Carbon–fluorine bond cleavage in fluoroarenes via a niobium(iii) imido complex: from stoichiometric to catalytic hydrodefluorination (English)
National licence
- New search for: Gianetti, Thomas L.
- New search for: Bergman, Robert G.
- New search for: Arnold, John
- New search for: Gianetti, Thomas L.
- New search for: Bergman, Robert G.
- New search for: Arnold, John
In:
Chemical Science
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5
, 6
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2517-2524
;
2014
- Article (Journal) / Electronic Resource
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Title:Carbon–fluorine bond cleavage in fluoroarenes via a niobium(iii) imido complex: from stoichiometric to catalytic hydrodefluorination
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Contributors:
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Published in:Chemical Science ; 5, 6 ; 2517-2524
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Publisher:
- New search for: The Royal Society of Chemistry
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Publication date:2014-05-07
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Size:8 pages
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ISSN:
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Coden:
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DOI:
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Type of media:Article (Journal)
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Type of material:Electronic Resource
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Language:English
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Source:
Table of contents – Volume 5, Issue 6
The tables of contents are generated automatically and are based on the data records of the individual contributions available in the index of the TIB portal. The display of the Tables of Contents may therefore be incomplete.
- 2103
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Front cover| 2014
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Inside front cover| 2014
- 2105
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Contents list| 2014
- 2123
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Bioorthogonal chemistry in living organismsBorrmann, Annika / van Hest, Jan C. M. et al. | 2014
- 2135
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Supramolecular control of selectivity in transition-metal catalysis through substrate preorganizationDydio, Paweł / Reek, Joost N. H. et al. | 2014
- 2146
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Transition metal-catalyzed direct nucleophilic addition of C–H bonds to carbon–heteroatom double bondsZhang, Xi-Sha / Chen, Kang / Shi, Zhang-Jie et al. | 2014
- 2160
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An iron–dopamine index predicts risk of parkinsonian neurodegeneration in the substantia nigra pars compactaHare, Dominic J. / Lei, Peng / Ayton, Scott / Roberts, Blaine R. / Grimm, Rudolf / George, Jessica L. / Bishop, David P. / Beavis, Alison D. / Donovan, Sarah J. / McColl, Gawain et al. | 2014
- 2170
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The ON/OFF switching by metal ions of the “Sergeants and Soldiers” chiral amplification effect on helical poly(phenylacetylene)sBergueiro, Julián / Freire, Félix / Wendler, Edison P. / Seco, José M. / Quiñoá, Emilio / Riguera, Ricardo et al. | 2014
- 2177
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A dual emission fluorescent probe enables simultaneous detection of glutathione and cysteine/homocysteineYang, Xiao-Feng / Huang, Qian / Zhong, Yaogang / Li, Zheng / Li, Hua / Lowry, Mark / Escobedo, Jorge O. / Strongin, Robert M. et al. | 2014
- 2184
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Total syntheses of indolactam alkaloids (−)-indolactam V, (−)-pendolmycin, (−)-lyngbyatoxin A, and (−)-teleocidin A-2Fine Nathel, Noah F. / Shah, Tejas K. / Bronner, Sarah M. / Garg, Neil K. et al. | 2014
- 2191
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A catalytic role for methionine revealed by a combination of computation and experiments on phosphite dehydrogenaseRanaghan, Kara E. / Hung, John E. / Bartlett, Gail J. / Mooibroek, Tiddo J. / Harvey, Jeremy N. / Woolfson, Derek N. / van der Donk, Wilfred A. / Mulholland, Adrian J. et al. | 2014
- 2200
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Iron catalyzed enantioselective sulfa-Michael addition: a four-step synthesis of the anti-asthma agent MontelukastWhite, James D. / Shaw, Subrata et al. | 2014
- 2205
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On the factors that control the reactivity of meta-benzynesGao, Jinshan / Jankiewicz, Bartłomiej J. / Reece, Jennifer / Sheng, Huaming / Cramer, Christopher J. / Nash, John J. / Kenttämaa, Hilkka I. et al. | 2014
- 2216
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Light-activated antimicrobial surfaces with enhanced efficacy induced by a dark-activated mechanismNoimark, Sacha / Allan, Elaine / Parkin, Ivan P. et al. | 2014
- 2224
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Visualizing tilted binding and precession of diatomic NO adsorbed to Co-porphyrin on Au(111) using scanning tunneling microscopyKim, Howon / Chang, Yun Hee / Lee, Soon-Hyeong / Lim, Soobin / Noh, Seung-Kyun / Kim, Yong-Hyun / Kahng, Se-Jong et al. | 2014
- 2230
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Denovo asymmetric synthesis of the mezzettiaside family of natural products via the iterative use of a dual B-/Pd-catalyzed glycosylationBajaj, Sumit O. / Sharif, Ehesan U. / Akhmedov, Novruz G. / O'Doherty, George A. et al. | 2014
- 2235
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Predicted crystal energy landscapes of porous organic cagesPyzer-Knapp, Edward O. / Thompson, Hugh P. G. / Schiffmann, Florian / Jelfs, Kim E. / Chong, Samantha Y. / Little, Marc A. / Cooper, Andrew I. / Day, Graeme M. et al. | 2014
- 2246
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Precision polymers: a kinetic approach for functional poly(norbornenes)Moatsou, Dafni / Hansell, Claire F. / O'Reilly, Rachel K. et al. | 2014
- 2251
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Ultrathin nanosheets of feroxyhyte: a new two-dimensional material with robust ferromagnetic behaviorChen, Pengzuo / Xu, Kun / Li, Xiuling / Guo, Yuqiao / Zhou, Dan / Zhao, Jiyin / Wu, Xiaojun / Wu, Changzheng / Xie, Yi et al. | 2014
- 2256
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Mechanism and active site of photocatalytic water splitting on titania in aqueous surroundingsZhao, Wei-Na / Liu, Zhi-Pan et al. | 2014
- 2265
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Ratiometric delivery of cisplatin and doxorubicin using tumour-targeting carbon-nanotubes entrapping platinum(iv) prodrugsChin, Chee Fei / Yap, Siew Qi / Li, Jian / Pastorin, Giorgia / Ang, Wee Han et al. | 2014
- 2271
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Isolation of the key intermediates of base-promoted borylene–carbonyl coupling reactionsBraunschweig, Holger / Kramer, Thoma / Radacki, Krzysztof / Shang, Rong / Siedler, Eva / Werner, Christine et al. | 2014
- 2277
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Catalytic enantioselective synthesis of 2-aryl-chromenesZeng, Bi-Shun / Yu, Xinyi / Siu, Paul W. / Scheidt, Karl A. et al. | 2014
- 2282
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Roles of carboxylate donors in O–O bond scission of peroxodi-iron(iii) to high-spin oxodi-iron(iv) with a new carboxylate-containing dinucleating ligandKodera, Masahito / Tsuji, Tomokazu / Yasunaga, Tomohiro / Kawahara, Yuka / Hirano, Tomoya / Hitomi, Yutaka / Nomura, Takashi / Ogura, Takashi / Kobayashi, Yoshio / Sajith, P. K. et al. | 2014
- 2293
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Exciton recombination dynamics in nanoring cycloparaphenylenesNishihara, Taishi / Segawa, Yasutomo / Itami, Kenichiro / Kanemitsu, Yoshihiko et al. | 2014
- 2297
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Zinc-seamed pyrogallol[4]arene dimers as structural components in a two-dimensional MOFMossine, Andrew V. / Mayhan, Collin M. / Fowler, Drew A. / Teat, Simon J. / Deakyne, Carol A. / Atwood, Jerry L. et al. | 2014
- 2304
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Electrochemical formation and reactivity of a manganese peroxo complex: acid driven H2O2 generation vs. O–O bond cleavageChing, H. Y. Vincent / Anxolabéhère-Mallart, Elodie / Colmer, Hannah E. / Costentin, Cyrille / Dorlet, Pierre / Jackson, Timothy A. / Policar, Clotilde / Robert, Marc et al. | 2014
- 2311
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Illuminating HIV gp120-ligand recognition through computationally-driven optimization of antibody-recruiting moleculesParker, Christopher G. / Dahlgren, Markus K. / Tao, Ran N. / Li, Don T. / Douglass, Eugene F. / Shoda, Takuji / Jawanda, Navneet / Spasov, Krasimir A. / Lee, Sangil / Zhou, Nannan et al. | 2014
- 2318
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Construction of an orthogonal ZnSalen/Salophen library as a colour palette for one- and two-photon live cell imagingXie, Da / Jing, Jing / Cai, Yuan-Bo / Tang, Juan / Chen, Juan-Juan / Zhang, Jun-Long et al. | 2014
- 2328
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Highly sensitive and selective detection of the pyrophosphate anion biomarker under physiological conditionsSánchez, Guzmán / Curiel, David / Tatkiewcz, Witold / Ratera, Imma / Tárraga, Alberto / Veciana, Jaume / Molina, Pedro et al. | 2014
- 2336
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Pd(quinox)-catalyzed allylic relay Suzuki reactions of secondary homostyrenyl tosylates via alkene-assisted oxidative additionStokes, Benjamin J. / Bischoff, Amanda J. / Sigman, Matthew S. et al. | 2014
- 2340
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Metal control of selectivity in acetate-assisted C–H bond activation: an experimental and computational study of heterocyclic, vinylic and phenylic C(sp2)–H bonds at Ir and RhCarr, Kevin J. T. / Davies, David L. / Macgregor, Stuart A. / Singh, Kuldip / Villa-Marcos, Barbara et al. | 2014
- 2347
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A catalyst-controlled selective synthesis of pyridines and pyrrolesJiang, Yaojia / Park, Cheol-Min et al. | 2014
- 2352
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Non-directed allylic C–H acetoxylation in the presence of Lewis basic heterocyclesMalik, Hasnain A. / Taylor, Buck L. H. / Kerrigan, John R. / Grob, Jonathan E. / Houk, K. N. / Du Bois, J. / Hamann, Lawrence G. / Patterson, Andrew W. et al. | 2014
- 2362
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Formal hydrogenation of arynes with silyl Cβ–H bonds as an active hydride sourceMamidipalli, Phani / Yun, Sang Young / Wang, Kung-Pern / Zhou, Tao / Xia, Yuanzhi / Lee, Daesung et al. | 2014
- 2362
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Formal hydrogenation of arynes with silyl Cb-H bonds as an active hydride sourceMamidipalli, P. / Yun, S. / Wang, K. P. / Zhou, T. / Xia, Y. / Lee, D. et al. | 2014
- 2368
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Rapid, facile synthesis of conjugated polymer zwitterions in ionic liquidsPage, Zachariah A. / Liu, Feng / Russell, Thomas P. / Emrick, Todd et al. | 2014
- 2374
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Coordination-triggered NO release from a dinitrosyl iron complex leads to anti-inflammatory activitySkodje, Kelsey M. / Kwon, Min-Young / Chung, Su Wol / Kim, Eunsuk et al. | 2014
- 2379
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Copper catalyzed direct alkenylation of simple alkanes with styrenesZhu, Yefeng / Wei, Yunyang et al. | 2014
- 2383
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Synthesis of diarylmethylamines via palladium-catalyzed regioselective arylation of 1,1,3-triaryl-2-azaallyl anionsLi, Minyan / Yücel, Bari / Adrio, Javier / Bellomo, Ana / Walsh, Patrick J. et al. | 2014
- 2392
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Guest-dependent mechanical anisotropy in pillared-layered soft porous crystals – a nanoindentation studyHenke, Sebastian / Li, Wei / Cheetham, Anthony K. et al. | 2014
- 2398
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Disubstituted sialic acid ligands targeting siglecs CD33 and CD22 associated with myeloid leukaemias and B cell lymphomasRillahan, Cory D. / Macauley, Matthew S. / Schwartz, Erik / He, Yuan / McBride, Ryan / Arlian, Britni M. / Rangarajan, Janani / Fokin, Valery V. / Paulson, James C. et al. | 2014
- 2407
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5-(Methylthio)tetrazoles as versatile synthons in the stereoselective synthesis of polycyclic pyrazolines via photoinduced intramolecular nitrile imine-alkene 1,3-dipolar cycloadditionPla, Daniel et al. | 2014
- 2416
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Copper catalyzed Heck-like cyclizations of oxime estersFaulkner, Adele / Race, Nicholas J. / Scott, James S. / Bower, John F. et al. | 2014
- 2422
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Selective radical amination of aldehydic C(sp2)–H bonds with fluoroaryl azides via Co(ii)-based metalloradical catalysis: synthesis of N-fluoroaryl amides from aldehydes under neutral and nonoxidative conditionsJin, Li-Mei / Lu, Hongjian / Cui, Yuan / Lizardi, Christopher L. / Arzua, Thiago N. / Wojtas, Lukasz / Cui, Xin / Zhang, X. Peter et al. | 2014
- 2428
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Boron–boron J coupling constants are unique probes of electronic structure: a solid-state NMR and molecular orbital studyPerras, Frédéric A. / Bryce, David L. et al. | 2014
- 2438
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Enantioselective direct α-alkylation of cyclic ketones by means of photo-organocatalysisArceo, Elena / Bahamonde, Ana / Bergonzini, Giulia / Melchiorre, Paolo et al. | 2014
- 2438
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Enantioselective direct a-alkylation of cyclic ketones by means of photo-organocatalysisArceo, E. / Bahamonde, A. / Bergonzini, G. / Melchiorre, P. et al. | 2014
- 2443
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Addition of pnictogen atoms to chromium(ii): synthesis, structure and magnetic properties of a chromium(iv) phosphide and a chromium(iii) arsenideReisinger, Sabine / Bodensteiner, Michael / Pineda, Eufemio Moreno / McDouall, Joseph J. W. / Scheer, Manfred / Layfield, Richard A. et al. | 2014
- 2449
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Sequence-responsive unzipping DNA cubes with tunable cellular uptake profilesBujold, Katherine E. / Fakhoury, Johan / Edwardson, Thomas G. W. / Carneiro, Karina M. M. / Briard, Joel Neve / Godin, Antoine G. / Amrein, Lilian / Hamblin, Graham D. / Panasci, Lawrence C. / Wiseman, Paul W. et al. | 2014
- 2456
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Pattern-based sensing of aminoglycosides with fluorescent amphiphilesKöstereli, Ziya / Scopelliti, Rosario / Severin, Kay et al. | 2014
- 2461
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Spin crossover iron(ii) complexes as PARACEST MRI thermometersJeon, Ie-Rang / Park, Jesse G. / Haney, Chad R. / Harris, T. David et al. | 2014
- 2466
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Phosphorus(v) tetraazaporphyrins: porphyrinoids showing an exceptionally strong CT band between the Soret and Q bandsFuruyama, Taniyuki / Yoshida, Takuya / Hashizume, Daisuke / Kobayashi, Nagao et al. | 2014
- 2475
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Magnitude and consequences of OR ligand σ-donation on alkene metathesis activity in d0 silica supported (&z.tbd;SiO)W(NAr)(&z.dbd;CHtBu)(OR) catalystsMougel, V. / Copéret, C. et al. | 2014
- 2482
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Phosphorescent nematic hydrogels and chromonic mesophases driven by intra- and intermolecular interactions of bridged dinuclear cyclometalated platinum(ii) complexesXiao, Xin-Shan / Lu, Wei / Che, Chi-Ming et al. | 2014
- 2489
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The role of 5f-orbital participation in unexpected inversion of the σ-bond metathesis reactivity trend of triamidoamine thorium(iv) and uranium(iv) alkylsGardner, Benedict M. / Cleaves, Peter A. / Kefalidis, Christos E. / Fang, Jian / Maron, Laurent / Lewis, William / Blake, Alexander J. / Liddle, Stephen T. et al. | 2014
- 2498
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Facile dissolution of selenium and tellurium in a thiol–amine solvent mixture under ambient conditionsWebber, David H. / Buckley, Jannise J. / Antunez, Priscilla D. / Brutchey, Richard L. et al. | 2014
- 2503
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X-ray fluorescence imaging reveals subcellular biometal disturbances in a childhood neurodegenerative disorderGrubman, A. / James, S. A. / James, J. / Duncan, C. / Volitakis, I. / Hickey, J. L. / Crouch, P. J. / Donnelly, P. S. / Kanninen, K. M. / Liddell, J. R. et al. | 2014
- 2517
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Carbon–fluorine bond cleavage in fluoroarenes via a niobium(iii) imido complex: from stoichiometric to catalytic hydrodefluorinationGianetti, Thomas L. / Bergman, Robert G. / Arnold, John et al. | 2014
- 2525
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Ambient condition oxidation in individual liposomes observed at the single molecule levelGodin, Robert / Liu, Hsiao-Wei / Cosa, Gonzalo et al. | 2014
- 2530
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Detecting intracellular translocation of native proteins quantitatively at the single cell levelCao, Zhenning / Geng, Shuo / Li, Liwu / Lu, Chang et al. | 2014
- 2536
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Conformational control of anticancer activity: the application of arene-linked dinuclear ruthenium(ii) organometallicsMurray, Benjamin S. / Menin, Laure / Scopelliti, Rosario / Dyson, Paul J. et al. | 2014
- 2546
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Multiple metal-bound oligomers from Ir-catalysed dehydropolymerisation of H3B·NH3 as probed by experiment and computationKumar, Amit / Johnson, Heather C. / Hooper, Thomas N. / Weller, Andrew S. / Algarra, Andrés G. / Macgregor, Stuart A. et al. | 2014
- 2554
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Aqueous solubilization of hydrophobic supramolecular metal–organic nanocapsulesKumari, H. / Kline, S. R. / Atwood, J. L. et al. | 2014
- 2560
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Stimuli-induced folding cascade of a linear oligomeric guest chain programmed through cucurbit[n]uril self-sorting (n = 6, 7, 8)Cera, Luca / Schalley, Christoph A. et al. | 2014
- 2560
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Stimuli-induced folding cascade of a linear oligomeric guest chain programmed through cucurbit[n]uril self-sorting (nCera, Luca et al. | 2014
- 2568
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Mapping electrogenerated chemiluminescence reactivity in space: mechanistic insight into model systems used in immunoassaysSentic, Milica / Milutinovic, Milena / Kanoufi, Frédéric / Manojlovic, Dragan / Arbault, Stéphane / Sojic, Neso et al. | 2014
- 2573
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Tuning the electronic environment of cations and anions using ionic liquid mixturesVillar-Garcia, Ignacio J. / Lovelock, Kevin R. J. / Men, Shuang / Licence, Peter et al. | 2014
- 2580
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En route towards panchromatic light harvesting: photophysical and electrochemical properties of Bodipy–porphyrazine conjugatesKuhri, S. / Engelhardt, V. / Faust, R. / Guldi, D. M. et al. | 2014
- 2589
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Back cover| 2014