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ARTICLES - Vinyl Monomers Bearing Chromophore Moieties and Their Polymers. VIII. Synthesis and Fluorescence Behavior of a Vinyloxy Monomer Having an Electron-Accepting Chromophore Moiety, p-((Vinyloxy)methyl)-benzonitrile, and Its Polymers - A vinyloxy monomer, p-((vinyloxy)methyl)benzonitrile (VOMBN), was synthesized and polymerized. Fluorescence studies showed that the emission intensity of the monomer is much lower than those of its polymers and the model compound, p-(ethoxymethyl)benzonitrile at the same chromophore concentration. That is, VOMBN shows the fluorescence "structural self-quenching effect" (SSQE), which is mainly caused by the intramolecular charge-transfer interaction between the electron-accepting chromophore and the electron-donating double bond in the same molecule as illustrated as in the scheme.
Online Contents | 1999| -
Synthesis and pH-dependent hydrolysis profiles of mono- and dialkyl substituted maleamic acids
British Library Online Contents | 2017| -
Synthesis and Photochemical Behavior of 2-(N-acridonyl)ethyl Methacrylate and Its Polymer
Online Contents | 1996| -
Application of finite element method and artificial neural networks to predict the rolling force in hot rolling of Mg alloy plates
British Library Online Contents | 2016| -
FEM Analysis of Contact Stress and Crown Control for Six-High CVC Mill
British Library Online Contents | 2012| -
Actuator Effectiveness Based on Finite Element and Neural Network
British Library Online Contents | 2012| -
Influence of Pass Parameters on Retained Mandrel Rolling Process
British Library Online Contents | 2011| -
Group FEM Model for Tube Shape Prediction of Stretch Reducing Process
British Library Online Contents | 2009| -
Mechanism of crack initiation and propagation on casting roller surface
British Library Online Contents | 2008| -
Effect of Oxide Scale on Interfacial Heat Transfer during Slab Hot Rolling
British Library Online Contents | 2002| -
Synthesis and Aggregation Behavior of Mannose-terminated Polylysine
British Library Online Contents | 2013| -
Void Closure Behavior in Large Diameter Steel Rod during H-V Rolling Process
British Library Online Contents | 2014| -
Application of Fuzzy Immune PID Controller Based on Gray Prediction in Gauge Control System
British Library Online Contents | 2010| -
A New Study on Online Control Model for Rolling Process of Strip
British Library Online Contents | 2010|
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