A Tale of Two Elements: The Lewis Acidity/Basicity Umpolung of Boron and Phosphorus (English)
- New search for: Stephan, Douglas W.
- New search for: Stephan, Douglas W.
In:
Angewandte Chemie International Edition
;
56
, 22
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5984-5992
;
2017
- Article (Journal) / Electronic Resource
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Title:A Tale of Two Elements: The Lewis Acidity/Basicity Umpolung of Boron and Phosphorus
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Contributors:Stephan, Douglas W. ( author )
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Published in:Angewandte Chemie International Edition ; 56, 22 ; 5984-5992
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Publisher:
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Publication date:2017-05-22
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Size:9 pages
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ISSN:
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DOI:
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Type of media:Article (Journal)
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Type of material:Electronic Resource
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Language:English
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Keywords:
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Source:
Table of contents – Volume 56, Issue 22
The tables of contents are generated automatically and are based on the data records of the individual contributions available in the index of the TIB portal. The display of the Tables of Contents may therefore be incomplete.
- 5945
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Cover Picture: Manganese Silylene Hydride Complexes: Synthesis and Reactivity with Ethylene to Afford Silene Hydride Complexes (Angew. Chem. Int. Ed. 22/2017)Price, Jeffrey S. / Emslie, David J. H. / Britten, James F. et al. | 2017
- 5946
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Inside Cover: Helically Coiled Graphene Nanoribbons (Angew. Chem. Int. Ed. 22/2017)Daigle, Maxime / Miao, Dandan / Lucotti, Andrea / Tommasini, Matteo / Morin, Jean‐François et al. | 2017
- 5948
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Guest Editorial: Celebrating Canadian ChemistryStephan, Douglas W. / Lautens, Mark et al. | 2017
- 5951
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Graphical Abstract: Angew. Chem. Int. Ed. 22/2017| 2017
- 5970
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Spotlights on our sister journals: Angew. Chem. Int. Ed. 22/2017| 2017
- 5974
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Rik R. Tykwinski| 2017
- 5975
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Chemical Institute of Canada and Canadian Society for Chemistry Awards| 2017
- 5980
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Cura Annonae—Chemically Boosting Crop Yields Through Metabolic Feeding of a Plant Signaling PrecursorVocadlo, David J. et al. | 2017
- 5984
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A Tale of Two Elements: The Lewis Acidity/Basicity Umpolung of Boron and PhosphorusStephan, Douglas W. et al. | 2017
- 5994
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The Stability Challenges of Oxygen Evolving Catalysts: Towards a Common Fundamental Understanding and Mitigation of Catalyst DegradationSpöri, Camillo / Kwan, Jason Tai Hong / Bonakdarpour, Arman / Wilkinson, David P. / Strasser, Peter et al. | 2017
- 6022
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Applications of the Wittig–Still Rearrangement in Organic SynthesisRycek, Lukas / Hudlicky, Tomas et al. | 2017
- 6068
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High‐Throughput Synthesis of Mixed‐Metal Electrocatalysts for CO2 ReductionHe, Jingfu / Dettelbach, Kevan E. / Salvatore, Danielle A. / Li, Tengfei / Berlinguette, Curtis P. et al. | 2017
- 6073
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Instantaneous Functionalization of Chemically Etched Silicon Nanocrystal SurfacesMobarok, Md Hosnay / Purkait, Tapas K. / Islam, Muhammad Amirul / Miskolzie, Mark / Veinot, Jonathan G. C. et al. | 2017
- 6078
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Development and Cycloaddition Reactivity of a New Class of Pyridine‐Based Mesoionic 1,3‐DipoleErguven, Huseyin / Leitch, David C. / Keyzer, Evan N. / Arndtsen, Bruce A. et al. | 2017
- 6083
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Supramolecular Nanofibrillar Thermoreversible Hydrogel for Growth and Release of Cancer SpheroidsLi, Yunfeng / Khuu, Nancy / Gevorkian, Albert / Sarjinsky, Sharon / Therien‐Aubin, Heloise / Wang, Yihe / Cho, Sangho / Kumacheva, Eugenia et al. | 2017
- 6088
-
Ultrafast Independent N−H and N−C Bond Deformation Investigated with Resonant Inelastic X‐Ray ScatteringEckert, Sebastian / Norell, Jesper / Miedema, Piter S. / Beye, Martin / Fondell, Mattis / Quevedo, Wilson / Kennedy, Brian / Hantschmann, Markus / Pietzsch, Annette / Van Kuiken, Benjamin E. et al. | 2017
- 6093
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Regioselective Photoisomerization/C−C Bond Formation of Asymmetric B(ppy)(Mes)(Ar): The Role of the Aryl Groups on BoronMellerup, Soren K. / Li, Cally / Peng, Tai / Wang, Suning et al. | 2017
- 6098
-
DNA Films Containing the Artificial Nucleobase Imidazole Mediate Charge Transfer in a Silver(I)‐Responsive WayLéon, J. Christian / She, Zhe / Kamal, Ajar / Shamsi, Mohtashim Hassan / Müller, Jens / Kraatz, Heinz‐Bernhard et al. | 2017
- 6103
-
Catalytic Reductive Synthesis and Direct Derivatization of Unprotected Aminoindoles, Aminopyrroles, and IminoindolinesLeijendekker, Leonardus H. / Weweler, Jens / Leuther, Tobias M. / Streuff, Jan et al. | 2017
- 6107
-
From Bidentate Gallium Lewis Acids to Supramolecular ComplexesHorstmann, Jan / Hyseni, Mentor / Mix, Andreas / Neumann, Beate / Stammler, Hans‐Georg / Mitzel, Norbert W. et al. | 2017
- 6112
-
Ultrasensitive Fluorogenic Reagents for Neuraminidase TitrationGao, Zhizeng / Niikura, Masahiro / Withers, Stephen G. et al. | 2017
- 6117
-
Single‐Molecule Force Spectroscopy Trajectories of a Single Protein and Its Polyproteins Are Equivalent: A Direct Experimental Validation Based on A Small Protein NuG2Lei, Hai / He, Chengzhi / Hu, Chunguang / Li, Jinliang / Hu, Xiaodong / Hu, Xiaotang / Li, Hongbin et al. | 2017
- 6122
-
Separating Dipolar and Chemical Exchange Magnetization Transfer Processes in 1H‐CESTYuwen, Tairan / Sekhar, Ashok / Kay, Lewis E. et al. | 2017
- 6126
-
An Optical Actuator Based on Gold‐Nanoparticle‐Containing Temperature‐Memory Semicrystalline PolymersGe, Feijie / Lu, Xili / Xiang, Jun / Tong, Xia / Zhao, Yue et al. | 2017
- 6131
-
Characterization of Plasma Membrane Ceramides by Super‐Resolution MicroscopyBurgert, Anne / Schlegel, Jan / Bécam, Jérôme / Doose, Sören / Bieberich, Erhard / Schubert‐Unkmeir, Alexandra / Sauer, Markus et al. | 2017
- 6136
-
Optical Distinction between “Slow” and “Fast” Translational Motion in Degenerate Molecular ShuttlesVukotic, V. Nicholas / Zhu, Kelong / Baggi, Giorgio / Loeb, Stephen J. et al. | 2017
- 6142
-
A DNAzyme Feedback Amplification Strategy for BiosensingLiu, Meng / Zhang, Qiang / Chang, Dingran / Gu, Jimmy / Brennan, John D. / Li, Yingfu et al. | 2017
- 6147
-
Anisotropic Polymer Nanoparticles with Tunable Emission Wavelengths by Intersegmental Chain PackingRuiz Perez, Julian D. / Mecking, Stefan et al. | 2017
- 6152
-
Patchy Nanofibers from the Thin Film Self‐Assembly of a Conjugated Diblock CopolymerKynaston, Emily L. / Fang, Yuan / Manion, Joseph G. / Obhi, Nimrat K. / Howe, Jane Y. / Perepichka, Dmitrii F. / Seferos, Dwight S. et al. | 2017
- 6157
-
Transition‐Metal‐Doped NIR‐Emitting Silicon NanocrystalsChandra, Sourov / Masuda, Yoshitake / Shirahata, Naoto / Winnik, Françoise M. et al. | 2017
- 6161
-
A Method for the Late‐Stage Formation of Ketones, Acyloins, and Aldols from Alkenylstannanes: Application to the Total Synthesis of Paecilonic Acid ASommer, Heiko / Hamilton, James Y. / Fürstner, Alois et al. | 2017
- 6166
-
Solid‐State 17O NMR Reveals Hydrogen‐Bonding Energetics: Not All Low‐Barrier Hydrogen Bonds Are StrongLu, Jiasheng / Hung, Ivan / Brinkmann, Andreas / Gan, Zhehong / Kong, Xianqi / Wu, Gang et al. | 2017
- 6171
-
Managing Hydrogen Bonding in Clathrate Hydrates by Crystal EngineeringShin, Kyuchul / Moudrakovski, Igor L. / Ratcliffe, Christopher I. / Ripmeester, John A. et al. | 2017
- 6176
-
Strings of Porous Carbon Polyhedrons as Self‐Standing Cathode Host for High‐Energy‐Density Lithium–Sulfur BatteriesLiu, Yazhi / Li, Gaoran / Fu, Jing / Chen, Zhongwei / Peng, Xinsheng et al. | 2017
- 6181
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Small‐Molecule Inhibition of the UNC119–Cargo InteractionMejuch, Tom / Garivet, Guillaume / Hofer, Walter / Kaiser, Nadine / Fansa, Eyad K. / Ehrt, Christiane / Koch, Oliver / Baumann, Matthias / Ziegler, Slava / Wittinghofer, Alfred et al. | 2017
- 6187
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Piezochromic Carbon Dots with Two‐photon FluorescenceLu, Siyu / Xiao, Guanjun / Sui, Laizhi / Feng, Tanglue / Yong, Xue / Zhu, Shoujun / Li, Baojun / Liu, Zhongyi / Zou, Bo / Jin, Mingxing et al. | 2017
- 6192
-
Inhibiting Polysulfide Shuttle in Lithium–Sulfur Batteries through Low‐Ion‐Pairing Salts and a Triflamide SolventShyamsunder, Abhinandan / Beichel, Witali / Klose, Petra / Pang, Quan / Scherer, Harald / Hoffmann, Anke / Murphy, Graham K. / Krossing, Ingo / Nazar, Linda F. et al. | 2017
- 6198
-
Water‐Soluble N‐Heterocyclic Carbene‐Protected Gold Nanoparticles: Size‐Controlled Synthesis, Stability, and Optical PropertiesSalorinne, Kirsi / Man, Renee W. Y. / Li, Chien‐Hung / Taki, Masayasu / Nambo, Masakazu / Crudden, Cathleen M. et al. | 2017
- 6203
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Palladium‐Catalyzed Carbonylation of sec‐ and tert‐AlcoholsDong, Kaiwu / Sang, Rui / Liu, Jie / Razzaq, Rauf / Franke, Robert / Jackstell, Ralf / Beller, Matthias et al. | 2017
- 6208
-
Poly‐cytosine DNA as a High‐Affinity Ligand for Inorganic NanomaterialsLu, Chang / Huang, Zhicheng / Liu, Biwu / Liu, Yibo / Ying, Yibin / Liu, Juewen et al. | 2017
- 6213
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Helically Coiled Graphene NanoribbonsDaigle, Maxime / Miao, Dandan / Lucotti, Andrea / Tommasini, Matteo / Morin, Jean‐François et al. | 2017
- 6218
-
Isolation of Azadiphosphiridines and Diphosphenimines by Cycloaddition of Azides and a Cationic DiphospheneSchwedtmann, Kai / Hennersdorf, Felix / Bauzá, Antonio / Frontera, Antonio / Fischer, Roland / Weigand, Jan J. et al. | 2017
- 6223
-
Manganese Silylene Hydride Complexes: Synthesis and Reactivity with Ethylene to Afford Silene Hydride ComplexesPrice, Jeffrey S. / Emslie, David J. H. / Britten, James F. et al. | 2017
- 6228
-
Rethinking the Claisen–Tishchenko ReactionMorris, Stacey A. / Gusev, Dmitry G. et al. | 2017
- 6232
-
The Reactivity of Benzyl Lithium Species is Regulated by Intermediate StructuresKroesen, Ulrike / Knauer, Lena / Strohmann, Carsten et al. | 2017
- 6236
-
Trapping Rare and Elusive Phosphinidene ChalcogenidesGraham, Cameron M. E. / Pritchard, Taylor E. / Boyle, Paul D. / Valjus, Juuso / Tuononen, Heikki M. / Ragogna, Paul J. et al. | 2017
- 6241
-
N‐Heterocyclic Carbene Catalyzed [4+2] Annulation of Enals via a Double Vinylogous Michael Addition: Asymmetric Synthesis of 3,5‐Diaryl CyclohexenonesChen, Xiang‐Yu / Liu, Qiang / Chauhan, Pankaj / Li, Sun / Peuronen, Anssi / Rissanen, Kari / Jafari, Ehsan / Enders, Dieter et al. | 2017
- 6246
-
Synthesis of Air‐Stable Cyclopentadienyl Fe(CO)2 (Fp) Polymers by a Host–Guest Interaction of Cyclodextrin with Air‐Sensitive Fp Pendant GroupsZhou, Na / Peng, Liao / Salgado, Shehan / Yuan, Jinying / Wang, Xiaosong et al. | 2017
- 6251
-
Coordination of KrF2 to a Naked Metal Cation, Mg2+Lozinšek, Matic / Mercier, Hélène P. A. / Brock, David S. / Žemva, Boris / Schrobilgen, Gary J. et al. | 2017
- 6255
-
On the Reactions of Thiols, Sulfenic Acids, and Sulfinic Acids with Hydrogen PeroxideChauvin, Jean‐Philippe R. / Pratt, Derek A. et al. | 2017
- 6260
-
Umpolung Addition of Aldehydes to Aryl IminesChen, Ning / Dai, Xi‐Jie / Wang, Haining / Li, Chao‐Jun et al. | 2017
- 6264
-
Oxalyl Boronates Enable Modular Synthesis of Bioactive ImidazolesLee, C. Frank / Holownia, Aleksandra / Bennett, James M. / Elkins, Jonathan M. / St. Denis, Jeffrey D. / Adachi, Shinya / Yudin, Andrei K. et al. | 2017
- 6268
-
Diazaphospholene Precatalysts for Imine and Conjugate ReductionsAdams, Matt R. / Tien, Chieh‐Hung / Huchenski, Blake S. N. / Ferguson, Michael J. / Speed, Alexander W. H. et al. | 2017
- 6272
-
Using N‐Heterocyclic Vinyl Ligands to Access Stable Divinylgermylenes and a Germylium CationHering‐Junghans, Christian / Andreiuk, Patricia / Ferguson, Michael J. / McDonald, Robert / Rivard, Eric et al. | 2017
- 6276
-
NHC‐Organocatalyzed CAr−O Bond Cleavage: Mild Access to 2‐HydroxybenzophenonesJanssen‐Müller, Daniel / Singha, Santanu / Lied, Fabian / Gottschalk, Karin / Glorius, Frank et al. | 2017
- 6280
-
A 11‐Steps Total Synthesis of Magellanine through a Gold(I)‐Catalyzed Dehydro Diels–Alder ReactionMcGee, Philippe / Bétournay, Geneviève / Barabé, Francis / Barriault, Louis et al. | 2017
- 6284
-
Diversity‐Oriented Synthesis of Cyclic Azapeptides by A3‐Macrocyclization Provides High‐Affinity CD36‐Modulating PeptidomimeticsZhang, Jinqiang / Mulumba, Mukandila / Ong, Huy / Lubell, William D. et al. | 2017
- 6289
-
A Direct Link from the Gas to the Condensed Phase: A Rotational Spectroscopic Study of 2,2,2‐Trifluoroethanol TrimersThomas, Javix / Seifert, Nathan A. / Jäger, Wolfgang / Xu, Yunjie et al. | 2017
- 6294
-
Batch and Continuous‐Flow One‐Pot Processes using Amine Diazotization to Produce Silylated Diazo ReagentsAudubert, Clément / Gamboa Marin, Oscar Javier / Lebel, Hélène et al. | 2017
- 6298
-
Taming Silicon Congeners of CO and CO2: Synthesis of Monomeric SiII and SiIV Chalcogenide ComplexesBurchert, Alexander / Müller, Robert / Yao, Shenglai / Schattenberg, Caspar / Xiong, Yun / Kaupp, Martin / Driess, Matthias et al. | 2017
- 6302
-
Carbonyls as Latent Alkyl Carbanions for Conjugate AdditionsDai, Xi‐Jie / Wang, Haining / Li, Chao‐Jun et al. | 2017
- 6307
-
Rhodium‐Catalyzed Enantioselective Isomerization of meso‐Oxabenzonorbornadienes to 1,2‐Naphthalene OxidesYen, Andy / Choo, Ken‐Loon / Yazdi, Shabnam K. / Franke, Patrick T. / Webster, Robert / Franzoni, Ivan / Loh, Charles C. J. / Poblador‐Bahamonde, Amalia I. / Lautens, Mark et al. | 2017
- 6312
-
Dehydrogenative B−H/C(sp3)−H Benzylic Borylation within the Coordination Sphere of Platinum(II)Kelly, Colin M. / Fuller, Jack T. III / Macaulay, Casper M. / McDonald, Robert / Ferguson, Michael J. / Bischof, Steven M. / Sydora, Orson L. / Ess, Daniel H. / Stradiotto, Mark / Turculet, Laura et al. | 2017
- 6317
-
Iron‐Catalyzed gem‐Specific Dimerization of Terminal AlkynesLiang, Qiuming / Osten, Kimberly M. / Song, Datong et al. | 2017
- 6321
-
The Need for an Alternative to Radicals as the Cause of Fragmentation of a Thiamin‐Derived Breslow IntermediateBielecki, Michael / Kluger, Ronald et al. | 2017
- 6324
-
In‐Phase Ultra High‐Resolution In Vivo NMRFugariu, Ioana / Bermel, Wolfgang / Lane, Daniel / Soong, Ronald / Simpson, Andre J. et al. | 2017
- 6329
-
Size‐Tunable Photothermal Germanium NanocrystalsSun, Wei / Zhong, Grace / Kübel, Christian / Ali, Feysal M. / Qian, Chenxi / Wang, Lu / Ebrahimi, Manuchehr / Reyes, Laura M. / Helmy, Amr S. / Ozin, Geoffrey A. et al. | 2017
- 6335
-
Oxidation‐Initiated Cyclizations of Pentadienyl Ethers: An Alternative Entry to the Nazarov ReactionFradette, Ryan J. / Kang, Minkyu / West, F. G. et al. | 2017
- 6339
-
Air‐Stable Manganese(I)‐Catalyzed C−H Activation for Decarboxylative C−H/C−O Cleavages in WaterWang, Hui / Lorion, Mélanie M. / Ackermann, Lutz et al. | 2017
- 6343
-
Inside Back Cover: Ultrafast Independent N−H and N−C Bond Deformation Investigated with Resonant Inelastic X‐Ray Scattering (Angew. Chem. Int. Ed. 22/2017)Eckert, Sebastian / Norell, Jesper / Miedema, Piter S. / Beye, Martin / Fondell, Mattis / Quevedo, Wilson / Kennedy, Brian / Hantschmann, Markus / Pietzsch, Annette / Van Kuiken, Benjamin E. et al. | 2017
- 6344
-
Back Cover: From Bidentate Gallium Lewis Acids to Supramolecular Complexes (Angew. Chem. Int. Ed. 22/2017)Horstmann, Jan / Hyseni, Mentor / Mix, Andreas / Neumann, Beate / Stammler, Hans‐Georg / Mitzel, Norbert W. et al. | 2017
-
Frontispiece: High‐Throughput Synthesis of Mixed‐Metal Electrocatalysts for CO2 ReductionHe, Jingfu / Dettelbach, Kevan E. / Salvatore, Danielle A. / Li, Tengfei / Berlinguette, Curtis P. et al. | 2017