Hydrogen Atom Transfer Reactivity and Selectivity through Solvent Polarity and Hydrogen BondingSalamone, Michela / Mangiacapra, Livia / Bietti, Massimo et al. | 2015
- 1155
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C–H Bond Functionalization via [1,5]-Hydride Shift/Cyclization Sequence: Approach to SpiroindoleninesWang, Peng-Fei / Jiang, Chun-Huan / Wen, Xiaoan / Xu, Qing-Long / Sun, Hongbin et al. | 2015
- 1163
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Stereoconvergent [1,2]- and [1,4]-Wittig Rearrangements of 2‑Silyl-6-aryl-5,6-dihydropyrans: A Tale of Steric vs Electronic Regiocontrol of Divergent PathwaysMori-Quiroz, Luis M. / Maleczka, Robert E. et al. | 2015
- 1192
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Nickel-Catalyzed One-Pot Tandem 1,4-1,2-Addition of P(O)H Compounds to 1,10-PhenanthrolinesGao, Yuxing / Deng, Honggui / Zhang, Shanshan / Xue, Wanhua / Wu, Yile / Qiao, Hongwei / Xu, Pengxiang / Zhao, Yufen et al. | 2015
- 1192
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Nickel-catalyzed one-pot tandem 1,4-1,2-addition of PH compounds to 1,10-phenanthrolinesYuxing Gao et al. | 2015
- 1200
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Synthesis of Chromeno[2,3‑b]indol-11(6H)‑one via PhI(OAc)2‑Mediated Intramolecular Oxidative C(sp2)–N(H2) Bond FormationSun, Jiyun / Zhang-Negrerie, Daisy / Du, Yunfei / Zhao, Kang et al. | 2015
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Synthesis of Oxaspiranic Compounds through [3 + 2] Annulation of Cyclopropenones and Donor–Acceptor CyclopropanesRivero, Alexandra R. / Fernández, Israel / Ramírez de Arellano, Carmen / Sierra, Miguel A. et al. | 2015
- 1214
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Direct Radical Acetoxyphosphorylation of Styrenes Mediated by Manganese(III)Zhou, Shao-Fang / Li, Da-Peng / Liu, Kui / Zou, Jian-Ping / Asekun, Olayinka Taiwo et al. | 2015
- 1221
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Cholate-Based Synthesis of Size-Tunable Cage CompoundsPeng, Lingling / Mo, Fanyang / Zhang, Qinghai et al. | 2015
- 1229
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Chromatography-Free Entry to Substituted Salicylonitriles: Mitsunobu-Triggered Domino Reactions of SalicylaldoximesWhiting, Ellis / Lanning, Maryanna E. / Scheenstra, Jacob A. / Fletcher, Steven et al. | 2015
- 1235
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Synthesis of Polysubstituted Pyrroles via Pd-Catalyzed Oxidative Alkene C–H Bond Arylation and AminationZheng, Jia / Huang, Liangbin / Huang, Chuyu / Wu, Wanqing / Jiang, Huanfeng et al. | 2015
- 1243
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Establishment of Relative and Absolute Configurations of Phaeosphaeride A: Total Synthesis of ent-Phaeosphaeride AKobayashi, Kenichi / Kobayashi, Yukiko / Nakamura, Misato / Tamura, Osamu / Kogen, Hiroshi et al. | 2015
- 1249
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Cu-Catalyzed Aerobic Oxidative Cyclization of Guanidylpyridines and DerivativesBartels, Björn / Bolas, Conor Gordon / Cueni, Philipp / Fantasia, Serena / Gaeng, Nicolas / Trita, Andrada Stefania et al. | 2015
- 1258
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Palladium-Catalyzed Oxidative Carbonylation of Aromatic C–H Bonds of N‑Alkylanilines with CO and Alcohols for the Synthesis of o‑AminobenzoatesChen, Ming / Ren, Zhi-Hui / Wang, Yao-Yu / Guan, Zheng-Hui et al. | 2015
- 1264
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Chloro, Difluoromethylation and Chloro, Carbomethoxydifluoromethylation: Reaction of Radicals Derived from RfSO2Cl with Unactivated Alkenes under Metal-Free ConditionsThomoson, Charles S. / Tang, Xiao-Jun / Dolbier, William R. et al. | 2015
- 1269
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Palladium-Catalyzed ortho-Sulfonylation of 2‑Aryloxypyridines and Subsequent Formation of ortho-Sulfonylated PhenolsXu, Yinfeng / Liu, Ping / Li, Shun-Li / Sun, Peipei et al. | 2015
- 1275
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Copper-Catalyzed Synthesis of Substituted Quinolines via C–N Coupling/Condensation from ortho-Acylanilines and Alkenyl IodidesKong, Lingkai / Zhou, Yuanyuan / Huang, He / Yang, Yang / Liu, Yuanyuan / Li, Yanzhong et al. | 2015
- 1279
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Metal-Catalyzed Thermal Reactions of Cyclic β‑Dicarbonyl Phenyliodonium Ylide with StyrenesBosnidou, Alexandra-Eleni / Kalpogiannaki, Dimitra / Karanestora, Sofia / Nixas, John A. / Hadjiarapoglou, Lazaros P. et al. | 2015
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Syntheses and Cytotoxicity of (R)- and (S)‑7-MethoxycryptopleurineAnton-Torrecillas, Cintia / Bosque, Irene / Gonzalez-Gomez, Jose C. / Loza, María Isabel / Brea, José et al. | 2015
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Synthesis of chromeno[2,3-b]indol-11-one via {PhI[.sub.2]}-mediated intramolecular oxidative C bond formationJiyun Sun et al. | 2015