Total Synthesis of Indolizidine Alkaloid (-)-209D: Overriding Substrate Bias in the Asymmetric Rhodium-Catalyzed [2+2+2] Cycloaddition We thank NIGMS (GM080442), Eli Lilly, Boehringer Ingelheim and Johnson & Johnson for support. T.R. is a fellow of the Alfred P. Sloan Foundation and thanks the Monfort Family Foundation for a Monfort Professorship. (German)
- New search for: Yu, Robert T
- New search for: Yu, Robert T
- New search for: Lee, Ernest E
- New search for: Malik, Guillaume
- New search for: Rovis, Tomislav
In:
Angewandte Chemie
;
121
, 13
; 2415-2418
;
2009
-
ISSN:
- Article (Journal) / Print
-
Title:Total Synthesis of Indolizidine Alkaloid (-)-209D: Overriding Substrate Bias in the Asymmetric Rhodium-Catalyzed [2+2+2] Cycloaddition We thank NIGMS (GM080442), Eli Lilly, Boehringer Ingelheim and Johnson & Johnson for support. T.R. is a fellow of the Alfred P. Sloan Foundation and thanks the Monfort Family Foundation for a Monfort Professorship.
-
Contributors:
-
Published in:Angewandte Chemie ; 121, 13 ; 2415-2418
-
Publisher:
- New search for: Wiley-VCH Verl.
-
Place of publication:Weinheim
-
Publication date:2009
-
ISSN:
-
ZDBID:
-
Type of media:Article (Journal)
-
Type of material:Print
-
Language:German
- New search for: 35.00 / 50.00
- Further information on Basic classification
- New search for: 020/3600/5700
-
Keywords:
-
Classification:
BKL: 35.00 Chemie: Allgemeines / 50.00 Technik allgemein: Allgemeines Local classification TIB: 020/3600/5700 -
Source:
Table of contents – Volume 121, Issue 13
The tables of contents are generated automatically and are based on the data records of the individual contributions available in the index of the TIB portal. The display of the Tables of Contents may therefore be incomplete.
- 2279
-
Titelbild: Metal–Organic Spheres as Functional Systems for Guest Encapsulation (Angew. Chem. 13/2009)Imaz, Inhar / Hernando, Jordi / Ruiz‐Molina, Daniel / Maspoch, Daniel et al. | 2009
- 2280
-
Innentitelbild: A Phosphine‐Mediated Conversion of Azides into Diazo Compounds (Angew. Chem. 13/2009)Myers, Eddie L. / Raines, Ronald T. et al. | 2009
- 2283
-
Graphisches Inhaltsverzeichnis: Angew. Chem. 13/2009| 2009
- 2296
-
Top‐Beiträge aus unseren Schwesterzeitschriften: Angew. Chem. 13/2009| 2009
- 2296
-
Top-Beitrage aus unseren Schwesterzeitschriften: Angew. Chem. 13/2009| 2009
- 2298
-
Organische Synthese: Mitsui Chemicals Catalysis Award an J. F. Hartwig und K. Nozaki / Nachwuchspreise für S. Matsunaga und Y. Nakao| 2009
- 2298
-
Organische Synthese: Mitsui Chemicals Catalysis Award an J. F. Hartwig und K. Nozaki / Nachwuchspreise fur S. Matsunaga und Y. Nakao| 2009
- 2299
-
Roberta Sessoli| 2009
- 2300
-
Amino Acids and the Asymmetry of Life.Caught in the Act of Formation. Von Uwe Meierhenrich.Kellogg, Richard M. et al. | 2009
- 2302
-
Nachweis von Drogenmissbrauch durch Nanopartikel‐verstärktes Fluoreszenz‐Imaging von latenten FingerabdrückenWolfbeis, Otto S. et al. | 2009
- 2302
-
Nachweis von Drogenmissbrauch durch Nanopartikel-verstarktes Fluoreszenz-Imaging von latenten FingerabdruckenWolfbeis, O. S. et al. | 2009
- 2305
-
Was ist wirklich nötig, um Komplexe später Übergangsmetalle mit terminalen Oxo‐Liganden zu stabilisieren?Limberg, Christian et al. | 2009
- 2305
-
Was ist wirklich notig, um Komplexe spater Ubergangsmetalle mit terminalen Oxo-Liganden zu stabilisieren?Limberg, C. et al. | 2009
- 2309
-
Koordinationspolymere: von metall‐organischen Gerüsten zu KugelnChampness, Neil R. et al. | 2009
- 2309
-
Koordinationspolymere: von metall-organischen Gerusten zu KugelnChampness, N. R. et al. | 2009
- 2312
-
Die C‐C‐Kreuzkupplung nach Liebeskind und SroglProkopcová, Hana / Kappe, C. Oliver et al. | 2009
- 2324
-
“Covalent Capture”: Verschmelzung von kovalenter und nichtkovalenter SynthesePrins, Leonard J. / Scrimin, Paolo et al. | 2009
- 2344
-
Oxidase‐Like Activity of Polymer‐Coated Cerium Oxide NanoparticlesAsati, Atul / Santra, Santimukul / Kaittanis, Charalambos / Nath, Sudip / Perez, J. Manuel et al. | 2009
- 2344
-
Oxidase-Like Activity of Polymer-Coated Cerium Oxide Nanoparticles The authors acknowledge funding by the National Institutes of Health (CA101781) and an UCF-NSTC Start Up Fund, all to J.M.P.Asati, Atul et al. | 2009
- 2349
-
Universal Scaffold for Fluorescent Conjugated Organoborane PolymersLi, Haiyan / Jäkle, Frieder et al. | 2009
- 2349
-
Universal Scaffold for Fluorescent Conjugated Organoborane Polymers Acknowledgement is made to the NSF (CAREER award CHE-0346828 and CHE-0809642) and the Alfred P. Sloan foundation for support. We thank Dr. Y. Qin for preparing the quinolato ligands and K. Parab for the copper reagents.Li, Haiyan et al. | 2009
- 2353
-
Helical-Ribbon Formation by a β-Amino Acid Modified Amyloid β-Peptide Fragment We thank Nick Spencer at the Biocentre (University of Reading) for assistance with XRD, and José Rodríguez and Rebecca Green (both School of Chemistry, Food Biosciences and Pharmacy, University of Reading) for help with FTIR.Castelletto, Valeria et al. | 2009
- 2353
-
Helical-Ribbon Formation by a b-Amino Acid Modified Amyloid b-Peptide FragmentCastelletto, V. / Hamley, I. W. / Hule, R. A. / Pochan, D. et al. | 2009
- 2353
-
Helical‐Ribbon Formation by a β‐Amino Acid Modified Amyloid β‐Peptide FragmentCastelletto, Valeria / Hamley, Ian W. / Hule, Rohan A. / Pochan, Darrin et al. | 2009
- 2357
-
The Imidazopyridine Derivative JK184 Reveals Dual Roles for Microtubules in Hedgehog SignalingCupido, Tommaso / Rack, Paul G. / Firestone, Ari J. / Hyman, Joel M. / Han, Kyuho / Sinha, Surajit / Ocasio, Cory A. / Chen, James K. et al. | 2009
- 2357
-
The Imidazopyridine Derivative JK184 Reveals Dual Roles for Microtubules in Hedgehog Signaling We thank Dr. G. Heffner, B. Moree, and Prof. Dr. A. F. Straight for technical assistance. This work was supported by the Stanford Interdisciplinary Translational Research Program, the Sidney Kimmel Foundation for Cancer Research, the Astellas USA Foundation, and the Brain Tumor Society-Rachel Molly Markoff Foundation.Cupido, Tommaso et al. | 2009
- 2361
-
Metal-Organic Spheres as Functional Systems for Guest Encapsulation This work was supported by projects MAT2006-13765-C02 and CTQ2006-01040. D.M. and J.H. thank the Ministerio de Ciencia y Tecnología for a RyC contract. I.I. thanks the Institut Català de Nanotecnologia for a research contract. We thank the Servei de Microscopia of the UAB and the Laboratori de Nanotecnologia of MATGAS.Imaz, Inhar et al. | 2009
- 2361
-
Metal–Organic Spheres as Functional Systems for Guest EncapsulationImaz, Inhar / Hernando, Jordi / Ruiz‐Molina, Daniel / Maspoch, Daniel et al. | 2009
- 2366
-
A Reduced SNARE Model for Membrane Fusion We are grateful to Wim Jesse for his technical assistance. We thank E. J. Creusen, V. J. J. Kusters, B. J. Conijn, S. Brouwer de Koning, and R. J. Voorhoeve, students of the Eindhoven University of Technology Honors Program, for their help in performing the cryo-TEM experiments. P. M. Frederik is acknowledged for fruitful discussions. SNARE=soluble NSF attachment protein receptor; NSF= N-ethylmaleimide-sensitive factor.Robson Marsden, Hana et al. | 2009
- 2366
-
A Reduced SNARE Model for Membrane FusionRobson Marsden, Hana / Elbers, Nina A. / Bomans, Paul H. H. / Sommerdijk, Nico A. J. M. / Kros, Alexander et al. | 2009
- 2370
-
A Luminescent Microporous Metal-Organic Framework for the Fast and Reversible Detection of High Explosives A.L. and K.L. contributed equally to this project. A.L. is currently a visiting scholar supported by the CAS-SAFEA International Partnership Program for Creative Research Teams for his research at Rutgers University. We are grateful for the financial support from the DOE (Grant No. DE-FG02-08ER46491).Lan, Anjian et al. | 2009
- 2370
-
A Luminescent Microporous Metal–Organic Framework for the Fast and Reversible Detection of High ExplosivesLan, Anjian / Li, Kunhao / Wu, Haohan / Olson, David H. / Emge, Thomas J. / Ki, Woosoek / Hong, Maochun / Li, Jing et al. | 2009
- 2375
-
Engineering A Uranyl‐Specific Binding Protein from NikRWegner, Seraphine V. / Boyaci, Hande / Chen, Hao / Jensen, Mark P. / He, Chuan et al. | 2009
- 2375
-
Engineering A Uranyl-Specific Binding Protein from NikR This work and use of the Advanced Photon Source, was supported by the US Department of Energy, Office of Science, Office of Basic Energy Sciences under contract numbers DE-FG02-07ER15865 (C.H.) and DE-AC02-06CH11357 (M.P.J. and APS use), and a UChicago-Argonne Strategic Collaborative Initiative grant (C.H. and M.P.J.). We thank P. T. Chivers for the nikR encoding plasmid and are grateful for the use of XOR-BESSRC-CAT and the Actinide Facility. NikR is a Ni2+-dependent transcriptional repressor protein.Wegner, Seraphine V et al. | 2009
- 2378
-
Synthesis of Goethite by Separation of the Nucleation and Growth Processes of Ferrihydrite Nanoparticles Using MicrofluidicsAbou‐Hassan, Ali / Sandre, Olivier / Neveu, Sophie / Cabuil, Valérie et al. | 2009
- 2378
-
Synthesis of Goethite by Separation of the Nucleation and Growth Processes of Ferrihydrite Nanoparticles Using Microfluidics We thank Patricia Beaunier from the Electron Microscopy Facility (UPMC, UFR 926) for the TEM and HRTEM images, Virginie Georget from the cellular imaging facility for the LCSM images (UPMC, IFR 83), and Preston Mohr and Thomas Boudier (UPMC, IFR 83) for fruitful discussions regarding image analysis.Abou-Hassan, Ali et al. | 2009
- 2382
-
A Total Synthesis of Norhalichondrin B This research was supported by the National Cancer Institute (NCI CA110246), Eli Lilly & Co under the auspices of the Lilly Awardee Program (to A.J.P.), and in part by The American Chemical Society Petroleum Research Fund (ACS PRF 38856-G1). We thank Prof. Robert H. Grubbs and Dr. Ian C. Stewart (Caltech), Materia Inc. for catalyst 41, Prof. Yoshito Kishi (Harvard), and Professors John Blunt and Murray Munro (Canterbury) for copies of spectra.Jackson, Katrina L et al. | 2009
- 2382
-
A Total Synthesis of Norhalichondrin BJackson, Katrina L. / Henderson, James A. / Motoyoshi, Hajime / Phillips, Andrew J. et al. | 2009
- 2387
-
Biomimetic Total Synthesis of (±)-Pallavicinolide A We thank the Research Grants Council of the Hong Kong Special Administrative Region, China (Project No. CUHK 403505) and Area of Excellence Scheme established under the University Grants Committee of the Hong Kong SAR, China (Project No. AoE-9-10-01) for financial support.Dong, Jia-Qiang et al. | 2009
- 2387
-
Biomimetic Total Synthesis of (±)‐Pallavicinolide ADong, Jia‐Qiang / Wong, Henry N. C. et al. | 2009
- 2391
-
Epimerization‐Free Block Synthesis of Peptides from Thioacids and Amines with the Sanger and Mukaiyama ReagentsCrich, David / Sharma, Indrajeet et al. | 2009
- 2395
-
A Phosphine‐Mediated Conversion of Azides into Diazo CompoundsMyers, Eddie L. / Raines, Ronald T. et al. | 2009
- 2395
-
A Phosphine-Mediated Conversion of Azides into Diazo Compounds We thank Dr. Ilia A. Guzei and Amit Choudhary for X-ray crsytallographic data pertaining to triazene 8 and Dr. Annie Tam for preparing azide 2 d. We acknowledge use of the National Magnetic Resonance Facility (NMRFAM) and services of the Mass Spectrometry Facility in the Department of Chemistry. This work was supported by NIH grant GM044783; NMRFAM was supported by NIH grant P41RR02301.Myers, Eddie L et al. | 2009
- 2400
-
Total Synthesis of (−)‐Amphidinolide KKo, Haye Min / Lee, Chung Whan / Kwon, Hyung Kyoo / Chung, Hea Seung / Choi, Soo Young / Chung, Young Keun / Lee, Eun et al. | 2009
- 2400
-
Total Synthesis of (-)-Amphidinolide K This work was supported by a grant from the Marine Biotechnology Program funded by the Ministry of Land, Transport, and Maritime Affairs, Republic of Korea, and a grant from the Korea Research Foundation (MOEHRD, Basic Research Promotion Fund; KRF-2008-314-C00198). BK21 graduate fellowship grants to H.M.K., C.W.L., H.K.K., and H.S.C., and a Seoul Science Fellowship grant to H.M.K. are gratefully acknowledged.Ko, Haye Min et al. | 2009
- 2403
-
Highly Efficient and Regioselective Platinum(II)‐Catalyzed Tandem Synthesis of Multiply Substituted Indolines and TetrahydroquinolinesLiu, Xin‐Yuan / Che, Chi‐Ming et al. | 2009
- 2403
-
Highly Efficient and Regioselective Platinum(II)-Catalyzed Tandem Synthesis of Multiply Substituted Indolines and Tetrahydroquinolines This study was supported by The University of Hong Kong (University Development Fund), The Hong Kong Research Grants Council, and The University Grants Committee of the Hong Kong SAR of China (Area of Excellence Scheme, AoE-P-10-01).Liu, Xin-Yuan et al. | 2009
- 2408
-
Stereoselective Synthesis of cis-β-Methyl- and Phenyl-Substituted Alkenylboronates by Platinum-Catalyzed Dehydrogenative Borylation This work was supported in part by a Grant-in-Aid for Young Scientists (B) (No. 20750076) from the Ministry of Education, Culture, Sports, Science and Technology (Japan).Ohmura, Toshimichi et al. | 2009
- 2408
-
Stereoselective Synthesis of cis‐β‐Methyl‐ and Phenyl‐Substituted Alkenylboronates by Platinum‐Catalyzed Dehydrogenative BorylationOhmura, Toshimichi / Takasaki, Yuta / Furukawa, Hideki / Suginome, Michinori et al. | 2009
- 2408
-
Stereoselective Synthesis of cis-b-Methyl- and Phenyl-Substituted Alkenylboronates by Platinum-Catalyzed Dehydrogenative BorylationOhmura, T. / Takasaki, Y. / Furukawa, H. / Suginome, M. et al. | 2009
- 2412
-
A Method for the Positioning and Tracking of Small Moving ParticlesRees, Neil V. / Matthews, Sinéad M. / Yunus, Kamran / Fisher, Adrian C. / Compton, Richard G. et al. | 2009
- 2412
-
A Method for the Positioning and Tracking of Small Moving Particles N.V.R. thanks the EPSRC for funding (grant no. EP-D012546-1).Rees, Neil V et al. | 2009
- 2415
-
Total Synthesis of Indolizidine Alkaloid (−)‐209D: Overriding Substrate Bias in the Asymmetric Rhodium‐Catalyzed [2+2+2] CycloadditionYu, Robert T. / Lee, Ernest E. / Malik, Guillaume / Rovis, Tomislav et al. | 2009
- 2415
-
Total Synthesis of Indolizidine Alkaloid (-)-209D: Overriding Substrate Bias in the Asymmetric Rhodium-Catalyzed [2+2+2] Cycloaddition We thank NIGMS (GM080442), Eli Lilly, Boehringer Ingelheim and Johnson & Johnson for support. T.R. is a fellow of the Alfred P. Sloan Foundation and thanks the Monfort Family Foundation for a Monfort Professorship.Yu, Robert T et al. | 2009
- 2419
-
Pd‐PEPPSI‐IPent: An Active, Sterically Demanding Cross‐Coupling Catalyst and Its Application in the Synthesis of Tetra‐Ortho‐Substituted BiarylsOrgan, Michael G. / Çalimsiz, Selçuk / Sayah, Mahmoud / Hoi, Ka Hou / Lough, Alan J. et al. | 2009
- 2419
-
Pd-PEPPSI-IPent: An Active, Sterically Demanding Cross-Coupling Catalyst and Its Application in the Synthesis of Tetra-Ortho-Substituted Biaryls This work is supported by NSERC (Canada) and the ORDCF (Ontario). PEPPSI=Pyridine-Enhanced Precatalyst Preparation Stabilization and Initiation.Organ, Michael G et al. | 2009
- 2424
-
Zwitterionic Corroles: Regioselective Nucleophilic Pyridination of a Doubly Linked Biscorrole This work was partly supported by Grants-in-Aid for Scientific Research (nos. 18685013, 19205006, and 20037034) from the Ministry of Education, Culture, Sports, Science, and Technology (Japan). H.S. acknowledges Ogasawara Science Foundation for financial support. S.H. acknowledges the Research Fellowships of the JSPS for Young Scientists.Hiroto, Satoru et al. | 2009
- 2424
-
Zwitterionic Corroles: Regioselective Nucleophilic Pyridination of a Doubly Linked BiscorroleHiroto, Satoru / Aratani, Naoki / Shibata, Naoki / Higuchi, Yoshiki / Sasamori, Takahiro / Tokitoh, Norihiro / Shinokubo, Hiroshi / Osuka, Atsuhiro et al. | 2009
- 2427
-
Catalytic Asymmetric Cycloaddition of Ketenes and Nitroso Compounds: Enantioselective Synthesis of a-Hydroxycarboxylic Acid DerivativesDochnahl, M. / Fu, G. C. et al. | 2009
- 2427
-
Catalytic Asymmetric Cycloaddition of Ketenes and Nitroso Compounds: Enantioselective Synthesis of α‐Hydroxycarboxylic Acid DerivativesDochnahl, Maximilian / Fu, Gregory C. et al. | 2009
- 2427
-
Catalytic Asymmetric Cycloaddition of Ketenes and Nitroso Compounds: Enantioselective Synthesis of α-Hydroxycarboxylic Acid Derivatives Support has been provided by the National Institutes of Health (National Institute of General Medical Sciences, grant R01-GM57034), the German Academic Exchange Service (postdoctoral fellowship for M.D.), Merck Research Laboratories, and Novartis.Dochnahl, Maximilian et al. | 2009
- 2430
-
Tellus in, Tellus out: The Chemistry of the Vanadium Bis(telluride) Functionality We thank the NSF (CHE-0348941) and the Sloan and the Dreyfus Foundations for financial support of this research. CI and MALDI mass spectra were recorded with the assistance of Angela Hansen. The MAT-95XP was purchased with funds from NIH grant 1S10RR016657-01 and the Bruker Biflex III MALDI-TOF was purchased with funds from NSF grant 9970211.Kilgore, Uriah J et al. | 2009
- 2430
-
Tellus in, Tellus out: The Chemistry of the Vanadium Bis(telluride) FunctionalityKilgore, Uriah J. / Karty, Jonathan A. / Pink, Maren / Gao, Xinfeng / Mindiola, Daniel J. et al. | 2009
- 2434
-
Parallel Kinetic Resolution Approach to the Cyathane and Cyanthiwigin Diterpenes Using a Cyclopropanation/Cope RearrangementMiller, Laura C. / Ndungu, J. Maina / Sarpong, Richmond et al. | 2009
- 2434
-
Parallel Kinetic Resolution Approach to the Cyathane and Cyanthiwigin Diterpenes Using a Cyclopropanation-Cope Rearrangement We are grateful to UC Berkeley, the American Cancer Society (RSG-09-017-01-CDD), and GlaxoSmithKline for support of this research. H. Wong, K. Uychaco, and B. Ikkanda are acknowledged for preliminary work. Prof. H. M. L. Davies (Emory University) is acknowledged for a gift of [Rh2{(S)-dosp}4]. Dr. F. Hollander is thanked for the X-ray crystal structure (see Ref. [23]).Miller, Laura C et al. | 2009
- 2439
-
Highly Enantioselective Pictet-Spengler Reactions with α-Ketoamide-Derived Ketimines: Access to an Unusual Class of Quaternary α-Amino Amides This work was supported by a grant from the National Science Foundation (CHE-08-09659). F.R.B.-H. was supported by a postdoctoral fellowship from the MDS Research Foundation. We thank Prof. Ged Parkin and Aaron Sattler for an X-ray crystal structure analysis (see the Supporting Information), and the National Science Foundation (CHE-0619638) is thanked for acquisition of an X-ray diffractometer.Bou-Hamdan, Farhan R et al. | 2009
- 2439
-
Highly Enantioselective Pictet–Spengler Reactions with α‐Ketoamide‐Derived Ketimines: Access to an Unusual Class of Quaternary α‐Amino AmidesBou‐Hamdan, Farhan R. / Leighton, James L. et al. | 2009
- 2439
-
Highly Enantioselective Pictet-Spengler Reactions with a-Ketoamide-Derived Ketimines: Access to an Unusual Class of Quaternary a-Amino AmidesBou-Hamdan, F. R. / Leighton, J. L. et al. | 2009
- 2443
-
Wireless Activation of Neurons in Brain Slices Using Nanostructured Semiconductor PhotoelectrodesZhao, Yixin / Larimer, Philip / Pressler, Richard T. / Strowbridge, Ben W. / Burda, Clemens et al. | 2009
- 2443
-
Wireless Activation of Neurons in Brain Slices Using Nanostructured Semiconductor Photoelectrodes This work was supported by NIH grants NS33590 and DC04285 to B.W.S. C.B. acknowledges BRTT support from the State of Ohio, and NSF grants NIRT 0608896, Career 0239688, and CRIF 0443570.Zhao, Yixin et al. | 2009
- 2447
-
Ultraschnelle Klickkonjugation von makromolekularen Bausteinen bei Raumtemperatur C.B.-K. dankt dem Karlsruher Institut für Technologie (KIT) für finanzielle Unterstützung im Rahmen der Exzellenzinitiative für führende deutsche Universitäten.Inglis, Andrew J et al. | 2009
- 2447
-
Ultraschnelle Klickkonjugation von makromolekularen Bausteinen bei RaumtemperaturInglis, Andrew J. / Sinnwell, Sebastian / Stenzel, Martina H. / Barner‐Kowollik, Christopher et al. | 2009
- 2451
-
Suboxide mit komplexen Anionen: das Suboxoindat Cs9InO4Hoch, Constantin / Bender, Johannes / Simon, Arndt et al. | 2009
- 2451
-
Suboxide mit komplexen Anionen: das Suboxoindat Cs9InO4 Wir danken R. Eger für Differenzthermoanalysen und F. Kögel für die Synthese von Caesiumoxid.Hoch, Constantin et al. | 2009
- 2454
-
Fluoreszenz‐Farbwechsel bei der DNA‐Hybridisierung mit Thiazolorange als artifizieller DNA‐BaseBerndl, Sina / Wagenknecht, Hans‐Achim et al. | 2009
- 2454
-
Fluoreszenz-Farbwechsel bei der DNA-Hybridisierung mit Thiazolorange als artifizieller DNA-Base Für die finanzielle Unterstützung durch die Deutsche Forschungsgemeinschaft, den Fonds der Chemischen Industrie und die Universität Regensburg wird gedankt.Berndl, Sina et al. | 2009
- 2461
-
Vorschau: Angew. Chem. 14/2009| 2009